supported by the National Natural Science Foundation of China(Nos.22371063,22222103,22173015,22025101,and 91961114);the State Key Laboratory of Fine Chemicals at Dalian University of Technology(KF 1607);the Fundamental Research Funds for the Central Universities of China(PA2021GDSK0063,DUT22LAB606).
Organic ligands play a pivotal role in lanthanide luminescence by acting as sensitizers for energy absorption and transfer,a phenomenon known as the fluorescence antenna effect.Herein,we introduce two tetradentate nit...
supported by the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB20000000);the Key Research Program of Frontier Science,CAS(QYZDJ-SSW-SLH033);the National Natural Science Foundation of China(52073286,21875252,21701177);the Natural Science Foundation of Fujian Province(2006L2005)。
A new 3D terbium(Ⅲ)metal-organic network[Tb(HIMDC)(HCOO)(H_(2)O)]_(n)(complex 1)has been synthesized by Tb^(3+)ions coordinated with 4,5-imidazole dicarboxylic acid(H_(3)IMDC)and formic acid under solvothermal condit...
supported by the Foundation of Key Laboratory of Functional Metal-organic Compounds of Hunan Province(MO20K05);Hunan Provincial Natural Science Foundation of China(2019JJ60021,2019JJ50013);the Scientific Research Found of Hunan Provincial Education Department of China(17A049);Industry and Research Key Project of Hengyang City(2019jhzx1093,2018KJ016,2017KJ155,2017KJ193)。
A new terbium(Ⅲ)complex Tb2(C15H11O3)6(2,2?-bipy)2 has been synthesized with 2-(4-methylbenzoyl)benzoic acid and 2,2?-bipy ligands.Crystal data for the complex:monoclinic,space group P21/n,a=14.9738(5),b=13.5469(4),c...
supported financially by Jiangsu Higher Education Institutions of China (18KJB150030)。
Enantiomerically pure lanthanide(Ⅲ)-based phosphonates are successfully synthesized by using(R)-or(S)-(1-phenylethylamino)-methylphosphonate acid(pempH2),namely,R-or S-[Tb3(pempH2)2(pempH)7]-Cl2·H2O(R-Tb or S-Tb),cr...
supported by the Foundation of Key Laboratory of Functional Metal-organic Compounds of Hunan Province,the Foundation of Key Laboratory of Functional Organometallic Materials,University of Hunan Province,Natural Science Foundation of Hunan Province (2019JJ60021,2019JJ50013);the Scientific Research Found of Hunan Provincial Education Department of China (17A049);Industry and Research Key Project of Hengyang City (2018kKJ016,2017KJ155,2017KJ193)。
A new terbium(Ⅲ) complex Tb2(C15H11O3)6(phen)2 has been synthesized with 2-(4-methylbenzoyl)benzoic acid and 1,10-phenanthroline as ligands.Crystal data for the complex are as follows:monoclinic,space group P21/n,a=1...
supported by the National Natural Science Foundation of China(21973047)。
A new terbium(III) metal-organic framework [Tb(HL)(H2O)](Tb L) based on a new synthetic ligand 9-(2,6-dicarboxy-pyridin-4-yl)-9 H-carbazole-3,6-dicarboxylic acid(H4 L) has been synthesized under solvothermal condition...
Supported by the National Natural Science Foundation of China(No.21661014 and 21861020);Natural Science Foundation of Jiangxi Province(20181BAB203001);the Innovation Fund for the Graduate Student(YJS2018059)。
A coordination polymer of [Tb(ntb)]n(1) based on 4,4’,4’’-nitrilotribenzoate ligand(ntb3–) was synthesized. Compound 1 crystallizes in monoclinic system, space group C2/c with a = 13.7318(4), b = 27.5628(9), c = 5...
supported by the cooperative project of Hengyang Normal University with Hengyang Yile New Materials Co.,Ltd.(HXKJ201905);the Natural Science Foundation of Hunan Province(2019JJ60021,2019JJ50013);the Scientific Research Found of Hunan Provincial Education Department of China(17A049);the Industry and Research Key Project of Hengyang City(2018k KJ016,2017KJ155,2017KJ193)
A new terbium(Ⅲ complex Tb(C20H14O3N)3(C12H8N2)(H2O)·H2O has been synthesized with 2-diphenylanine carbonyl benzoic acid and 1,10-phenanthroline as ligands. Crystal data for the complex are as follows: triclinic, ...
Supported by the NSF of China(21361013,31460488);NSF of Fujian(2018J01447);Jiangxi Provincial Department of Education’s Item of Science and Technology(GJJ170637);the Open Foundation(20180008)of State Key Laboratory of Structural Chemistry
A novel terbium-mercury complex [Tb(IA)3(H3 O)2]2 n(2 n HgCl4)(n Hg2 Cl5)·n H3 O· 3 n H2 O(1, HIA = isonicotinic acid) has been synthesized through hydrothermal reactions and characterized by single-crystal X-ray di...
supported by the National Natural Science Foundation of China(No.21671114 and U1804131);Natural Science Foundation of Henan Province(No.182300410166,182102310909 and 182102310897)
A new terbium complex based on biphenyl-2,3,3’,5’-tetracarboxylic acid(H4bptc) has been synthesized, {[Tb(Hbptc)(H2O)4]×H2O}n(1). Its structure was determined by single-crystal X-ray diffraction analysis an...