supported by the National Basic Research Program of China(973Program,2012CB821702);the National Natural Science Foundation of China(21173221and20903096);the State Key Laboratory of Structural Chemistry(20120015)
A pyrazole-substituted diiron dithiolate complex [Fez(p-pdt)(CO)5(3,5-Me2Pz)] (1, 3,5-MezPz = 3,5-dimethylpyrazole) was prepared as a biomimetic model for the active site of [FeFe]-hydrogenase by CO-substituti...
supported by the National Basic Research Program of China(973Program,2012CB821702);the National Natural Science Foundation of China(21173221and20903096);the State Key Laboratory of Structural Chemistry;Fujian Institute of Research onthe Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian350002,China
Two new coordination polymers, [Cd(N3)2(Baep)l/2]n (1) and [Cd2(N3)4(CH3OH)(Bapp)I/.2]n (2) (Baep = 1,4-bis(2-aminoethyl)piperazine, Bapp = 1,4-bis(3-aminopropyl)piperazine) were synthesized. The c...
supported by the State Key Laboratory of Structural Chemistry (CAS,SZD08002-2);National Basic Research Program of China (973 Program,2007CB815306);the National Natural Science Foundation of China (20903096,20733003);Young Scientist’s Foundation of Fujian Province (2006F3163);Knowledge Innovation Program of the Chinese Academy of Sciences
Solvothermal reaction of [WS4]2-with CuCN and trithiocyanuric acid(L1) in orga-nic solvents gave rise to a new W/Cu/S polymer with a 2D anionic network,namely [Et4N]2[WS4Cu3(C3N3S3H1.5)2](1).The anionic layer of...