国家自然科学基金(2047104)

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Standard Molar Enthalpy of Formation of RE(C_5H_8NS_2)_3(C_(12)H_8N_2)
《Journal of Rare Earths》2005年第1期93-98,共6页孟祥鑫 帅琪 陈三平 谢钢 高胜利 史启祯 
Project supported by the Natural Science Foundation of China (2047104) and the Natural Science Foundation of Shaanxi Province (2003B19)
Four solid ternary complexes of RE (C_5H_8NS_2)_3(C_(12)H_8N_2) (RE=Eu, Gd, Tb, Dy) were synthesized in absolute ethanol by rare earth chloride low hydrate with the mixed ligands of ammonium pyrrolidinedi-thiocarbamat...
关键词：inorganic chemistry standard molar enthalpy of formation CALORIMETRY constant-volume combustion heat rare earths 
Mixed-valence copper coordination polymers based on CuSCN or CuN_(3) as bridging motifs
《Science China Chemistry》2005年第z1期41-44,共4页FAN Guang,GAO Shengli,CHEN Sanping,ZENG Minghua & XIE Gang Department of Chemistry,Northwest University,Xi’an 710069,China Department of Chemistry,Guangxi Normal University,Guilin 541000,China 
supported by the National Natural Science Foundation of China(Grant No.2047104);the Education Committee of Shaanxi Province(Grants No.01JK229,FF02328 and 05JK291).
Two novel mixed valence copper coordination polymers, [Cu(2-pac)2(CuN3)(H2O)]n (1) and [Cu(2-pac)2(CuSCN)2]n (2), have been prepared through hydrothermal synthesis and analyzed for structure determination, which exhib...
关键词：HYDROTHERMAL synthesis  crystal structure  2-pyrazinecarboxylic acid  coordination polymer. 
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