supported by the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB20000000);the Key Research Program of Frontier Science,CAS(QYZDJ-SSW-SLH033);the National Natural Science Foundation of China(52073286,21875252,21701177);the Natural Science Foundation of Fujian Province(2006L2005)。
A new 3D terbium(Ⅲ)metal-organic network[Tb(HIMDC)(HCOO)(H_(2)O)]_(n)(complex 1)has been synthesized by Tb^(3+)ions coordinated with 4,5-imidazole dicarboxylic acid(H_(3)IMDC)and formic acid under solvothermal condit...
supported by the Foundation of Key Laboratory of Functional Metal-organic Compounds of Hunan Province,the Foundation of Key Laboratory of Functional Organometallic Materials,University of Hunan Province,Natural Science Foundation of Hunan Province (2019JJ60021,2019JJ50013);the Scientific Research Found of Hunan Provincial Education Department of China (17A049);Industry and Research Key Project of Hengyang City (2018kKJ016,2017KJ155,2017KJ193)。
A new terbium(Ⅲ) complex Tb2(C15H11O3)6(phen)2 has been synthesized with 2-(4-methylbenzoyl)benzoic acid and 1,10-phenanthroline as ligands.Crystal data for the complex are as follows:monoclinic,space group P21/n,a=1...
supported financially by Jiangsu Higher Education Institutions of China (18KJB150030)。
Enantiomerically pure lanthanide(Ⅲ)-based phosphonates are successfully synthesized by using(R)-or(S)-(1-phenylethylamino)-methylphosphonate acid(pempH2),namely,R-or S-[Tb3(pempH2)2(pempH)7]-Cl2·H2O(R-Tb or S-Tb),cr...
supported by Youth Fund of Nanyang Normal University(QN2017046)
A dual functional coordination polymer, namely, {[Tb(mat)(1.5)H2O]·2.5H2O}n(1, H2mta = 2-methoxyterephthalic acid), was synthesized under solvothermal condition and characterized by single-crystal X-ray diffrac...
Supported by the National Natural Science Foundation of China(No.21361011 and 21101081);Science Founds of State Key Laboratory of Structural Chemistry(20130011)
A dinuclear Tb(Ⅲ) compound, Tb_2(μ_2-anthc)_4(anthc)_2(1,10-phen)_2(1, Hanthc = 9-anthracenecarboxylic acid and 1,10-phen = 1,10-phenanthroline), was synthesized under solvothermal condition and structural...
Supported by Henan Province Key Scientific Research Projects(122102210395);Pingdingshan Key Scientific Research Projects(No.2013066)
A new coordination compound with formula [Tb(2-TC)3(DMF)]n (1, 2-TC = 2-thio- phenecarboxylic ligand and DMF = dimethylformamide) was synthesized by solvothermal method. The structure of compound 1 was determine...
supported by the National Natural Science Foundation of China (91022025, 51072036);the Natural Science Foundation of Fujian Province (2010J01284)
A new nonlinear optical crystal of sodium terbium borate (Na2.67Tb2.11B3O9, Mr = 573.14) was synthesized by solid reaction method. The colorless transparent single crystals were grown from the high temperature solut...
supported by the Natural Science Foundation of Jiangxi Province (No. 0320026 and 0520036);the Natural Science Foundation of Jinggangshan University (No. JZ0815)
A novel Tb(Ⅲ) coordination polymer [Tb(bpapO2)2(NO3)3]n [bpapO2 = N2,N6- bi(pyridin-2-yl)pyridine-2,6-diamine-N,N'-dioxide-dioxide] has been synthesized and it exhibits terbium’s characteristic fluorescent ...
supported by the Natural Science Foundation of Beijing (2073022)
The complex of [Tb(2-IBA)3(H2O)2]n (2-IBA=2-iodobenzoate) was prepared by solvent method from TbCl3-6H2O and 2-iodobenzoic acid. The crystal structure was determined with X-ray single-crystal diffraction. The X-...
the National Natural Science Foundation of China (No. 20573113)
TbCu(TeO3)2Cl was obtained in high yield from high temperature solid-state reacion of Tb407, CuO, CuCl2 and TeO2 in a 1:2:2:8 molar ratio at 710 ℃ in an evacuated quartz tube. Its structure was established by si...