This work was partly supported by the National Natural Science Foundation of China (Nos. 21429201, 21231003, 21571026). The authors also thank the Network and Information Center of the Dalian University of Technology for part of the computational resources.
Single-electron oxidation of a diiron-sulfur complex [Cpπ*Fe(μ-bdt)FeCp^*] (1, Cp^*=η^5-C5Me5; bdt = benzene-1,2-dithiolate) to [Cp^*Fe(μ-bdt)FeCp^*]]^+ (2) has been experimentally conducted. The bdt...
A new thiolate-bridged diiron complex with two mono-coordinated azido ligands, [Cp*Fe(kt-SMe)N3]2 (Cp^* = η^5-C5Me5), was synthesized from [Cp*Fe(η-SMe)MeCNMPF6]2 and NaN3 in a bi-solvent system of acetone ...