Cyclocarbon fully consists of sp-hybridized carbon atoms,which shows quite unusual electronic and geometric structures compared to common molecules.In this work,we systematically studied strain energy(SE)of cyclocarbo...
financially supported by the National Natural Science Foundation of China(21790053,and 51821002);the Ministry of Science and Technology(2017YFA0205002);the Collaborative Innovation Center of Suzhou Nano Science&Technology,the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD);the 111 project。
Direct coupling or transformation of inert alkanes based on the selective C-H activation is of great importance for both chemistry and chemical engineering.Here,we report the coupling of polyenes that are transformed ...
Lobetyolin(LBT)is a polyacetylene glycoside found in diverse medicinal plants but mainly isolated from the roots of Codo-nopsis pilosula,known as Radix Codonopsis or Dangshen.Twelve traditional Chinese medicinal prepa...
supported partly by the National Natural Science Foundation of China,No.30873057,81171245;a grant from the Key Basic Project of Shanghai Municipal Science and Technology Commission of China,No.08JC1413600,11JC1406600
Nerve growth factor(NGF) promotes axonal growth in PC12 cells primarily by regulating the RTK-RAS-MEK-ERK pathway. Panaxydol, a polyacetylene isolated from Panax notoginseng, can mimic the effects of NGF. Panaxydol ...
funded by the National Science and Technology Project of China(No.2012ZX09301002-001003)
Four new glycosides including a eudesmane-type sesquiterpenoid(1), a guaiane-type sesquiterpenoid(2), and two C_(14)-polyacetylenes(3, 4) were isolated from the rhizomes of Atractylodes lancea. Their structure...
financially supported by the National Natural Science Foundation of China(Nos.21074073 and 51173050);The Guangdong Provincial Engineering Research Center of Green Fine Chemical Technology,China
A novel phenylacetylene derivative containing urea groups was synthesized and polymerized with a Rh catalyst to give the corresponding polymer, poly(1) with moderate number-average molecular weights. The poly(1) w...
financially supported by the National Natural Science Fund of China(Nos.20971021,51073031 and 20974018);the National Oversea Scholar Cooperation Research Found of China(No.50928301)
A novel functional polyacetylene containing fluorene group as a pendant,poly(2-(p-methylstyrene)-7-acetylene-9,9-dioctyl-fluorene), was synthesized in moderate yield by[Rh(nbd)Cl]_2-Et_3N catalyst.The structures...
supported by the National Natural Science Fund of China(No.21071002/B0111);the Natural Science Fund of Anhui Province(No.11040606M33)
Two new functional polyacetylenes bearing carbazole group as pendant, poly { 3-[(4-ethynylstyryl)-N-butyl] carbazole } (P1 ) and poly{3-14-(prop-2-ynyloxy)phenyl-N-butyl]carbazole}(P2), were prepared using [Rb...
supported by the National Natural Science Foundation of China(Nos.20634020,5074046016 and 50703033);the Ministry of Science&Technology(No.2009CB623605);the Research Grants Council of Hon Kong(Nos.603008,602707 and 602706);the support from the Cao Guangbiao Foundation of Zhejian University
Functional polyacetylenes containing pyridinium side groups(PPyA-MX,X = Br and I) were successfully synthesized.Spectroscopic techniques such as ^1H-NMR,^(13)C-NMR,and FTIR spectroscopy were used to characterize t...
Supported by the National Natural Science Foundation of China(Nos.50773029 and 50902067);the Natural Science Foundation of Jiangxi Province,China(Nos.2007GZC1727 and 2008GQH0046);the Program for Innovative Research Team in University of Jiangxi Province,China
Poly(1-alkyne) with octoxy spacer —{[HC=C(CH2)8O—terphenyl—CN]}n—(PA8CN) and terphenyl liquid crystalline pendant was synthesized,and the effects of structure on the optical properties,especially the liquid ...