METALLOFULLERENES

作品数：9被引量：1H指数：1
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相关领域：理学更多>>
相关作者：廉永福郝健梁希慧更多>>
相关机构：黑龙江大学更多>>
相关期刊：《Chinese Physics B》《Science China Chemistry》《Chinese Journal of Structural Chemistry》《Science Bulletin》更多>>
相关基金：国家自然科学基金国家重点基础研究发展计划更多>>
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ScY@C_(3v)(8)-C_(82):Metal-Metalσ^(2)Bond in Mixed Rare-Earth Di-metallofullerenes
《Chinese Journal of Chemistry》2023年第15期1809-1814,共6页Lihao Zheng Yannick Roselló Yingjing Yan Yang-Rong Yao Xiaolin Fan Josep M.Poblet Antonio Rodríguez-Fortea Ning Chen 
the National Science Foundation China(NSFC No.52172051);the NSF of Jiangsu Province(BK20200041);the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD);A.R.-F.and J.M.P.thank the Spanish Ministry of Science(grant PID2020-112762GB-I00 funded by MCIN/AEl/10.13039/501100011033);the Generalitat de Catalunya(grant 2021 SGR 00110)and the URV for support.
Comprehensive Summary The experimental investigation of rare-earth metal-metal bonds remains a challenge in the study of chemical bonds.Herein,we report the synthesis and characterization of a novel heteronuclear di-m...
关键词：FULLERENES Endohedral fullerenes Rare earths Densityfunctional calculations Metal-metal bond 
Studies on the Luminescence Property of Yttrium-Based Metallofullerenes
《Chinese Journal of Structural Chemistry》2022年第9期1-7,共7页Jiayi Liang Chunru Wang Taishan Wang 
National Natural Science Foundation of China(52022098,51972309,51832008);Youth Innovation Promotion Association of Chinese Academy of Sciences(Y201910)。
Endohedral metallofullerenes(EMFs) exhibit various properties due to their multiple combinations between internal metals and outer carbon cages. Among them, yttrium-based metallofullerenes have attracted much attentio...
关键词：METALLOFULLERENES YTTRIUM LUMINESCENCE thermally activated delayed fluorescence PHOSPHORESCENCE 
Highly delocalized endohedral metal in Gd@C2v（9）-C82 metallofullerenes co-crystallized with α-Se
《Nano Research》2018年第4期2277-2284,共8页Cheng Li Xuejiao J. Gao Huanli Yao Huan Huang Rongli Cui Xihong Guo Lele Zhang Bing Liu Binggang Xu Weiqun Shi Jinquan Dong Lai Feng Xingfa Gao Baoyun Sun 
This work was financially supported by the National Basic Research Program of China （No. 2016YFA0203200） and the National Natural Science Foundation of China （Nos. 51372158, 21402202, 11505191 and U1632113）.
A new Gd@C2v（9）-C82·2.5（S8）·0.5（CS2） co-crystal was prepared for the first time and characterized by single-crystal X-ray diffraction （XRD）. The analysis dearly showed that, even though the C2v（9）-C82 cage...
关键词：METALLOFULLERENES sulfur structure elucidation DELOCALIZATION density functional theory（DFT） calculations 
Identification of the Most Stable Sc2C80 Isomers： Structure, Electronic Property, and Molecular Spectra Investigations
《Chinese Journal of Chemistry》2012年第4期765-770,共6页吴静怡 王太山 舒春英 吕鑫 王春儒 
A systematic density functional theory investigation has been carried out to explore the possible structures of Sc2C80 at the BMK/6-31 G（d） level. The results clearly show that Sc2@C80-Ih, Sc2@Cso-Dsh, and Sc2C2@C78...
关键词：METALLOFULLERENES density functional theory relative energy HOMO-LUMO gap 
Ab initio investigations of the charge transport properties of endohedral M@C_(20)(M=Na and K)metallofullerenes被引量：1
《Chinese Physics B》2010年第11期330-335,共6页安义鹏 杨传路 王美山 马晓光 王德华 
Project supported by the National Natural Science Foundation of China (Grant Nos. 10674114 and 10974078)
Using density functional theory and quantum transport calculations based on nonequilibum Green＇s function formalism, we investigate the charge transport properties of endohedral M@C20（M = Na and K） metallofullerene...
关键词：M@C20 metallofullerenes electronic transport density functional theory nonequilibum Green＇s function 
Formation of substitutional metallofullerenes by laser ablation of externally doped fullerenes C_(60)M_x(M=Sm,Pt,Ni and Rh)
《Chinese Science Bulletin》2002年第4期284-291,共8页KONG Qingyu, SHEN Yifeng, ZHUANG Jun, ZHAO Li, QIAN Shixiong, LI Yufen, LI Xu, LIN Yanghui & CAI RuifangDepartment of Physics, Fudan University, Shanghai 200433, China State Key Joint Laboratory for Materials Modification by Laser, Ion and Electro 
This work was supported by the National Natural Science Foundation of China (Grant No. Project 29890216).
Photofragmentation study of metal fullerides C60Mx (M=Sm, Pt, Ni and Rh) by excimer laser ablation-TOF mass spectrometry shows that metallofullerenes C2nM and C2n+1M formed in both the positive and negative ionic mode...
关键词：TOF-MS laser ablation SUBSTITUTIONAL METALLOFULLERENES odd-numbered high carbon clusters. 
Intensity Exaggeration of Endohedral Metallofullerenes in Laser Desorption-Ionization Time-of-Flight Mass Spectrometry
《Chinese Chemical Letters》1998年第8期761-764,共4页Da Yong SUN Wen Guo XU and Shu Ying LIU(The No. 9 Laboratory, Changchun Institute of Applied Chemistry,Chinese Academy of Sciences, Changchun 130022) 
The laser-desorption-ionization time-of-flight mass spectrometry and desorption-electron-ionization mass spectrometry were employed for the characterization of metallofullerenes extract. it was found that the relative...
关键词：METALLOFULLERENES LD-TOF MS 
Electronic structure and fluorescent property of endohedral terbium fullerenes
《Chinese Science Bulletin》1997年第21期1798-1802,共5页Sun, DY Liu, ZY Guo, XH Xu, WG Liu, SY 
ENDOHEDRAL metallofullerencs is the important part of modern fullerene science research.From the first determination of La@C2n, in laser mass spectrometry till now, great progresshas been made in this field...
关键词：METALLOFULLERENES TERBIUM XPS FLUORESCENT spectroscopy. 
Studies on extracting solutions of endohedral rare-earth metallofullerenes by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry
《Science China Chemistry》1997年第6期590-599,共10页孙大勇 刘志强 刘子阳 郭兴华 徐文国 刘淑莹 
Project supported by the National Natural Science Foundation of China
Thirteen extracting solutions of rare-earth metallofullerenes containing La,Ce,Pr,Nd Sm,Eu,Gd,Tb,Dy,Ho,Er,Tm and Yb respectively have been investigated by means of matrix-assisted laser desorpuon/ ionization time-of-f...
关键词：METALLOFULLERENES FULLERENES laser desorption/ionization TIME-OF-FLIGHT mass SPECTROMETRY 
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