O-CARBORANE

作品数：21被引量：6H指数：1
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相关领域：理学更多>>
相关作者：苗金玲聂永卞德乾更多>>
相关机构：济南大学福州大学更多>>
相关期刊：《聊城大学学报（自然科学版）》《Organic Chemistry Frontiers》《Science China Chemistry》《Chinese Journal of Structural Chemistry》更多>>
相关基金：国家自然科学基金高等学校学科创新引智计划国家重点基础研究发展计划山东省自然科学基金更多>>
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Synthesis and properties of tetraphenylethene cationic cyclophanes based on o-carborane skeleton
《Chinese Chemical Letters》2024年第12期440-447,共8页Rongjian Chen Jiahui Liu Caixia Lin Yuanming Li Yanhou Geng Yaofeng Yuan 
supported by the National Natural Science Foundation of China(No.22071025);the Joint Independent Innovation Fund of Tianjin University and Fuzhou University(No.TF2021-3);the Young and Middle-aged Teacher Education Research Project of Fujian Province(No.JAT210020)。
Two o-carborane based tetraphenylethene(TPE)cationic cyclophanes O1.4PF_(6)and O2.4PF_(6)were syn thesized through an S_(N)2 reaction.Their structures were confirmed both possessing Z-shaped cavities in single crystal...
关键词：O-CARBORANE Tetraphenylethene Cationic cyclophanes NUCLEOTIDES AIE effect 
Bi-ortho-Carborane Unit-Riveted Perylene Monoimides:Structure-Tuned Optical Switches for Electron Transfer and Robust Thin Film-Based Fluorescence Sensors
《CCS Chemistry》2023年第12期2922-2932,共11页Nannan Ding Yu-Chan Liao Gang Wang Kai-Hsin Chang Zhaolong Wang Ke Liu Jiani Ma Pi-Tai Chou Yu Fang 
the Ministry of Science and Technology of China(grant nos.SQ2022YFA1200081 and 2022010133);the National Natural Science Foundation of China(grant nos.21820102005 and 22132002);111 project(grant no.B14041).
Innovative design of sensing fluorophores possessing superior photophysical properties,porosity,and packing-resistance structures is pivotal for high performance film-based fluorescent sensors.Herein,PDCB,a perylene m...
关键词：perylene monoimide O-CARBORANE excited-state charge transfer fluorescent film sensors ACETONE 
Nickel-catalyzed regioselective B(3,4,5,6)-H tetra-alkylation of o-carboranes
《Science China Chemistry》2023年第10期2836-2841,共6页Jianwei Zhao Zuowei Xie 
supported by the Research Grants Council of the Hong Kong Special Administration Region (SRFS20214S05)。
Though transition metal-catalyzed cage BH methylation has been well documented, catalytic alkylation of cage BH bonds remained elusive because transition metal alkyl complexes are prone to undergo β-H elimination. We...
关键词：nickel catalysis B-H activation CARBORANE ALKYLATION regioselectivity 
Octanuclear Palladacycles with B(3)-H Bond Activation of o-Carborane
《Chinese Journal of Chemistry》2023年第3期307-313,共7页Run-Ze Yuan Peng-Fei Cui Yue-Jian Lin Guo-Xin Jin 
supported by the National Natural Science Foundation of China (Nos.22031003,21720102004);the Shanghai Science Technology Committee (No.19DZ2270100).
Herein,we describe the synthesis of a carborane-supported octanuclear palladacycle complex,Pd_(8)(o-C_(2)B_(10)H_(10)CS_(2)CH_(3))_(4)Cl_(4)(CH_(3)CN)_(4)(complex 1),with B(3)-H activations on o-carborane ligand.The s...
关键词：CARBORANE Palladacycle Regioselective B-H activation Polynuclear complex Dithioester chemistry 
Structure-fluorescence relationships in pyrrole appended o-carborane crystalline materials
《Chinese Chemical Letters》2022年第5期2532-2536,共5页Dan Wang Gang Wang Ke Liu Jing Li Zhaolong Wang Jing Liu Liping Ding Rong Miao Yu Fang 
funding from the Natural Science Foundation of China (Nos. 22072084, 21820102005);111 Project (No. B14041);the Fundamental Research Funds for the Central Universities (Nos. GK202103048, GK202001005, 2020CSLY008);the Innovation Capability Support Program of Shaanxi (No. 2021TD-18)
Based on three rationally designed pyrrole-appended o-carborane derivatives,we present that fluores-cence properties of crystalline materials are highly dependent on intermolecular interaction and steric hinderance.Th...
关键词：FLUORESCENCE o-Carborane crystal Steric hinderance Molecular packing Temperature sensing 
Regioselectivity of Pd-catalyzed o-carboranearylation: a theoretical view
《Organic Chemistry Frontiers》2022年第6期1686-1695,共10页Jiying Liu Dongmin Fu Zitong Chen Tiantian Li Ling-Bo Qu Shi-Jun Li Wenjing Zhang Yu Lan 
supported by the National Natural Science Foundation of China(Grants 21903071);the Program for Science Technology Innovation Talents in Universities of Henan Province(No.20HASTIT004).
The mechanism and the regioselectivity of Pd-catalyzed B(4)–H arylation and B(4,5)–H diarylation foro-carborane with bidentate directing groups were investigated. The complete catalytic cycle involves Pdmediated con...
关键词：ELIMINATION CATALYZED REDUCTIVE 
A facile access to mono-C-alkynylated-o-carboranes from o-carboranes and arylsulfonylacetylenes
《Chinese Chemical Letters》2022年第1期201-204,共4页Mengyang Bai Guanyu Tao Zhenxing Liu Lili Wang Zheng Duan 
financial support from the National Natural Science Foundation of China(Nos.21672193,21272218);the Key Scientific and Technological Project of Henan Province(No.202102310327);the Ministry of Industry and Information Technology(No.Z135060009002);the Postdoctoral Research Grant in Henan Province(No.001803004);the Programme of Introducing Talents of Discipline to Universities(111 Project,No.D20003);Zhengzhou University of China。
A facile access to mono-C-alkynyl-o-carboranes from o-carboranes and arylsulfonylacetylenes was developed.This facile process tolerates a wide variety of functional groups,occurs at mild conditions in onepot procedure...
关键词：ALKYNYLATION O-CARBORANE Arylsulfonylacetylene Transition-metal-free 1 2-Difunctionalized o-carborane 
Rational design for thermochromic luminescence in amorphous polystyrene films with bis-o-carborane-substituted enhanced conjugated molecule having aggregation-induced luminochromism
《Aggregate》2021年第5期171-178,共8页Keisuke Wada Kazushi Hashimoto Junki Ochi Kazuo Tanaka Yoshiki Chujo 
Nakatani Foundation;Ministry of Education,Culture,Sports,Science,and Technology,Japan for Scientific Research,Grant/Award Number:JP21H02001;ScientificResearch on Innovative Areas“New Polymeric Materials Based on Element-Blocks”,Grant/Award Numbers:No.2401,JP24102013。
We designed the triad molecule,bis-o-carborane-substituted bis(thienylethynyl)benzene,as a filler for realizing thermochromic luminescent behaviors based on conventional polymer films,such as polystyrene.From the opti...
关键词：CARBORANE LUMINESCENCE POLYSTYRENE THERMOCHROMISM 
N-Heterocyclic Carbenes with a Nido-C_(2)B_(9) Carborane Backbone被引量：1
《Chinese Journal of Chemistry》2021年第9期2410-2416,共7页Zhongzheng Cui Beining Wang Junxia Li Ronglin Pang Yanrui Kang Xu-Qiong Xiao 
support from the National Natural Science Foundation of China(Grant No.21771048);the Natural Science Foundation of Zhejiang Provinee(Grant No.LY17B010002).
The steric and electronic properties of A/-heterocyclic carbenes(NHCs)can be modified by the exocyclic substituents at the nitrogen atoms,by 1-3 atoms'replacements of the five-membered imidazolium skeleton and by the ...
关键词：CARBORANES nido-Carborane anion Carbene ligands Density functional calculations Gold 
Synthesis of phosphanaphthalenes and nido-carborane fused six-membered phosphacycles
《Chinese Chemical Letters》2021年第1期194-197,共4页Guanyu Tao Feichao Yang Lujun Zhang Yang Li Zheng Duan François Mathey 
the National Natural Science Foundation of China(Nos.21672193,21272218);Ministry of Industry and Information Technology of the People's Republic of China(No.Z135060009002);111 Project(No.D20003);Zhengzhou University of China for financial support of this research。
A simple method to synthesize luminescent λ^(5)-phosphanaphthalenes and zwitterionic nido-carborane fused six-membered phosphacycles was developed from the reaction of ortho-phosphinobenzoaldehydes or ortho-phosphino...
关键词：PHOSPHORUS λ^(5)-Phosphanaphthalenes ZWITTERIONIC nido-Carborane Electron-deficient alkyne 
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