SEMIQUINONE

作品数：8被引量：10H指数：2
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Intrinsic chemiluminescence production from the degradation of haloaromatic pollutants during environmentally-friendly advanced oxidation processes:Mechanism,structure-activity relationship and potential applications被引量：4
《Journal of Environmental Sciences》2017年第12期68-83,共16页Benzhan Zhu Chen Shen Huiying Gao Liya Zhu Jie Shao Li Mao 
supported by the Strategic Priority Research Program of CAS(No.XDB01020300);NSF China Grants(Nos.21577149,21477139,21237005 and 21321004);NIH Grants(Nos.ES11497,RR01008 and ES00210)
The ubiquitous distribution of halogenated aromatic compounds（XAr） coupled with their carcinogenicity has raised public concerns on their potential risks to both human health and the ecosystem. Recently, advanced ox...
关键词：Halogenated phenols Halogenated quinoid intermediates Semiquinone radical Hydroxyl radicals Fenton reaction Chemiluminescene method 
Radical Stabilization in Dissolved Humates
《Open Journal of Physical Chemistry》2011年第3期55-60,共6页Barbora Bakajová Ray von Wandruszka 
Quinoid entities, in which quinone and hydroquinone groups equilibrate via a semiquinone radical intermediate, are a common structural feature in humic materials. The electron paramagnetic resonance (EPR) signals of t...
关键词：HUMIC Acid SEMIQUINONE EPR Enhancement BRIDGING Interactions Aggregation RADICAL STABILIZATION 
Photogeneration of the free radicals and singlet oxygen by chrysophanol from rheum被引量：3
《Science China Chemistry》2004年第5期381-387,共7页RAO Jing1,2, XIE Jie1, ZHAO Jingquan1 & ZHU Teng2 1. Key Laboratory of Photochemistry, Center for Molecular Science, Institute of Chemistry, The Chinese Academy of Sciences, Beijing 100080, China 2. University of Science and Technology Beijing, Beijing 10083, China 
This work was supported by the National Natural Science Foundation of China(Grant No.20273079).
In the current work, chryosphanol (MHAQ) was isolated and purified from rheum, and the photosensitization activities were studied. In nitrogen-saturated DMSO solution, irradia- tion of chryosphanol (MHAQ) with visible...
关键词：chrysophanol  ESR  SEMIQUINONE RADICAL anions  superoxide RADICAL anions  hydroxyl radical  singlet oxygen. 
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