ENANTIOSEPARATION

作品数:50被引量:46H指数:3
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相关作者:顾峻岭傅若农李方靳慧田颂九更多>>
相关机构:北京理工大学黑龙江省药品检验所中国药品生物制品检定所天津大学更多>>
相关期刊:《Science China Chemistry》《Journal of Beijing Institute of Technology》《Chinese Journal of Polymer Science》《Wuhan University Journal of Natural Sciences》更多>>
相关基金:国家自然科学基金中国博士后科学基金湖北省自然科学基金福建省自然科学基金更多>>
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Synthesis of Proline-Derived Helical Copolyacetylenes as Chiral Stationary Phases for HPLC Enantioseparation
《Chinese Journal of Polymer Science》2025年第1期61-69,I0007,共10页Yue Li Shu-Ming Kang Ge Shi Yi-Fu Chen Bo-Wen Li Jie Zhang Xin-Hua Wan 
supported by the National Natural Science Foundation of China(Nos.52273002 and 52333008);the funding of Boya Postdoctoral Fellowship at Peking University,BMS Junior Fellow Program and the National Funding Program for Postdoctoral Researchers(No.GZC20230031).
A series of optically active copolymers with various feed ratios have been synthesized through helix-sense-selective copolymerization catalyzed by[Rh(norbornadiene)Cl]2-triethylamine.This process involves two proline-...
关键词:Helical copolyacetylene Chiral stationary phase High performance liquid chromatography ENANTIOSEPARATION Hydrogen bonding 
Chiral metal-organic frameworks-based materials for chromatographic enantioseparation
《Chinese Chemical Letters》2024年第12期111-124,共14页Genlin Sun Yachun Luo Zhihong Yan Hongdeng Qiu Weiyang Tang 
supported by the Science and Technology Project of Education Department of Jiangxi Province (No.GJJ201249)。
The homochiral compounds play an important role in human health and pharmaceutical industry.Currently,the chromatographic enantioseparation has become one of the most effective and practical approach to obtain pure en...
关键词:CHIRALITY Racemic separation Chiral metal-organic frameworks Chromatographic technology Chiral stationary phases 
Construction of chiral crown ethers in robust covalent organic frameworks for electrochromatographic enantioseparation
《National Science Review》2024年第10期266-276,共11页Shiguo Fu Gaizhao Qin Jinqiao Dong Chen Yuan Yan Liu Li-Ming Yuan Yong Cui 
financially supported by the National Natural Science Foundation of China(22331007,22225111 and 22174125);the National Key R&D Program of China(2021YFA1200402,2021YFA1501501,2022YFA1503302 and 2021YFA1200302);the Key Project of Basic Research of Shanghai(22JC1402000 and 21JC1401700).
Capillary electrochromatography(CEC)is a rapidly emerging separation technique that merges the high separation efficiency of capillary electrophoresis with the exceptional selectivity of liquid chromatography.However,...
关键词:covalent organic framework chiral material POROSITY capillary electrochromatography ENANTIOSEPARATION 
A chemical perspective on the chiral induced spin selectivity effect被引量:1
《National Science Review》2024年第9期33-46,共14页Brian P.Bloom Zhongwei Chen Haipeng Lu David H.Waldeck 
support from the National Natural Science Foundation of China(22205186);the Research Grants Council of Hong Kong via the Early Career Scheme(26300721);General Research Fund(16300123);support from the United States NSF-CHE-2140249 and the United States DOE grant ER46430.
This review discusses opportunities in chemistry that are enabled by the chiral induced spin selectivity(CISS)effect.First,the review begins with a brief overview of the seminal studies on CISS.Next,we discuss differe...
关键词:CHIRAL spin selectivity hybrid organic-inorganic layered material ENANTIOSEPARATION 
Symmetry breaking of highly symmetrical nanoclusters for triggering highly optical activity
《Fundamental Research》2024年第1期63-68,共6页Xiao Wei Hao Li Honglei Shen Chuanjun Zhou Shuxin Wang Xi Kang Manzhou Zhu 
We acknowledge the financial support of the NSFC(21631001,21871001,and 22101001);the Ministry of Education,and the University Synergy Innovation Program of Anhui Province(GXXT-2020-053).
Developing new approaches to fulfill the enantioseparation of nanocluster racemates and construct cluster-based nanomaterials with optical activity remains highly desired in cluster science,because it is an essential ...
关键词:Atomically precise nanocluster Symmetry breaking ENANTIOSEPARATION Circularly polarized luminescent Photoluminescence 
A quasi-dual-chiral-channel specific enantioseparation material
《Chinese Chemical Letters》2023年第12期514-517,共4页Xinling Lu Yuan Li Jitong Yang Yong Wang 
financially funded by the National Key R&D Program of China(No.2019YFC1905500);National Natural Science Foundation of China(No.21922409);National Natural Science Foundation of China(No.22274109).
Researchers engrossed in enantioseparation keep seeking for versatile chiral separation selectors.This work proposes a concept of quasi-dual-chiral-channel(QDCC)enantioseparation platform,where the surface sequentiall...
关键词:ENANTIOSEPARATION Functional cyclodextrin QUININE Chiral channel High performance liquid chromatography 
A chiral metal-organic framework{(HQA)(ZnCl_(2))(2.5H_(2)O)}n for the enantioseparation of chiral amino acids and drugs
《Journal of Pharmaceutical Analysis》2023年第4期421-429,共9页Xiangtai Zheng Qi Zhang Qianjie Ma Xinyu Li Liang Zhao Xiaodong Sun 
This study was funded by the National Natural Science Foundation of China(Grant No.:82003705);the Shanghai Science and Technology Innovation Foundation(Grant Nos.:23010500200 and 23ZR1422700).
Chiral metal-organic frameworks(CMOFs)with enantiomeric subunits have been employed in chiral chemistry.In this study,a CMOF formed from 6-methoxyl-(8S,9R)-cinchonan-9-ol-3-carboxylic acid(HQA)and ZnCl_(2),{(HQA)(ZnCl...
关键词:Capillary electrochromatography Metal-organic framework ENANTIOSEPARATION Chiral stationary phase Open-tubular column Dansyl amino acids 
Chiral phenethylamine synergistic tricarboxylic acid modified β-cyclodextrin immobilized on porous silica for enantioseparation
《Chinese Chemical Letters》2023年第3期162-165,共4页Hui Li Xiaoping Wang Chengxiang Shi Liang Zhao Zuguang Li Hongdeng Qiu 
supported by the National Natural Science Foundation of China(Nos.22074154 and 22174129);Nature Science Foundation of Zhejiang Province(No.LZY21E030001);Foundation for Science and Tech Research Project of Gansu Province(Nos.20JR10RA052 and 20JR10RA292);LICP Cooperation Foundation for Young Scholars(No.HZJJ20-08)。
In this work, a series of chiral phenethylamine synergistic tricarboxylic acid modified β-cyclodextrin bonded stationary phase for high performance liquid chromatography(HPLC) were synthesized via a simple one-pot sy...
关键词:Tricarboxylic acid Β-CYCLODEXTRIN Chiral stationary phases ENANTIOSEPARATION One-pot strategy 
MIL-53-based homochiral metal-organic framework as a stationary phase for open-tubular capillary electrochromatography被引量:2
《Journal of Pharmaceutical Analysis》2022年第3期509-516,共8页Xiaodong Sun Bing Niu Qi Zhang Qin Chen 
funded by the National Natural Science Foundation of China(Grant No.:82003705).
Homochiral metal-organic frameworks(MOFs)have attracted considerable attention in many fields of research,such as chiral catalysis and chiral chromatography.However,only few homochiral MOFs can be effectively used in ...
关键词:Homochiral MOF L-His-NH-MIL-53 Chiral stationary phase Capillary electrochromatography ENANTIOSEPARATION 
A β-cyclodextrin covalent organic framework used as a chiral stationary phase for chiral separation in gas chromatography被引量:1
《Chinese Chemical Letters》2022年第2期898-902,共5页Bo Tang Wei Wang Huipeng Hou Yiquan Liu Zongkun Liu Lina Geng Liquan Sun Aiqin Luo 
financially supported by the National Key R&D Program of China (No.2019YFA0904104)。
Chiral covalent organic frameworks(CCOFs) featuring chirality, stability, and good porosity have attracted a considerable amount of attention due to their important applications, such as asymmetric catalysis, chiral s...
关键词:Β-CYCLODEXTRIN Covalent organic framework Chiral stationary phase Gas chromatography ENANTIOSEPARATION 
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