Financial support for this work was provided by the National Natural Science Foundation of China(nos.21931013,21702225,21672238,and 21421002);the Strategic Priority Research Program of the Chinese Academy of Sciences(no.XDB20000000).
Although trifluoromethylthiolated compounds have privileged applications in pharmaceuticals and agrochemicals,efficient strategies for the asymmetric construction of C_(sp)^(3)-SCF_(3)bonds are limited.Specifically,th...
the National Natural Science Foundation of China(Nos.21873044 and 21901109);Science and Technology Innovation Commission of Shenzhen Municipality(No.JCYJ 20170817104715174);the Guangdong Major Project of Basic and Applied Basic Research(No.2019B030302009).
Three zwitterionic and one cationic N-heterocyclic allenylidene(NHA)platinum(Ⅱ)complexes were prepared and characterized via NMR,HR-MS;and FT-IR,etc.Single crystal structure analyses revealed the various intermolecul...
This research was supported by the National Natural Science Foundation of China (Nos. 21332002).
A variety of rigid ruthenium and osmium allenylidene, ruthenium alkynyl-allenylidene complexes have been prepared. These allenylidene complexes were derived from 9-ethynyl-9-fluorenol and 9-hydroxy-9-ethynyl-4,5-diaza...