HYDROFORMYLATION

作品数：63被引量：60H指数：4
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Hydroformylation over polyoxometalates supported single-atom Rh catalysts
《National Science Open》2023年第2期161-174,共14页Shixiang Feng Qi Yu Xinbin Ma Xiaohu Yu Ning Yan 
supported by the National Natural Science Foundation of China(92061109 and 22273053);the Natural Science Basic Research Program of Shaanxi(2021JCW-20 and 2022KJXX-18).
Atomic dispersion of Rh on phosphotungstic acid(PTA)salts was achieved by a self-assembled precipitation method using alkali metal ions as coprecipitation reagents.During styrene hydroformylation,the supported Rh sing...
关键词：POLYOXOMETALATES Rh single-atom HYDROFORMYLATION SELF-ASSEMBLY STYRENE 
Organic Ligand-Free Hydroformylation with Rh Particles as Catalyst被引量：1
《Chinese Journal of Chemistry》2020年第2期139-143,共5页Shujuan Liu Xingchao Dai Hongli Wang Xinzhi Wang Feng Shi 
Financial supports from the NSFC(No.21633013);the Cooperation Foundation of Dalian National Laboratory for Clean Energy of CAS(No.DNL201901);the"Light of West China"Program,Fujian Innovation Academy,Key Research Program of Frontier Sciences(No.Q.YZDJ-SSW-SLH051);Strategic Priority Research Program(No.XDA21020700)of the CAS are gratefully acknowledged.
Summary of main observation and conclusion An efficient and organic ligand-free heterogeneous catalytic system for hydroformylation of olefins is highly desirable for both academy and industry.In this study,simple Rh ...
关键词：CATALYST negligible ALDEHYDES 
A theoretical study on the alkene insertion step in Rh-Yanphos catalyzed hydroformylation被引量：2
《Chinese Chemical Letters》2013年第12期1083-1086,共4页Xiao-Jie Du Yan-Hui Tang Xin Zhang Ming Lei 
in part supported by the National Natural Science Foundation of China (Nos. 21072018 and 21203006)
This paper studied the mechanism of the alkene insertion elementary step in the asymmetric hydroformylation （AHF） catalyzed by RhH（CO）2[（R,S）-Yanphos] using four alkene substrates （CH2=CH- Ph, CH2=CH-Ph-（p）-M...
关键词：DFT Hydroformylation Mechanism Alkene insertion Coordination mode 
Hydroformylation of methyl-3-pentenoate over a phosphite ligand modified Rh/SiO_2 catalyst被引量：1
《Journal of Natural Gas Chemistry》2008年第4期351-354,共4页Xianming Li Yunjie Ding Guiping Jiao Jingwei Li Li Yan Hejun Zhu 
supported by the National Key Fundamental Research Development Plan("973"Plan,No.2009CB623503)
A phosphite ligand modified Rh/SiO2 catalyst has been developed for hydroformylation of internal olefins to linear aldehydes, which showed high activity and regioselectivity and could be separated easily by filtration...
关键词：Rh/SiO2 PHOSPHITE HYDROFORMYLATION internal olefins linear aldehydes 
Studies on the Recycling Efficiency of Thermoregulated Phase-separable Rh/PETPP Complex Catalyst被引量：1
《Chinese Chemical Letters》2003年第1期91-93,共3页Yan Hua WANG Fang CHENG Xiao Wei WU Zi Lin JIN 
The financial support of the National Natural Science Foundation of China (grant no. 29906001) and the Research Institute of Petroleum Processing; China Petroleum & Chemical Corporation is gratefully acknowledged.
Effects on the recycling efficiency of thermoregulated phase-separable Rh/PETPP (P-[p-C6H4O(CH2CH2O)nH]3, N=3n) complex catalyst involved in hydroformylation of 1-decene are for the first time presented. It was found...
关键词：Thermoregulated phase-separable catalysis (TPSC) HYDROFORMYLATION nonionic phosphine ligand rhodium. 
HYDROFORMYLATION OF 1-HEXENE WITH Rh_4(CO)_(12) AND [Rh(CO)_2Cl]_2
《分子催化》1989年第S1期1-7,共7页Li Xianjun and Chen Yueqiang (Department of Chemistry, Sichuan University, Chengdu, China)Xie Hui and Chen Yu (Analytical and Testing Center, Sichuan University, Chengdu, China) 
This work was supported by the Science Foundation of Chinese Academy of Sciences
The hydroformylation of hexene-1 catalyzed by Rh4 （CO）12 and 〔Rh（CO）2Cl〕2 andthe effects of solvents （benzene, n-heptane and THF） and PPh3 on the activity...
关键词：ambient benzene catalyzed molar selectivity probably carbonyl MONONUCLEAR MONOXIDE overlapped 
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