supported by the National Natural Science Foundation of China(Nos.21773247,22275185,21521061,21875252);the Natural Science Foundation of Fujian Province(No.2006L2005).
Partial substitution of polyoxometalate(POM)is an efficient route to modulate the catalytic property of maternal POM.In this work,a new Keggin type POM involving{Ni 6}cluster,{[Ni(H_(2)O)_(2)(Dach)_(2)][Ni(Dach)_(2)]_...
financially supported by the National Natural Science Foundation of China(Grant Nos.21871077,22071042,22171070);the Program for Innovation Teams in Science and Technology in Universities of Henan Province(Grant Nos.20IRTSTHN004)。
A propanetricarboxylic acid ornamented multi-CeⅢencapsulated phospho(Ⅲ)tungstate[H_(2)N(CH_(3))_(2)]_(4)Na_(4)H_(2)[Ce_(4)(HP)W_(4)(H_(2)0)_(14)(H_(2)PTCA)_(2)O_(18)][(HPⅢ)_(2)W_(22)O_(76)]·16H_(2)O(1,H_(3)PTCA=1,...
supported by the Natural Science Foundation of Heilongjiang Province of China (Grant No. LH2019B025)
An efficient extraction-free oxidative desulfurization(ODS)process using a series of cross-linked polyionic liquid phosphotungstate(CLPIL-PW)catalysts is reported.The cross-linked PILs were prepared with DVB and 1-n-a...
supported by the Natural Science Foundation of China(21301049,U1304208);the Natural Science Foundation of Henan Province(122300410106)
A new organic-inorganic hybrid phosphotungstate-based Cu^Ⅱ-Er^Ⅲ heterometallic derivative[Cu(dap)2(H2O)][Cu(dap)2]4.5[Er(α-PW11O39)2]·4H2O(1,dap = 1,2-diaminopropane) has been hydrothermally prepared and...
Supported by the National Natural Science Foundation of China(21161009);the Natural Science Foundation of Jiangxi Province(20122BAB213001,20114BAB213002);the Science and Technology Foundation of Jiangxi Province(GJJ11613)
A novel cerium(Ⅲ) salt of Dawson type tungstophosphoric acid(Ce2P2W18O62·16H2O) was prepared by doping cerous nitrate in H6P2W18O62·13H2O powder and characterized by thermogravimetry and differential thermal analys...
supported by the National Natural Science Foundation of China (21136005)
An ionic hybrid catalyst 1,1'-(butane- 1,4-diyl)-bis(3-methylimidazolium) phosphotungstate (abbreviated [Dmimh.sPW) has been prepared by anion-exchange of the divalent ionic liquid (1L) 1,1 '-(butane-1,4-d...
supported by the National Natural Science Foundation of China (20773037, 21073058)
Olefins and allylic alcohols have been epoxidized with commercially available hydrogen peroxide (30% H2O2) using a phase transfer catalyst,composed of cetyltrimethylammonium cations and a lacunary-type phosphotungstat...
Supported by the Natural Science Foundation of Henan Province (No. 0611011900);Program for New Century Excellent Talents in Universities of Henan Province
A novel composite, [C16H36N][Cu(2,2-bipy)3][PW12O40]·CH3CN·H2O based on Keggin-type phosphotungstate, has been synthesized in acetonitrile at moderate temperature and then characterized by IR and single-crystal X-...
1 Results Octyl Acetate is an important chemical material.It is widely used as solvent in many industries,such as plasterer,artificial leather,and lacquer varnish,spice and medicine industries.At the present time,it i...
The conclusion has been made that mono- and tri-vacant Dawson phosphotungstates (shown as P2W17 and P2W15)exist. The bi-vacant Dawson phosphotungstate (P2W16...