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Synthesis,Crystal Structure,Physical Properties and Theoretical Studies of the New Ternary Sulfide with Closed Cavities:CsYb_7S_(11)被引量：2: 《Chinese Journal of Structural Chemistry》2017年第11期1780-1790,共11页郑宇君刘鹏飞吴新涛吴立明林华; supported by the National Natural Science Foundation of China(21301175,21233009,21571020 and 91422303);the Natural Science Foundation of Fujian Province(2015J01071); A novel ternary rare-earth sulfide, CsYb7S（11）, has been successfully synthesized by high-temperature solid-state reaction of an elemental mixture with modified Cs Cl flux. The single-crystal X-ray diffraction data ...; 关键词：rare-earth sulfide high-temperature solid-state reaction crystal structure magnetic property optical band gap

KBa2(PO3)5： Properties and Comparison with Isostructural Polyphosphate Compounds被引量：1: 《Chinese Journal of Structural Chemistry》2017年第8期1283-1290,共8页Muhammad Ali Khan 段瑞焕黎艳艳刘鹏飞林华陈玲; supported by the National Natural Science Foundation of China(No.21225104,21233009,21301175,21571020 and 91422303); A noncentrosymmetric polyphosphate compound, KBa2（PO3）5, 1 was prepared and characterized. It features 1D [PO3]∞ chains of condensed [PO4]^（3-） tetrahedral units. The polycrystalline sample of 1 exhibits second h...; 关键词：polyphosphate compound thermal analysis second harmonic generation（SHG） optical band gap electronic structure

Ba13(BS3)6(SnS6):Synthesis,Crystal Structure,Electronic Structure,and Optical Property: 《Chinese Journal of Structural Chemistry》2017年第2期204-210,共7页MUHAMMAD Ali Khan 王金秋刘鹏飞陈玲黎艳艳; supported by the National Natural Science Foundation of China(21233009,21225104,91422303,21301175 and 21171168); A new zero-dimensional（0D） thioborate compound Ba（13）（BS3）6（SnS6）, the first one in the AE/B/Sn/Q（AE=alkali-earth metals; Q=S, Se, Te） family, has been synthesized by conventional high-temperature solid-stat...; 关键词：boron filled trigonal alkali BS3 Ba SnS6 Synthesis graphite diffractometer

Synthesis,Crystal Structure,and Optical Property of Zero-dimensional Quaternary Thioborate：Ba9B3GaS15被引量：1: 《Chinese Journal of Structural Chemistry》2016年第12期1860-1867,共8页王金秋刘鹏飞黎艳艳吴立明; Supported by the National Natural Science Foundation of China(21233009,21225104,91422303,21301175 and 21171168); A new zero-dimensional（0D） thioborate Ba_9B_3GaS_（15） has been discovered by conventional high-temperature solid-state reaction. The compound crystallizes in orthorhombic space group Pbca with a = 8.4759（8）,b = ...; 关键词：thioborate high-temperature solid-state reaction crystal structure optical band gap electronic structure calculation

Thermoelectric Properties of Ag-doped In_4Se_(2.95) Polycrystalline Compounds: 《Chinese Journal of Structural Chemistry》2016年第12期1868-1875,共8页陈燕春刘鹏飞陈玲吴立明; supported by the National Natural Science Foundation of China(91422303,21225104,21571020,21233009,and 21301175); In_4Se_3-based materials are noticeable n-type thermoelectric materials because of lead-free and intrinsically low lattice thermal conductivity,but the In4Se_3-δ crystals（with Se-deficiency,δ） suffer strong anisot...; 关键词：In4Se2.95 Ag doping thermoelectric property

Two Near-infrared Emissive Lanthanide-based Metal-organic Complexes Constructed from Efficient Energy Transfer Ligand: 《Chinese Journal of Structural Chemistry》2016年第7期1077-1084,共8页邹述志杜少武; supported by the National Basic Research Program of China(973 Program,2012CB821702);the National Natural Science Foundation of China(21233009 and 21571175);the State Key Laboratory of Structural Chemistry; Utilizing two polycarboxylic acids as primary ligands and 1,10-phenanthrolion as an auxiliary ligand in the existence of lanthanide nitrates, two lanthanide-based complexes formulated as [Nd4（2,6-pydc OH）6（Phen）4...; 关键词：synthesis crystal structure near-infrared material lanthanide-based complexes

A New Pyridine-substituted Azadithiolate 2Fe2S Complex Related to the Active Site of[FeFe]-hydrogenase: 《Chinese Journal of Structural Chemistry》2016年第2期237-245,共9页XU Fen-Fen FENG Ya-Nan DU Shao-Wu CHEN Yi-Feng; supported by the National Basic Research Program of China(973 Program;2012CB821702);the National Natural Science Foundation of China(21233009 and 21173221);the State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences; A new 2Fe2 S complex[（2-C5H4N）N（μ-CH2S）2Fe2（CO）6]（1） related to the active site of[FeFe]-hydrogenase was obtained by treating（HS）2Fe2（CO）6 with（pyridin-2-ylazanediyl）dimethanol.Protonation occurred at t...; 关键词：bioinorganic chemistry [FeFe]-hydrogenase PROTONATION proton reduction

Two Novel Complexes Based on N-N Bridged Ligand:Syntheses,Crystal Structures,Fluorescence and Magnetic Property: 《Chinese Journal of Structural Chemistry》2016年第1期119-128,共10页周忠源邢修双韩云虎田崇斌杜少武; supported by the National Basic Research Program of China(973 Program;2012CB821702);the National Natural Science Foundation of China(21233009 and 21173221);the State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences; Two novel coordination compounds,1[Zn4（L1）4（NO3）2（H2O）2]（NO3）2·2H2O and 2[Mn2（L2）2（DMF）（H2O）3]（ClO4）2·DMF（HL1 = N＇-[（1E）-pyridine-2-ylmethylidene]pyrazine-2-carbohydrazide,H2L2 = 2-hydroxy-3-meth...; 关键词：coordination compounds N–N bridged ligands blue shift antiferromagnetic interactions

Syntheses, Structures and Luminescent Properties of Two Europium-based Metal-organic Frameworks被引量：5: 《Chinese Journal of Structural Chemistry》2015年第8期1265-1272,共8页ZOU Shu-Zhi DU Shao-Wu; supported by the National Basic Research Program of China(973 Program,2012CB821702);the National Natural Science Foundation of China(21233009 and 21173221);the State Key Laboratory of Structural Chemistry; Two new europium-based metal-organic-frameworks （MOFs）, namely [NMen][Eu（m- BDC）2] （1） and [Eu3（p-BDC）4（ClO4）（H2O）4] （2）, have been synthesized and structurally characte- rized. Single-crystal X-ray diff...; 关键词：synthesis crystal structure lanthanide-based MOFs luminescence

Thermoelectric Properties of Ni-substituted Polycrystalline In_4Se_3: 《Chinese Journal of Structural Chemistry》2015年第8期1217-1223,共7页HE Su-Hua LIN Zi-Xiong Muhammad Ali Khan LIU Peng-Fei CHEN Ling WU Li-Ming; supported by National Natural Science Foundation of China(21233009,21225104,91422303,21171168 and 21301175); Thermoelectric （TE） materials can convert directly low-grade heat energy to electricity, and vice versa, which is highly expected to play an important role in the future energy management. The application practice d...; 关键词：In4Se3 TE materials Ni substitution he

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