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Acknowledgements This work was supported by the National Natural Science Foundation of China (Grant Nos. 21273227 and 21403258) and the Strategic Priority Research Program of the Chinese Academy of Science (Grant Nos XDB 17020400).
Hydroformylation has been widely used in industry to manufacture high value-added aldehydes and alcohols, and is considered as the largest homogenously catalyzed process in industry. However, this process often suffer...
Supported by the National Natural Science Foundation of China(Nos.21373120, 21301098, 21071086, 21271110), the National "111" Project of China's Higher Education(No.B 12015), the Applied Basic Research Programs of Science and Technology Commission Foundation ofTianjin, China(Nos.13JCQNJC02000, 12JCYBJC13100).
TiO2 nanotubes supported amorphous Co-B(Co-B/TNTs) catalyst was prepared via impregnation- chemical reduction procedure. The catalyst was characterized with transmission electron microscopy(TEM), ammonia temperatu...
A series of olefin hydroformylations over supported aqueous-phase rhodium catalyst with the substitUtion of CO/D2 for CO/H2 were cAned out to study the isotope effects of deuterium. The rate of aldehyde formation in C...
Polymer Ru-Co bimetallic complexes have been examined by X-ray photoelectron spectroscopy.The catalyst is highly active only when the mole ratio of Co/Ru is 4: 3. The activity of catalysts does not depend on the total...
Six kinds of polymer ligands, supported on SiO_2, containing coordinating atoms P, S and N respectively, have been synthesized. The Ru(Ⅲ)-Co(Ⅱ) bimetallic complexes of these polymer ligands have been obtained and ex...
The project is supported by the National Natural Science Foundation of China.
A series of polymer-supported tetranuclear rhodium carbonyl cluster catalysts were prepared b the reaction of Rh4(CO)12with several kinds of polymer supports such as crosslinked poly (N-vinylpyrrolidone) (PNVP)...