相关期刊:《Journal of Chemistry and Chemical Engineering》《Chinese Journal of Structural Chemistry》《Science Bulletin》《International Journal of Organic Chemistry》更多>>
A silica-supported poly-γ- aminopropylsiloxane-rhodium-cobalt bimetallic complex(abbreviated as SiO_2-NH_2-Rh-Co)has been prepared and used as catalyst for hydroformylationof methyl methacrylate. The results showed t...
Four polymer-supported Fe-Co tetrametallic clusters have been prepared by ion exchange and ligand exchange. Their structures were characterized by IR, UV/visible diffuse reflectance spectra and elemental analysis, and...
The cobalt and ruthenium bimetallic complex of poly-γ-amino-propylsiloxane( abbr. as Si-CH_2-Co-Ru) was prepared, and it was found that it can catalyze the hydroformylation of cyclobexene effectively with the convers...
The project is supported by National Natural Science Foundation of China
The polymer-supported cluster FeCo3 (CO)_(12) (μ3-AuPph_2 CH_2) (4) has been synthesized through reaction of CH_2 ph_2 PAuCl with the cluster anion FeCo_3 (CO)_(12)^-. They are characterized through IR spectra, elect...
Polymer Ru-Co bimetallic complexes have been examined by X-ray photoelectron spectroscopy.The catalyst is highly active only when the mole ratio of Co/Ru is 4: 3. The activity of catalysts does not depend on the total...
Six kinds of polymer ligands, supported on SiO_2, containing coordinating atoms P, S and N respectively, have been synthesized. The Ru(Ⅲ)-Co(Ⅱ) bimetallic complexes of these polymer ligands have been obtained and ex...
The project is supported by the National Natural Science Foundation of China.
A series of polymer-supported tetranuclear rhodium carbonyl cluster catalysts were prepared b the reaction of Rh4(CO)12with several kinds of polymer supports such as crosslinked poly (N-vinylpyrrolidone) (PNVP)...