STEREOSELECTIVITY

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相关机构：中国人民解放军白求恩国际和平医院北京大学华东理工大学西南大学更多>>
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Iron Catalyzed Isomerization of a-Alkyl Styrenes to Access Trisubstituted Alkenes被引量：3
《Chinese Journal of Chemistry》2021年第3期585-589,共5页Songgen Xu Guixia Liu Zheng Huang 
the National Natural Science Foundation of China(Nos.21825109,21821002,21732006);the National Basic Research Program of China(No.2016YFA0202900);the Strategic Priority Research Program of Chinese Academy of Sciences(No.XDB20000000);the Chinese Academy of Sciences Key Research Program of Frontier Sciences(No.QYZDB-SSW-SLH016);the K.C.Wong Education Foundation,and the Science and Technology Commission of Shanghai Municipality(No.17JC1401200)is gratefully acknowledged.
Main observation and conclusion Stereoselective isomerization of a-alkyl styrenes is accomplished using a new iron catalyst supported by phosphine-pyridine-oxazoline(PPO)ligand.The protocol provides an atom-efficient ...
关键词：CATALYSIS IRON lsomerization Trisubstituted alkenes STEREOSELECTIVITY 
Biosynthesis of clinically used antibiotic fusidic acid and identification of two short-chain dehydrogenase/reductases with converse stereoselectivity被引量：4
《Acta Pharmaceutica Sinica B》2019年第2期433-442,共10页Zhiqin Cao Shaoyang Li Jianming Lv Hao Gao Guodong Chen Takayoshi Awakawa Ikuro Abe Xinsheng Yao Dan Hu 
supported by grants from the National Natural Science Foundation of China(31870032,3171101305,and 31670036);the 111 Project of Ministry of Education of the People's Republic of China(B13038);the JST/NSFC Strategic International Collaborative Research Program;Japanese-Chinese Collaborative Research Program;Chang Jiang Scholars Program(Hao Gao,2017)from the Ministry of Education of China;Guangdong Special Support Program(2016TX03R280);Guangdong Province Universities and Colleges Pearl River Scholar Funded Scheme(Hao Gao,2014);K.C.Wong Education Foundation(Hao Gao,2016);Guangzhou Science and Technology Project(201707010266,China);the Fundamental Research Funds for the Central Universities(21617495);Kobayashi International Scholarship Foundation;a Grant-in-Aid for Scientific Research from the Ministry of Education,Culture,Sports,Science and Technology,Japan(JSPS KAKENHI Grant Number JP15H01836 and JP16H06443)
Fusidic acid is the only fusidane-type antibiotic that has been clinically used. However,biosynthesis of this important molecule in fungi is poorly understood. We have recently elucidated the biosynthesis of fusidane-...
关键词：BIOSYNTHESIS FUNGI Fusidic acid Fusidane-type ANTIBIOTICS SDR 
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