BOROHYDRIDE

作品数：39被引量：42H指数：3
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Facile construction of Mxene-supported niobium hydride nanoparticles toward reversible hydrogen storage in magnesium borohydride
《Rare Metals》2024年第9期4387-4400,共14页Ao Xia Jia-Guang Zheng Qing-Bo Zhang Yu-Gang Shu Cheng-Guo Yan Liu-Ting Zhang Zhan-Liang Tao Li-Xin Chen 
financially supported by the National Natural Science Foundation of China(No.52201255);the Natural Science Foundation of Jiangsu Province(No.BK20210884);the Innovation and Entrepreneurship Program of Jiangsu Province(No.JSSCBS20211007)。
The facile construction of nanoscale NbH_(x)supported by Ti_(3)C_(2)(NbH_(x)@Ti_(3)C_(2))was achieved using facile ball milling strategy to improve the hydrogen desorption kinetics and reversibility of magnesium boroh...
关键词：Hydrogen storage Magnesium borohydride Catalysts Mxene 
Borohydride Ammoniate Solid Electrolyte Design for All-Solid-State Mg Batteries被引量：1
《Energy & Environmental Materials》2024年第1期100-106,共7页Yuepeng Pang Zhengfang Nie Fen Xu Lixian Sun Junhe Yang Dalin Sun Fang Fang Shiyou Zheng 
the support of the National Natural Science Foundation of China(51971146,51971147,52171218 and 52271222);the Shanghai Municipal Science and Technology Commission(21010503100);the Major Program for the Scientific Research Innovation Plan of Shanghai Education Commission(2019-01-07-00-07E00015);the Shanghai Outstanding Academic Leaders Plan,the Guangxi Key Laboratory of Information Materials(Guilin University of Electronic Technology,201017-K);the Shanghai Rising-Star Program(20QA1407100);the General Program of Natural Science Foundation of Shanghai(20ZR1438400)
Searching for novel solid electrolytes is of great importance and challenge for all-solid-state Mg batteries.In this work,we develop an amorphous Mg borohydride ammoniate,Mg(BH_(4))_(2)·2NH_(3),as a solid Mg electrol...
关键词：all-solid-state Mg batteries amorphization Mg borohydride ammoniate Mg vacancy migration solid electrolyte 
Magnesium borohydride Mg(BH_(4))_(2) for energy applications:A review
《Journal of Materials Science & Technology》2023年第30期170-179,共10页Xiao Li Yigang Yan Torben R.Jensen Yaroslav Filinchuk Iurii Dovgaliuk Dmitry Chernyshov Liqing He Yongtao Li Hai-Wen Li 
This work was financially supported by the National Natural Science Foundation of China Projects(Nos.52171205,21975168 and 52101249);the Anhui Provincial Natural Science Foundation for Ex-cellent Youth Scholars(No.2108085Y16);the Youth Science and Technology Fund Project of China Machinery Industry Group Co.,Ltd.(No.QNJJ-ZD-2022-01);the Natural Science Foundation of Anhui Province(No.2108085QE191);This work was also sup-ported by the Independent Research Fund Denmark for Technology and Production(No.9041-00226B);by FNRS(PDR T.0169.13,EQP U.N038.13,J.0164.17,CdR J.0073.20);the CommunautéFrançaise de Belgique under Grant ARC 18/23-093.
Mg(BH_(4))_(2) with several polymorphs,known as a high capacity(14.9 wt.%)hydrogen storage material,has become more intriguing due to the recently found new functions of gas physisorption and ionic conduc-tivity.Here ...
关键词：HYDRIDE Hydrogen storage Gas adsorption Hydrogen adsorption ELECTROLYTE 
Niobium fluoride-modified hydrogen evolution reaction of magnesium borohydride diammoniate
《Journal of Materials Science & Technology》2023年第25期197-205,共9页Yujie Lv Bao Zhang Haixiang Huang Bogu Liu Wei Lv Jianguang Yuan Guanglin Xia Xuebin Yu Dalin Sun Ying Wu 
supported by the National Key Research and Development Plan(Grant No.2021YFB3802400);the National Natural Science Foundation of China(Grant Nos.52071141,52271212,52201250);the Equipment Pre-research Field Foundation(Grant No.6140721040101);the Interdisciplinary Innovation Program of North China Electric Power University(Grant No.XM2112355).
Metal borohydride ammoniates have become one of the most promising hydrogen storage materials due to their ultrahigh capacities.However,their application is still restricted by the high temperature of hydrogen desorpt...
关键词：Hydrogen storage Magnesium borohydride Ammoniates NbF5 CATALYSIS 
Li-and Mg-based borohydrides for hydrogen storage and ionic conductor被引量：1
《Journal of Materials Science & Technology》2023年第22期181-204,共24页Yike Huang Yun Zheng Jianding Li Xiaozhi Bao Junpo Guo Jingjun Shen Yan Guo Qi Zhang Jing Li Wen Lei Huaiyu Shao 
H.S.acknowledges the Guangdong-Hong Kong-Macao Joint Laboratory (Grant No.2019B121205001),Macao Sci-ence and Technology Development Fund (FDCT) (Project No.0098/2020/A2),National Key Research and Development Program (No.2022YFE0206400),Natural Science Foundation of Guang-dong Province (No.2023A1515010765)and FDCT-MOST joint project (Grant No.0026/2022/AMJ)for funding.We also acknowl-edge the support of the National Natural Science Foundation of China (Grant No.52104309);Natural Science Foundation of Hubei Province (No.2021CFB011);“Macao Young Scholars Program”China (No.AM2020004);FDCT Funding Scheme for Postdoctoral Researchers (No.0026/APD/2021).
LiBH_(4) and Mg(BH_(4))_(2) with high theoretical hydrogen mass capacity receive significant attentions for hy-drogen storage.Also,these compounds can be potentially applied as solid-state electrolytes with their high...
关键词：Hydrogen storage Solid-state electrolyte Ionic conductor BOROHYDRIDE Thermal analysis 
Coupling atom ensemble and electron transfer in PdCu for superior catalytic kinetics in hydrogen generation被引量：1
《Nano Research》2023年第7期9012-9021,共10页Xinru Zhao Yanyan Liu Huiyu Yuan Hao Wen Huanhuan Zhang Saima Ashraf Shuyan Guan Tao Liu Sehrish Mehdi Ruofan Shen Xianji Guo Yanping Fan Baozhong Liu Baojun Li 
This work was financially supported by the National Natural Science Foundation of China(Nos.22279118,22279117,52071135,51871090,and U1804135);the Fundamental Research Funds for the Universities of Henan Province(No.NSFRF220201).
The design of high-performance catalysts is the key to the efficient utilization of hydrogen energy.In this work,a PdCu nanoalloy was successfully anchored on TiO_(2)encapsulated with carbon to construct a catalyst.Ou...
关键词：PdCu nanoalloy d-band holes ensemble effect borohydride hydrolysis dual-active sites 
Robust architecture of 2D nano Mg-based borohydride on graphene with superior reversible hydrogen storage performance被引量：3
《Journal of Materials Science & Technology》2023年第15期121-130,共10页Xuancheng Wang Yuxiao Jia Xuezhang Xiao Panpan Zhou Jiapeng Bi Jiacheng Qi Ling Lv Fen Xu Lixian Sun Lixin Chen 
supported by the National Natural Science Foundation of China(Nos.52171223 and U20A20237);the Zhejiang Provincial Natural Science Foundation of China(No.LZ21E010002).
Efficient technical strategies to synthesize hydrides with high capacity and favorable reversibility are significant for the development of novel energy materials.Herein,nano Mg-based borohydride,Mg(BH_(4))_(2),with r...
关键词：Mg(BH_(4))_(2) Nano-confinement Kinetics THERMODYNAMICS Reversible hydrogen storage 
Polar O-Co-P Surface for Bimolecular Activation in Catalytic Hydrogen Generation
《Energy & Environmental Materials》2023年第1期224-233,共10页Huanhuan Zhang Ke Zhang Saima Ashraf Yanping Fan Shuyan Guan Xianli Wu Yushan Liu Baozhong Liu Baojun Li 
H.Z.and K.Z.contributed equally to this work.Financial supports from the National Natural Science Foundation of China (nos.22075254,52071135,51871090,U1804135,21805071,51671080,and 21401168);Plan for Scientific Inno-vation Talent of Henan Province (no.194200510019);Key Project of Educa-tional Commission of Henan Province (no.19A150025)are acknowledged.
Boron hydrides release an abundant amount of hydrogen in the presence of a suitable catalyst.Accelerating bimolecular activation kinetics is the key to designing cost-effective catalysts for borohydride hydrolysis.In ...
关键词：bimolecular activation borohydride hydrolysis hydrogen generation noble-metal-free catalysts polar site 
Modulation effects of Cu modification and ligands (oxalate and borohydride) functionalization on Pt d-band center, upper d-band edge, and alloyed PtCe support acidity on semihydrogenation of acetylene
《Journal of Energy Chemistry》2022年第9期495-508,I0014,共15页Olumide Bolarinwa Ayodele 
The modulating effects of Cu modification and oxalate or borohydride ligands functionalization on the structure,catalyst d-band center(εd),upper d-band edge(εu),and acetylene partial hydrogenation of expediently syn...
关键词：ACETYLENE SEMIHYDROGENATION Ethylene Pt d-band center Upper d-band edge 
Current Research Progress in Magnesium Borohydride for Hydrogen Storage(A review)被引量：1
《Progress in Natural Science:Materials International》2021年第6期809-820,共12页Yujie Lv Ying Wu 
supported by National Key Research and Development Plan(2018YFB1502102);the National Natural Science Foundation of China(Grant no.52071141,51371056,51771056,51701043);the Equipment Pre-research Field Foundation(6140721040101);Interdisciplinary Innovation Program of North China Electric Power University(Grant no.XM2112355)。
Hydrogen storage in solid-state materials is believed to be a most promising hydrogen-storage technology for high efficiency,low risk and low cost.Mg(BH_(4))_(2)is regarded as one of most potential materials in hydrog...
关键词：Magnesium borohydride Hydrogen storage BOROHYDRIDES KINETICS THERMODYNAMICS 
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