国家自然科学基金(21171040)

作品数:12被引量:28H指数:3
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相关作者:陈水生乔瑞王德海杨松凡素华更多>>
相关机构:阜阳师范学院郑州幼儿师范高等专科学校南京大学更多>>
相关期刊:《无机化学学报》《Chinese Journal of Structural Chemistry》更多>>
相关主题:CRYSTAL_STRUCTURESYNTHESISLIGANDS荧光性质MIXED更多>>
相关领域:理学化学工程更多>>
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Synthesis,Structure and Luminescent Property of a Zn(Ⅱ)Complex with Mixed Multi-N Donor and 2,5-Dihydroxy-terephthalic Acid Ligands被引量:1
《Chinese Journal of Structural Chemistry》2018年第7期1117-1124,共8页郭星哲 李家乐 施珊珊 周慧 韩帅帅 陈水生 
supported by the National Natural Science Foundation of China(No.21171040);the Natural Science Foundation of Anhui Provincial Education Commission(No.KJ2017ZD29);National Undergraduates Innovation Project(201710371018)
A new complex, [Zn2(HL)2(2,5-OH-pbda)]n(1, L = 1-(1 H-imidazol-4-yl)-4-(4 Htetrazol-5-yl)benzene(H2L) and 2,5-OH-H2 pbda = 2,5-dihydroxy-terephthalic acid), has been hydrothermally prepared and characteriz...
关键词:metal-organic framework CRYSTAL STRUCTURE luminescent property 
Synthesis, Crystal Structure and Luminescent Property of a Zn(Ⅱ) Complex Based on 4-Imidazole-carboxylate Ligand被引量:1
《Chinese Journal of Structural Chemistry》2017年第8期1348-1354,共7页朱美安 郭星哲 陈水生 
supported by the National Natural Science Foundation of China(No.21171040)
A new complex, [Zn(L)2](1), has been hydrothermally prepared by the reaction of ZnSO4·7H2O with 2-(1H-imidazol-4-yl)benzoic acid(HL) incorporating 4-imidazolyl and carboxylate functional groups, and character...
关键词:SYNTHESIS supramolecular polymer LUMINESCENCE 
Synthesis,Crystal Structure and Water Vapor Adsorption Property of a New Supramolecular Architecture被引量:1
《Chinese Journal of Structural Chemistry》2017年第6期985-992,共8页肖伯安 张自由 
Supported by the National Natural Science Foundation of China(No.21171040);National Undergraduates Innovation Project(201510371010)
A new complex, [Cu(HL)(phen)(H2O)]·4H2O(1, H3L·HCl = 5-((4-carboxypiperidin-1-yl)methyl)isophthalic acid hydrochloride, phen = 1,10-phenanthroline), has been hydrothermally prepared and characterized by ...
关键词:Cu(II) complex  supramolecular architecture  gas adsorption 
由芳香羧酸和含氮配体构筑的两个金属锌配合物的合成、晶体结构和荧光性质(英文)被引量:10
《无机化学学报》2017年第2期347-353,共7页肖伯安 陈水生 
国家自然科学基金(No.21171040)资助项目
以1-(4-咪唑基)-4-(四氮唑)苯(HL)与对苯二甲酸(H_2pbda)或间苯二甲酸(H_2mbda)作为混合配体,与硫酸锌进行水热合成反应,构筑了2个新的金属配位配合物[Zn_2(L)_2(pbda)]n(1)和[Zn_2(L)_2(mbda)]_n(2),并进行了元素分析、红外、热重、X...
关键词:配位聚合物 合成 结构 荧光性质 
Two Three-dimensional Supramolecular Polymer Built from Mixed N-Donor and Carboxylate Ligands被引量:2
《Chinese Journal of Structural Chemistry》2016年第5期781-788,共8页肖丽 李卫东 方旭 蒋连燕 陈水生 
supported by the National Natural Science Foundation of China(No.21171040);excellent organic teaching and research project(No.2013JCJS01);National Undergraduates Innovation Project(201510371010)
Two new complexes, [Mn(L)(mmbda)(H_2O)](1) and [Co(L)(btc)(H_2O)]·H_2O(2), were synthesized by reacting the corresponding metal(Ⅱ) salts with rigid ligand 1,4-di(1Himidazol-4-yl)benzene(L) and ...
关键词:synthesis supramolecular polymer non-covalent bonding interactions 
Non-covalent Bonded 3D Supramolecular Architectures Based on Acid-base Adducts被引量:3
《Chinese Journal of Structural Chemistry》2016年第1期46-54,共9页李卫东 方旭 乔瑞 陈水生 
supported by the National Natural Science Foundation of China(No.21171040 and 21302019);the disguished organic project(2013JCJS01)
Two novel acid-base adducts,[H2L1^2+](Hpbda)2(1,L1 = 1,4-di(lH-imidazol-4-yl)benzene,H2pbda = 1,4-benzenedicarboxylic acid) and[H2L2^2+](NO3)2(2,L2 = l,4-di(l-carboxymethyl-imidazol-4-yl)benzene),have be...
关键词:synthesis acid-base adducts crystal structure noncovalent interactions 
Synthesis, Crystal Structure and Properties of a New Cd(II) Complex Based on Mixed 5-Hydroxy-isophthalic Acid and 1-(1H-imidazol-4-yl)-3-(4H-tetrazol-5-yl)benzene Ligands被引量:2
《Chinese Journal of Structural Chemistry》2015年第6期899-905,共7页HU Zhi-Yong ZHU Juan-Juan CHEN Shui-Sheng QIAO Rui 
supported by the National Natural Science Foundation of China(No.21171040 and 21302019);Organic Teaching and Research Project(No.JCJS01 and 201310371004)
A new coordination polymer [Cd2(5-IPA)(HL)2(H20)2]'4H20 (1) was prepared under hydrothermal conditions based on 5-hydroxy-isophthalic acid (5-H2IPA) with multi-N-donor ligand 1-(1H-imidazol-4-yl)-3-(4H-t...
关键词:SYNTHESIS crystal structure luminescence property 
两个基于4-咪唑羧酸配体超分子配位聚合物的合成、结构和性质(英文)被引量:1
《无机化学学报》2015年第2期420-428,共9页陈水生 吕弹龙 乔瑞 朱娟娟 盛良全 
国家自然科学基金(No.21171040,21302019);南京大学配位化学重点实验室开放基金;国家大学生创新项目(No.201310371004);有机教研项目(No.2013JCJS01)资助项目
以含4-咪唑和羧酸基团的双功能基团4-咪唑基苯甲酸(HL1)为配体,用水热法合成了2个超分子化合物[Cd(L1)(HL1)I](1)和[Co2(L1)4(H2O)8](2),并进行了元素分析、红外、热重、粉末衍射及X-射线单晶衍射等表征。晶体结构解析结果表明:配合物1...
关键词:合成 超分子聚合物 荧光性质 气体吸附性质 
Two New Metal-organic Frameworks Constructed from 3,4,5-Substituted-1,2,4-Triazole Ligands被引量:1
《Chinese Journal of Structural Chemistry》2013年第9期1415-1421,共7页陈水生 乔瑞 杨松 凡素华 
supported by the National Natural Science Foundation of China(No.21171040);the Natural Science Foundation of Anhui Provincial Education Commission(No.KJ2011B128,2011SQRL101 and 10040606Q49)
Two new complexes,[Zn(L1)2(SCN)2]·H2O(1,L1 = 3,5-dimethyl-4-p-tolyl-4H1,2,4-triazole and [Cd3(L2)6(SCN)6](2,L2 = 3,5-dimethyl-4-phenyl-4H-1,2,4-triazole),have been hydrothermally prepared and characterized...
关键词:synthesis 1 2 4-triazole metal-organic framework crystal structure 
研究型实验教学对学生知识体系的构建被引量:5
《阜阳师范学院学报(自然科学版)》2013年第1期88-91,共4页陈水生 张淑萍 乔瑞 杨松 凡素华 王德海 
国家自然科学基金项目(21171040);阜阳师范学院教学研究项目(2012JYXM38;2012JCJY22;2012JYXM21)资助
以5-((4-甲酰基-1-哌啶基)甲基)异肽酸及其Cu(II)配合物的合成为例,从化合物的设计合成、目标产物的表征、研究型实验结果反馈三方面阐述了综合性实验与理论知识体系的相互关系。实践表明,研究型综合实验教学能提高学生实验操作技能,培...
关键词:研究型实验实践教学 知识体系 构建 
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