国家重点基础研究发展计划(2007CB925103)

作品数:13被引量:24H指数:3
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相关作者:季长春李静郑和根王作为许正江更多>>
相关机构:南京大学安庆师范学院中国科学院福建物质结构研究所更多>>
相关期刊:《无机化学学报》《Chinese Journal of Structural Chemistry》《Journal of Rare Earths》《Science China Chemistry》更多>>
相关主题:SYNTHESESCRYSTAL_STRUCTURES晶体结构LIGANDSUPRAMOLECULAR更多>>
相关领域:理学生物学一般工业技术化学工程更多>>
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Synthesis and nonlinear optical properties of copolymers of fluoro-containing bisphenol A and chromophores
《Chinese Chemical Letters》2011年第11期1367-1370,共4页Jie Ping Shi Hui Yang Li Wei Hong Wen Hu Guo Yuan Lu 
supported by the National Natural Science Foundation(No20774039);the National Basic Research Program of China(No2007CB925103)
A series of new fluoro-containing copolymers have been synthesized by a Mitsunobu reaction with 4,4'-(hexafluoroisopropylidene) bisphenol A(6FBPA) and the corresponding N,N-dihydroxyethylaminoaryl azo or ring-loc...
关键词:NLO materials NLO chromophores Ring-locked triene Mitsunobu reaction 
Syntheses,crystal structures and properties of three novel coordination polymers with tripodal imidazole-containing ligands and benzenetetracarboxylate被引量:2
《Science China Chemistry》2010年第10期2164-2169,共6页SU Zhi, FAN Jian & SUN WeiYin State Key Laboratory of Coordination Chemistry Nanjing National Laboratory of Microstructures Coordination Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China 
supported by the National Natural Science Foundation of China (20731004 and 20721002);the National Basic Research Program of China (2007CB925103 and 2010CB923303)
Three novel coordination polymers, [Ni2(tib)2(btec)]·2H2O (1), [Co2(tib)2(btec)]·2H2O (2) and [Zn4(tib)2(btec)Cl4]·2H2O (3), have been synthesized by using mixed ligands of 1,3,5-tris(1-imidazolyl)benzene (tib) and...
关键词:coordination polymer self-penetration crystal structure thermal stability photoluminescence property 
Syntheses and Crystal Structures of Three Coordination Complexes Based on Ln(Ⅲ) and mpca-Ligand
《Chinese Journal of Structural Chemistry》2010年第8期1213-1218,共6页徐基贵 卢振中 卓馨 郑和根 
Supported by the National Natural Science Foundation of China (Nos. 20971065,20771005);National Basic Research Program of China (2007CB925103);the Young Teachers Program of College in Anhui Province (2008jql138);the Natural Science Foundation of Anhui Province (090416239)
Three complexes obtained by the reaction of Pr(Ⅲ) or Nd(Ⅲ) salts with 5-methyl-2-pyrazinecarboxylic acid(Hmpca) are structurally determined by single-crystal X-ray diffraction.Complex [Pr(mpca-)3(H2O)2]2·...
关键词:crystal structure lanthanide complex coordination polymer 
Syntheses and Crystal Structures of Four Cobalt Supramolecular Architectures with Hmtyaa Ligand被引量:3
《Chinese Journal of Structural Chemistry》2010年第6期843-852,共10页马美华 潘兆瑞 徐姣 李一志 郑和根 
Supported by the National Natural Science Foundation of China (Nos. 20971065, 20721002);National Basic Research Program of China (2007CB925103,2010CB923303)
Four cobalt supramolecular architectures with Hmtyaa(2-(5-methyl-1,3,4-thiadiazol-2-ylthio)acetic acid) ligand have been synthesized.[Co(mtyaa)2(H2O)4]·4(H2O)(1):triclinic,space group P1 with a = 6.7537...
关键词:SYNTHESES crystal structures COBALT SUPRAMOLECULAR H-BONDS 
四种新型柔性吡啶基配合物的合成、结构及配体构象与配合物结构的关系被引量:4
《高等学校化学学报》2010年第5期867-873,共7页季长春 许正江 李静 刘光祥 郑和根 
国家自然科学基金(批准号:20971065);国家“九七三”计划项目(批准号:2007CB925103,2010CB923303)资助
合成了柔性配体3-吡啶甲酸-1,2-乙二酯(3-pyridinecarboxylic acid 1,2-ethanediyl ester,pcaede),并将其分别与Co盐和Hg盐进行组装,得到4个新配合物[Co(pcaede)2Cl2.2CH3CN.H2O]n(1),[Co(pcae-de)2Cl2.H2O]n(2),[Hg(pcaede)I2]n(3)和[H...
关键词:晶体结构 柔性配体 构象 理论计算 
Tripod molecules build molecular networks and open-dimer capsules by weak interactions
《Science China Chemistry》2010年第4期851-857,共7页HAN Jun1, DENG Chao1, FANG Ru1, LI YiZhi2, WANG LeYong1& PAN Yi2 1Key Laboratory of Mesoscopic Chemistry, Ministry of Education School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China 2State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China 
supported by the National Natural Science Foundation of China (Grant Nos. 20602017 & 20932004);the National Basic Research Program of China (Grant No. 2007CB925103);the Natural Science Foundation of Jiangsu (Grant No. BK2008259)
Three tripod molecules, tris(2-methoxy-5-nitrobenzyl)phosphine oxide (1), tris(2-butoxy-3-methyl-5-nitrobenzyl)phosphine oxide (2), and tris(3-nitrobenzyl)amine (TNBA), were synthesized and crystallized. The structure...
关键词:TRIPOD molecule SUPRAMOLECULAR network open-dimer capsule weak interaction 
镉配合物的合成、晶体结构与荧光性质被引量:5
《无机化学学报》2009年第12期2083-2089,共7页李静 季长春 王作为 郑和根 
国家自然科学基金(No.20971065,20721002);国家重点基础研究发展计划资助:分子及自旋体系中的量子调控(No.2007CB925103)
用水热合成法得到了镉的2个配合物[CdCl(pybma)·H2O]n(1)和[Cd2(pybma)2(OH-BDC)]n(2)(Hpybma=2-(2-吡啶基)苯并咪唑基乙酸,OH-H2BDC=5-羟基-1,3-苯二酸),对它们进行了元素分析、红外光谱、XRD,热重,荧光等表征,并用X-射线单晶衍射测...
关键词:镉配合物 晶体结构 氢键 荧光性质 
人工核酸酶的设计和与核酸的相互作用被引量:3
《中国科学(B辑)》2009年第3期194-207,共14页张晶晶 邵莺 韦丽 李英 盛欣 刘芳 陆国元 
国家自然科学基金(批准号:20872061;20372032);国家重点基础研究发展计划(编号:2007CB925103)项目资助
人工核酸酶在基因药物设计和分子生物学研究领域具有重要的科学意义,因此人工核酸酶的设计和酶模拟方面的研究引起了广泛关注并取得了重要进展.本文介绍近年来国内外学者和作者研究组在"双功能协同催化"、"双核协同催化"、"无金属催化"...
关键词:人工核酸酶 DNA切割 无金属切割DNA 胍基 氮杂冠醚 
Two novel interpenetrated zinc(Ⅱ) and cadmium(Ⅱ) coordination polymers based on 4-imidazole-benzoate:Syntheses,crystal structures and properties被引量:5
《Science China Chemistry》2009年第4期459-464,共6页BAI ZhengShuai,CHEN ShuiSheng,ZHANG ZhengHua,CHEN ManSheng,LIU GuangXiang & SUN WeiYin State Key Laboratory of Coordination Chemistry,Institute of Coordination Chemistry,School of Chemistry and Chemical Engineering,Nanjing University,Nanjing 210093,China 
Supported by the National Natural Science Foundation of China (Grant Nos. 20731004 & 20721002);the National Basic Research Program of China (Grant No. 2007CB925103)
Two novel interpenetrated coordination polymers,[Zn(IBA)2]n (1) and {[Cd(IBA)2(H2O)].4H2O}n (2),have been synthesized by using 4-imidazole-benzoic acid (HIBA) as ligand under hydrothermal con-ditions. Complex 1 crysta...
关键词:coordination polymer INTERPENETRATION CRYSTAL structure photoluminescence property 
Unprecedented synthesis of chiral calix[4](aza)crowns and its potent encapsulating methanol
《Science China Chemistry》2009年第4期497-504,共8页ZhengYi Li  MingYu Teng  JieJie Ma  Ji Huang  LeYong Wang Yi Pan 
Supported by the National Basic Research Program of China (Grant No. 2007CB925103);the National Natural Science Foundation of China (Grant No. 20602017);NCET-07-0425
Unprecedented synthesis of chiral (aza)crown ethers of calix[4]arene derivatives bearing a carboxyl amide bridge was described. The synthesis proceeds through condensation of the corresponding dinitriles with opticall...
关键词:CHIRAL (aza)crown dinitrile 1 2-aminoalcohol X-ray crystal structure inclusion complex 
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