HOMOCHIRAL

作品数：26被引量：21H指数：2
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相关领域：理学更多>>
相关机构：东南大学更多>>
相关期刊：《Science China Chemistry》《Chemical Research in Chinese Universities》《Chinese Journal of Structural Chemistry》《Science Bulletin》更多>>
相关基金：国家自然科学基金国家重点基础研究发展计划中国博士后科学基金河北省自然科学基金更多>>
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Self-assembly of two pairs of homochiral M_(2)L_(4)coordination capsules with varied confined space using Tröger's base ligands
《Chinese Chemical Letters》2025年第2期332-337,共6页Yi Zhou Wei Zhang Rong Fu Jiaxin Dong Yuxuan Liu Zihang Song Han Han Kang Cai 
supported by the National Natural Science Foundation of China(No.22271164);the Fundamental Research Funds for the Central Universities;Nankai University(NKU)。
Chiral coordination molecular cages/capsules with discrete nanoconfined chiral cavities demonstrate significant potential applications across various fields.In this study,we utilized Tr?ger's base as the building bloc...
关键词：Metal-organic capsule Chirality SELF-SORTING Tröger's base Host-guest recognition 
Hierarchical Homochiral Assembly of Polyhedral Cage-Type Nanoclusters
《CCS Chemistry》2024年第10期2537-2548,共12页Cheng-Long Deng Bao-Liang Han Ze-Yu Liu Zhong-Hua Pan Jiao He Yu-Long Li Zhi-Lin Yang Geng-Geng Luo Chen-Ho Tung Di Sun Lan-Sun Zheng 
supported by the National Natural Science Foundation of China(grant nos.22325105,92361301,52261135637,22171164,92161118,91961105,and 21641011);the Natural Science Foundation of Fujian Province(grant no.2022J01298);the Open Project Program of the State Key Laboratory of Photocatalysis on Energy and Environment(grant no.SKLPEE-KF202109).
Hierarchical chiral self-assembly is of profound significance for biomolecules for their biological functions.Atom-precise metal nanoclusters(NCs)offer better opportunities to construct hierarchical superlattices.Neve...
关键词：polyhydrido copper nanoclusters chiral polyhedral metallacage hierarchical homochiral assembly thermally activated delayed fluorescence 
Homochiral metalated tetraphenylethylene-based organic cages: Unusual chiral and luminescent behavior depending on thermodynamic and kinetic aggregation
《Aggregate》2024年第5期423-432,共10页Hao-Jie Zhang Ya-Liang Lai Hu Yang Xian-Chao Zhou Zi-Jun Yuan Li Deng Xiao-Lan Hu Xue Li Xiao-Ping Zhou Dan Li 
National Natural Science Foundation of China,Grant/Award Numbers:22375075,22171106,21731002,21975104,22301103,22201101;Guangdong Major Project of Basic and Applied Research,Grant/Award Number:2019B030302009;Natural Science Foundation of Guangdong Province,Grant/Award Number:2022A1515011937;Fundamental Research Funds for the Central Universities,Grant/Award Number:21622103;China Postdoctoral Science Foundation,Grant/Award Numbers:2022M711327,2023T160269;Guangdong Provincial Key Laboratory of Speed Capability Research,Grant/Award Number:2023B1212010009;Jinan University。
Chirality and luminescence are important for both chemistry and biology,which are highly influenced by aggregation.In this work,a pair of metalated tetraphenylethylene(TPE)-based organic cage enantiomers are reported,w...
关键词：concentration-dependent chirality kinetic aggregation metalated organic cage TETRAPHENYLETHYLENE thermodynamic aggregation 
Homochiral design of titanium-organic cage for circularly polarized luminescence-based molecular detection
《Science China Chemistry》2023年第9期2558-2562,共5页Guang-Hui Chen Yan-Ping He Yinghua Yu Qiao-Hong Li Jian Zhang 
supported by the National Natural Science Foundation of China (21935010, 92261108, 92161105);the China National Postdoctoral Program for Innovative Talents (BX2021316);the China Postdoctoral Science Foundation (2021M703217)。
Post-assembly modification strategy is used as an effective approach to improve the functional applications of metal-organic cages. The active vertex of the racemic tetrahedral Ti4L6(L = embonate) cages traps four chi...
关键词：chiral recognition circularly polarized luminescence post-assembly modification titanium-organic cages 
In situ synthesized homochiral dysprosium-oxo clusters with threonine Schiff bases
《Chinese Chemical Letters》2023年第8期458-461,共4页Song Peng Xiaoming Ouyang Yihan Wang Qinghu Teng Yan Li Xiuqing Zhang Zhaobo Hu Kai Wang Fupei Liang 
This work was financially supported by the National Natural Science Foundation of China(Nos.21961008,22271068,22075058 and 22261012);Guangxi Science and Technology Base and Talents Program(No.AD21220105);Guangxi Natural Science Foundation(No.2022GXNSFBA035472).
Chiral high-nuclearity lanthanide(4f)clusters have shown fantastic properties in various fields.However,their synthesis is still of great challenge.Herein,we report two pairs of enantiomers of highnuclearity Dy-oxo cl...
关键词：CHIRALITY Lanthanide-oxo cluster In situ synthesis Threonine Schiff bases Hydrolysis Magnetic properties 
MIL-53-based homochiral metal-organic framework as a stationary phase for open-tubular capillary electrochromatography被引量：2
《Journal of Pharmaceutical Analysis》2022年第3期509-516,共8页Xiaodong Sun Bing Niu Qi Zhang Qin Chen 
funded by the National Natural Science Foundation of China(Grant No.:82003705).
Homochiral metal-organic frameworks(MOFs)have attracted considerable attention in many fields of research,such as chiral catalysis and chiral chromatography.However,only few homochiral MOFs can be effectively used in ...
关键词：Homochiral MOF L-His-NH-MIL-53 Chiral stationary phase Capillary electrochromatography ENANTIOSEPARATION 
Homochiral Coordination Polymers from Single Helices to Multiple Helices Controlled by Metal Ions
《Chinese Journal of Structural Chemistry》2021年第9期1131-1137,1107,共8页XU Zhong-Xuan HU Bang-Ping LI Li-Feng XU Shi-Fei 
the National Natural Science Foundation of China(No.21761036)。
Helix as essential molecular chiral phenomenon at supramolecular level offers an affective method to study chiral characteristic of homochiral coordination polymers(CPs).Herein,two homochiral CPs[Cd((R)-CBA)_(2)(3,5-D...
关键词：homochiral coordination polymers helical chain metal ion effect supramolecular framework 
Synthesis, Crystal Structure and Luminescence of One-dimensional Homochiral Terbium (Ⅲ) Coordination Polymers被引量：4
《Chinese Journal of Structural Chemistry》2020年第6期1044-1050,共7页XU Yan LI Xin-Xing WANG Hong-Xia LIU Hao-Ran CHEN Meng-Qi DOU Qiang 
supported financially by Jiangsu Higher Education Institutions of China (18KJB150030)。
Enantiomerically pure lanthanide(Ⅲ)-based phosphonates are successfully synthesized by using(R)-or(S)-(1-phenylethylamino)-methylphosphonate acid(pempH2),namely,R-or S-[Tb3(pempH2)2(pempH)7]-Cl2·H2O(R-Tb or S-Tb),cr...
关键词：terbium(Ⅲ) crystal structure LUMINESCENCE HOMOCHIRAL 
A Zeolitic rho-type Chiral Metal-organic Framework Based on L-alanine被引量：1
《Chinese Journal of Structural Chemistry》2019年第6期963-969,共7页WANG Ning FU Hong-Ru XIE Tao SHI Feng-Yue WANG Ting-Yi YAN Li-Bing LI Fei-Fei 
supported financially by National Natural Science Foundation of China(No.21601080)
One new chiral zeolitic rho-type metal-organic framework [Cd（L-ala）2]n（1） has been successfully synthesized based on L-alanine chiral ligand, which demonstrates the feasibility of fabricating MOF that integrates t...
关键词：HOMOCHIRAL METAL-ORGANIC framework RHO zeolitic TOPOLOGY L-ALANINE 
A 3D Homochiral Mn(Ⅱ) Coordination Polymer Based on the Ligand 2,2'-(Ethane-1,2-diylbis(oxy)) Dicinnamic Acid被引量：1
《Chinese Journal of Structural Chemistry》2018年第6期966-972,共7页陈新 张明星 黄坤林 
supported by Scientific and Technological Research Program of Chongqing Municipal Education Commission(No.KJ130638)
A 3D homochiral coordination polymer [Mn（edca）]n（1） was synthesized from a flexible coupled cinnamic acid ligand, 2,2？-（ethane-1,2-diylbis（oxy）） dicinnamic acid（H_2 edca） and MnCl_2×4 H_2 O under solvother...
关键词：CHIRALITY coupled cinnamic acid MANGANESE second harmonic generation 
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