supported by the National Natural Science Foundation of China(No.22071025);the Joint Independent Innovation Fund of Tianjin University and Fuzhou University(No.TF2021-3);the Young and Middle-aged Teacher Education Research Project of Fujian Province(No.JAT210020)。
Two o-carborane based tetraphenylethene(TPE)cationic cyclophanes O1.4PF_(6)and O2.4PF_(6)were syn thesized through an S_(N)2 reaction.Their structures were confirmed both possessing Z-shaped cavities in single crystal...
funding from the Natural Science Foundation of China (Nos. 22072084, 21820102005);111 Project (No. B14041);the Fundamental Research Funds for the Central Universities (Nos. GK202103048, GK202001005, 2020CSLY008);the Innovation Capability Support Program of Shaanxi (No. 2021TD-18)
Based on three rationally designed pyrrole-appended o-carborane derivatives,we present that fluores-cence properties of crystalline materials are highly dependent on intermolecular interaction and steric hinderance.Th...
financial support from the National Natural Science Foundation of China(Nos.21672193,21272218);the Key Scientific and Technological Project of Henan Province(No.202102310327);the Ministry of Industry and Information Technology(No.Z135060009002);the Postdoctoral Research Grant in Henan Province(No.001803004);the Programme of Introducing Talents of Discipline to Universities(111 Project,No.D20003);Zhengzhou University of China。
A facile access to mono-C-alkynyl-o-carboranes from o-carboranes and arylsulfonylacetylenes was developed.This facile process tolerates a wide variety of functional groups,occurs at mild conditions in onepot procedure...
the National Natural Science Foundation of China(Nos.21672193,21272218);Ministry of Industry and Information Technology of the People's Republic of China(No.Z135060009002);111 Project(No.D20003);Zhengzhou University of China for financial support of this research。
A simple method to synthesize luminescent λ^(5)-phosphanaphthalenes and zwitterionic nido-carborane fused six-membered phosphacycles was developed from the reaction of ortho-phosphinobenzoaldehydes or ortho-phosphino...
supported by a grant from the Research Grants Council of the Hong Kong Special Administration Region (No. 14305918)
How long a C-C bond can be?A question has long fascinated chemists.This work reports an example of extraordinary long C-C bond distance of 1.990(4)?observed in single-crystal X-ray structure of 1,2-(NHMes)2-o-carboran...