PHOSPHOTUNGSTATE

作品数:10被引量:17H指数:2
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相关领域:理学更多>>
相关期刊:《Chinese Journal of Chemical Engineering》《Science China Chemistry》《Chinese Journal of Structural Chemistry》《Science Bulletin》更多>>
相关基金:国家自然科学基金河南省自然科学基金更多>>
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Synergic catalysis of W and Ni originating from substitution of trivacant phosphotungstate for the selective oxidation of aniline to azoxybenzene
《Chinese Chemical Letters》2024年第2期558-563,共6页Sheng Cai Xiao-Yuan Wu Weiming Wu Sa-Sa Wang Can-Zhong Lu 
supported by the National Natural Science Foundation of China(Nos.21773247,22275185,21521061,21875252);the Natural Science Foundation of Fujian Province(No.2006L2005).
Partial substitution of polyoxometalate(POM)is an efficient route to modulate the catalytic property of maternal POM.In this work,a new Keggin type POM involving{Ni 6}cluster,{[Ni(H_(2)O)_(2)(Dach)_(2)][Ni(Dach)_(2)]_...
关键词:Polyoxometalate {Ni_(6)}cluster Modulated catalytic property Aniline oxidation AZOXYBENZENE 
Propanetricarboxylic acid ornamented multi-Ce^(Ⅲ) encapsulated phospho(Ⅲ) tungstate and its electrochemical sensing properties被引量:2
《Tungsten》2023年第2期277-285,共9页Bao-Xing Zeng Guo-Ping Liu Yu-Jiao Hao Zhuo Chen Li-Juan Chen Jun-Wei Zhao 
financially supported by the National Natural Science Foundation of China(Grant Nos.21871077,22071042,22171070);the Program for Innovation Teams in Science and Technology in Universities of Henan Province(Grant Nos.20IRTSTHN004)。
A propanetricarboxylic acid ornamented multi-CeⅢencapsulated phospho(Ⅲ)tungstate[H_(2)N(CH_(3))_(2)]_(4)Na_(4)H_(2)[Ce_(4)(HP)W_(4)(H_(2)0)_(14)(H_(2)PTCA)_(2)O_(18)][(HPⅢ)_(2)W_(22)O_(76)]·16H_(2)O(1,H_(3)PTCA=1,...
关键词:POLYOXOMETALATE PHOSPHOTUNGSTATE Rare earth ELECTROCHEMISTRY NORADRENALINE 
An Efficient Extraction-Free Method for Oxidative Desulfurization of Model Fuels Employing Cross-Linked Polyionic Liquid Phosphotungstate Catalysts被引量:2
《China Petroleum Processing & Petrochemical Technology》2022年第3期10-20,共11页Yuan Dandan Zhang Ling Yin Guoqing Wang Yuanyuan Zhang Jiaojing 
supported by the Natural Science Foundation of Heilongjiang Province of China (Grant No. LH2019B025)
An efficient extraction-free oxidative desulfurization(ODS)process using a series of cross-linked polyionic liquid phosphotungstate(CLPIL-PW)catalysts is reported.The cross-linked PILs were prepared with DVB and 1-n-a...
关键词:DESULFURIZATION polyionic liquids(PILs) cross-linking phosphotungstic acid oxidation reaction 
An Organic-inorganic Hybrid Two-dimensional Bilayer Assembled from 1:2-Type[Er(α-PW11O39)2]^11–Moieties and[Cu(dap)2]^2+Linkers被引量:1
《Chinese Journal of Structural Chemistry》2016年第1期39-45,共7页罗婕 宋开放 赵浩哲 赵俊伟 陈利娟 
supported by the Natural Science Foundation of China(21301049,U1304208);the Natural Science Foundation of Henan Province(122300410106)
A new organic-inorganic hybrid phosphotungstate-based Cu^Ⅱ-Er^Ⅲ heterometallic derivative[Cu(dap)2(H2O)][Cu(dap)2]4.5[Er(α-PW11O39)2]·4H2O(1,dap = 1,2-diaminopropane) has been hydrothermally prepared and...
关键词:polyoxometalate heterometallic complex phosphotungstate 
Preparation,Characterization of Dawson-type Heteropoly Acid Cerium(Ⅲ) Salt and Its Catalytic Performance on the Synthesis of n-Butyl Acetate被引量:9
《Chinese Journal of Chemical Engineering》2013年第5期500-506,共7页曹小华 任杰 徐常龙 张康华 占昌朝 蓝健 
Supported by the National Natural Science Foundation of China(21161009);the Natural Science Foundation of Jiangxi Province(20122BAB213001,20114BAB213002);the Science and Technology Foundation of Jiangxi Province(GJJ11613)
A novel cerium(Ⅲ) salt of Dawson type tungstophosphoric acid(Ce2P2W18O62·16H2O) was prepared by doping cerous nitrate in H6P2W18O62·13H2O powder and characterized by thermogravimetry and differential thermal analys...
关键词:cerous phosphotungstate Dawson structure CATALYST ESTERIFICATION n-butyl acetate 
A dicationic ionic liquid-modified phosphotungstate hybrid catalyst for the heterogeneous oxidation of alcohols with H_2O_2被引量:2
《Science China Chemistry》2012年第9期1796-1801,共6页LENG Yan ZHAO PingPing ZHANG MingJue CHEN GuoJian WANG Jun 
supported by the National Natural Science Foundation of China (21136005)
An ionic hybrid catalyst 1,1'-(butane- 1,4-diyl)-bis(3-methylimidazolium) phosphotungstate (abbreviated [Dmimh.sPW) has been prepared by anion-exchange of the divalent ionic liquid (1L) 1,1 '-(butane-1,4-d...
关键词:hybrid catalyst HETEROPOLYACID ionic liquid oxidation of alcohols heterogeneous catalysis 
Epoxidation of olefins with hydrogen peroxide catalyzed by a reusable lacunary-type phosphotungstate catalyst被引量:1
《Science China Chemistry》2011年第5期769-773,共5页HUA Li,QIAO YunXiang,LI Huan,FENG Bo,PAN ZhenYan,YU YinYin,ZHU WenWen & HOU ZhenShan Key Laboratory for Advanced Materials Research Institute of Industrial Catalysis,East China University of Science and Technology,Shanghai 200237,China 
supported by the National Natural Science Foundation of China (20773037, 21073058)
Olefins and allylic alcohols have been epoxidized with commercially available hydrogen peroxide (30% H2O2) using a phase transfer catalyst,composed of cetyltrimethylammonium cations and a lacunary-type phosphotungstat...
关键词:heteropolyphosphotungstate lacunary EPOXIDATION degradation rate 
A Novel Composite Based On Phosphotungstate Anion [n-Bu4N][Cu(2,2-bipy)_3][PW_(12)O_(40)]·CH_3CN·H_2O
《Chinese Journal of Structural Chemistry》2008年第1期53-56,共4页周大鹏 王凯华 王敬平 
Supported by the Natural Science Foundation of Henan Province (No. 0611011900);Program for New Century Excellent Talents in Universities of Henan Province
A novel composite, [C16H36N][Cu(2,2-bipy)3][PW12O40]·CH3CN·H2O based on Keggin-type phosphotungstate, has been synthesized in acetonitrile at moderate temperature and then characterized by IR and single-crystal X-...
关键词:crystal structure POLYOXOMETALATE Keggin type 
Study on the Synthesis of Octyl Acetate by Phosphotungstate Heteropolyacid with Keggin Structure
《复旦学报(自然科学版)》2007年第5期769-,775,共2页Han Jie-li, Li Hai-feng, Wang Zi-wei, Wu Chuan, Ren Jian-guo(School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006,China) 
1 Results Octyl Acetate is an important chemical material.It is widely used as solvent in many industries,such as plasterer,artificial leather,and lacquer varnish,spice and medicine industries.At the present time,it i...
关键词:octyl acetate phosphotungstate heteropolyacid Kaggin Structure 
THE SYNTHESIS AND STRUCTURE OF BI-VACANT D AWSON PHOSPHOTUNGSTATE K_(10)Na_2H_2P_2W_(16)O_(60)·18H_2O
《Chinese Science Bulletin》1992年第5期387-390,共4页吴新国 蒋安仁 
The conclusion has been made that mono- and tri-vacant Dawson phosphotungstates (shown as P2W17 and P2W15)exist. The bi-vacant Dawson phosphotungstate (P2W16...
关键词:DAWSON STRUCTURE vacant HETEROPOLY ACID PHOSPHOTUNGSTATE 
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