HYDRODENITROGENATION

作品数:15被引量:28H指数:3
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相关领域:理学石油与天然气工程更多>>
相关作者:崔勇更多>>
相关机构:清华大学更多>>
相关期刊:《Carbon Resources Conversion》《Journal of Chemistry and Chemical Engineering》《Petroleum Science》《Chinese Journal of Chemical Engineering》更多>>
相关基金:国家自然科学基金国家重点基础研究发展计划中国科学院科研项目更多>>
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Effect of noble metal nanoparticle size on C–N bond cleavage performance in hydrodenitrogenation: a study of active sites
《Frontiers of Chemical Science and Engineering》2023年第12期1986-2000,共15页Yi-Fan Xue Jie Feng Yun-Cai Song Wen-Ying Li 
supported by the Key Project of National Natural Science Foundation of China(Grant No.22038008);the Science and Technology Innovation Project of National Energy Group China Shenhua Coal to Oil Chemical Co.(Grant No.MZYHG-2021-01).
Breakage of the C-N bond is a structure sensitive process,and the catalyst size significantly affects its activity.On the active metal nanoparticle scale,the role of catalyst size in C-N bond cleavage has not been cle...
关键词:SP3 sp2-hybridized C–N bond noble metal nanoparticle catalytic active site turnover frequency DFT 
Promotion of boron phosphate on the NiMoAl catalyst for hydroprocessing FCC slurry oil
《Carbon Resources Conversion》2022年第3期240-247,共8页Changwei Liu Chunyan Tu Qi Chen Qian Zhang Wei Huang 
This work was supported by the National Natural Science Foundation of China(21808155);the National Key R&D Program of China(2018YFB0604600-01).
Mesoporous NiMoAl catalysts with boron phosphate(BPO4)modification were synthesized through the complete liquid-phase method.X-ray diffraction(XRD)analysis evidenced the presence of BPO4-AlOOH mixed support in these B...
关键词:NiMo catalysts Boron phosphate FCC slurry oil HYDRODENITROGENATION HYDRODESULFURIZATION 
Catalyst particle shapes and pore structure engineering for hydrodesulfurization and hydrodenitrogenation reactions
《Frontiers of Chemical Science and Engineering》2022年第6期897-908,共12页Yao Shi Zhao Li Changfeng Yang Zhanlin Yang Zhenhui Lv Chong Peng Bao-Lian Su Weikang Yuan Xinggui Zhou Xuezhi Duan 
the National Natural Science Foundation of China(Grant Nos.22038003,21922803,22178100 and 21776077);the Innovation Program of Shanghai Municipal Education Commission,the Program of Shanghai Academic/Technology Research Leader(Grant No.21XD1421000).
Catalyst particle shapes and pore structure engineering are crucial for alleviating internal diffusion limitations in the hydrodesulfiirization(HDS)/hydrodeni-trogenation(HDN)of gas oil.The effects of catalyst particl...
关键词:hydrodesulfiirization HYDRODENITROGENATION particle shape pore structure 
Charge effects on quinoline hydrodenitrogenation catalyzed by Ni-Mo-S active sites-A theoretical study by DFT calculation被引量:2
《Petroleum Science》2022年第1期339-344,共6页Si-Jia Ding Shao-Zhong Peng Zuo-Jie Yan Ji-Feng Wang Shu-Jiao Jiang Zhan-Lin Yang 
the financial support from the Sinopec Science and Technology Department(Grant No.121014-1)。
The charge distribution on Ni-Mo-S active sites can affect hydrodenitrogenation(HDN)activity.In this study,a series of model Ni-Mo-S were developed with various charge distributions.For comparison,the charge distribut...
关键词:Charge distribution Ni-Mo-S active Sites QUINOLINE HYDRODENITROGENATION Quantum chemistry calculation 
Supercritical Water as a Reaction Medium for Nitrogen-Containing Heterocycles被引量:1
《Journal of Chemistry and Chemical Engineering》2012年第10期897-910,共14页Wahyudiono Yui Matsunaga Siti Machmudah Mitsuru Sasaki Motonobu Gotol 
Supercritical water has been focused on as an environmentally attractive reaction media, in which organic materials can be decomposed into smaller molecules. The reaction behavior of pyrrole as a simple model compound...
关键词:Supercritical water PYRROLE HYDRODENITROGENATION non-basic aromatic nitrogen compound conversion. 
NiMo/Al_2O_3 catalyst containing nano-sized zeolite Y for deep hydrodesulfurization and hydrodenitrogenation of diesel被引量:8
《Journal of Natural Gas Chemistry》2011年第4期441-448,共8页Hailiang Yin Tongna Zhou Yunqi Liu Yongming Chai Chenguang Liu 
financially supported by the Basic Research Program'Green Chemistry and Engineering of Heavy Oil Conversion with High Efficiency' and the National Key Fundamental Research Development Project(973 Project:No.2010CB226905)
Two mixed-matrix NiMo/Al2O3 catalysts containing nano-and micro-sized zeolite Y have been prepared to explore the size effect of zeolite Y particle on the hydrodesulfurization(HDS)and hydrodenitrogenation(HDN)acti...
关键词:zeolite Y nano-sized zeolite micro-sized zeolite HYDRODESULFURIZATION HYDRODENITROGENATION DIESEL 
Synergetic effect between sulfurized Mo/γ-Al_2O_3 and Ni/γ-Al_2O_3 catalysts in hydrodenitrogenation of quinoline被引量:4
《Journal of Natural Gas Chemistry》2011年第2期214-217,共4页Lihua Liu Bin Liu Yongming Chai Yunqi Liu Chenguang Liu 
supported by the State Key Development Program for Basic Research of China (No. 2010CB226905);supported by the Basic Research Program " Green Chemistry and Engineering of Heavy Oil Conversionwith High Efficiency "
An evidence for the synergetic effect between the stacked bed of Mo/γ-Al2O3 and Ni/γ-Al2O3 in the hydrodenitrogenation (HDN) reaction of quinoline has been provided in this paper. The synergism factor decreases wh...
关键词:hydrogen spillover synergetic effect HYDRODENITROGENATION NiMo catalyst 
Synthesis of Ni_2P promoted trimetallic NiMoW/γ-Al_2O_3 catalysts for diesel oil hydrotreatment被引量:3
《Journal of Natural Gas Chemistry》2011年第2期117-122,共6页Ling Lan Shaohui Ge Kunhong Liu Yuandong Hou Xiaojun Bao 
supported by the PetroChina Innovation Foundation (2009D-5006-04-01);Petro China Company Limited of Science and Tech-nology (2008-B-3104-01-01)
The Ni2P promoted and γ-Al2O3 supported NiMoW sulfide catalyst consisting of 4 wt% Mo, 22 wt% W, 2 wt% Ni and 2.5 wt% Ni2P was synthesized by a co-impregnation method. The catalysts were characterized by N2 adsorptio...
关键词:NiMoW sulfide Ni2P phosphide HYDRODESULFURIZATION HYDRODENITROGENATION diesel oil 
Synthesis, characterization and hydrotreating performance of supported tungsten phosphide catalysts
《Frontiers of Chemical Science and Engineering》2008年第2期155-164,共10页Guida SUN Cuiqing LI Zhijun ZHOU Fengyan LI 
State Key Development Basic Research of China(Grant No.G2000048003);the National Natural Science Foundation of China(Grant No.200273011);China Petrochemical Corporation(X501022).
Supported tungsten phosphide catalysts were prepared by temperature-programmed reduction of their precursors(supported phospho-tungstate catalysts)in H2 and characterized by X-ray diffraction(XRD),BET,temperature-prog...
关键词:supported tungsten phosphide catalyst hydrodesulfurization(HDS) hydrodenitrogenation(HDN) DIBENZOTHIOPHENE carbazole 
Preparation, Characterization, Hydrodesulfurization and Hydrodenitrogenation Activities of Alumina-supported Tungsten Phosphide Catalysts被引量:11
《Chinese Journal of Chemical Engineering》2006年第2期184-193,共10页李翠清 孙桂大 李成岳 宋亚娟 
Supported by the National Natural Science Foundation of China (No.200273011), the National 973 Project (No.G2000048003)and the Beijing Natural Science Foundation (No.2052009).
Two series of WP/Al2O3 catalyst precursors with WP mass loading in the range 18.5%—37.1% were prepared using the impregnation method and mixing method, respectively, and the catalysts were then obtained by temperatur...
关键词:HYDRODESULFURIZATION HYDRODENITROGENATION tungsten phosphide PYRIDINE THIOPHENE 
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