Herein the use of rare-earth compounds in catalytic reduction systems for the end-group functionalization of carboxyl-terminated low-molecularweight fluoropolymers was explored.Leveraging the high catalytic activity a...
financially supported by the National Natural Science Foundation of China(Nos.22231008 and 22071167);the Natural Science Foundation of Jiangsu Higher Education Institutions of China(No.22KJA150005);a project funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions。
Nuclear magnetic resonance(NMR)is an advanced technique for the molecular weight(MW)determination of polymers at quantitative conditions.In this study,we investigate the effect of liquid^(1)H-NMR instrumental setting ...
the financial support fromtheNSFC(21975055,U2001222,52103352,52120105006,and 51925306);National Key R&D Program of China(2018FYA 0305800);Key Research Program of Chinese Academy of Sciences(XDPB08-2);the Youth Innovation Promotion Association of Chinese Academy of Sciences(2022165);the Fundamental Research Funds for the Central Universities.DFT results described in this article were obtained from the National Supercomputing Centre in Shenzhen(Shenzhen Cloud Computing Centre).
By employing the asymmetric end-group engineering,an asymmetric nonfused-ring electron acceptor(NFREA)was designed and synthesized.Compared with the symmetric analogs(NoCA-17 and NoCA-18),NoCA-19 possesses broader lig...
supported by the National Key R&D Program of China (2021YFB3801904);the National Natural Science Foundation of China (U19A2095);the Institutional Research Fund from Sichuan University (2020SCUNL205);the Fundamental Research Funds for the Central Universities;the 111 Project (B20001)。
A chemically closed-loop-recyclable biodegradable polymer,poly(p-dioxanone)(PPDO),is one of the ideal candidates for single-use plastic products due to its suitability for different application scenarios.Fascinatingly...
financially supported by the National Natural Science Foundation of China (22279152,U21A20331);the National Science Fund for Distinguished Young Scholars (21925506);the Ningbo key scientific and technological project (2022Z117);the Ningbo Natural Science Foundation (2021J192)。
Phenazine-based non-fullerene acceptors(NFAs)have demonstrated great potential in improving the power conversion efficiency(PCE)of organic solar cells(OSCs).Halogenation is known to be an effective strategy for increa...
supported by National Key Research&Development Program(No.2021YFB3800603);National Natural Science Foundation of China(No.92066208);Shenzhen Science and Technology Program(Nos.KQTD20180411143514543,JCYJ20180504165831308);Guangdong Natural Science Foundation(No.2020A1515011043).
Although many dielectric polymers exhibit high energy storage density(Ue)with enhanced dipolar polarization at room temperature,the substantially increased electric conduction loss at high applied electric fields and ...
supported by The National Natural Science Foundation of China(21504039)。
Recyclable polymers offer a great opportunity to address the environmental issues of plastics.Herein,functionalization of recyclable polymers,poly((R)-3,4-trans six-membered ring-fused GBL)(P((R)-M)),were reported via...
This work was supported by the National Natural Science Foundation of China(Project U1704150);the Scientific and Technological Projects of Henan Province(182102410017).
In this study,we describe a simple synthesis route to prepare triblock copolymers with disulfide-linkers,poly(ethylene glycol)-SS-poly(ε-caprolactone)-SS-poly(ethylene glycol)(PEG-SS-PCL-SS-PEG)for application in the...
Six grades of biopolymers formulated to have oil content of 40% (M1), 50% (M2), and 60% (M3) melon seed oil (MESO) and 40% (C1), 50% (C2), and 60% (C3) cottonseed oil (COSO) respectively, were prepared with phthalic a...
supported by the National Natural Science Foundation of China(21274065,20804020,21001065);National Basic Research Program of China(2009CB930601);Natural Science Foundation of Jiangsu Province(BK2011751);A project funded by the priority academic program development of Jiangsu higher education institutions,and Scientific Re-search Foundation of Nanjing University of Posts and Telecommunications(NY210017,NY210046)
Semi-empirical AM1 and ZINDO/S,as well as density function theory(DFT)method B3LYP/6-31G(d)quantum chemical calculations were carried out to study the electronic structures and optical properties of poly(p-phenylene v...