supported by the NSF of China(21827813,21921001,22075283);Scientific Research Fund of Natural Science Foundation of Fujian Province(2020J01115);the Youth Innovation Promotion Association of CAS(No.20200303)。
A new quaternary metal thiophosphate,Cs_(2)Ga_(3)PS_(8),in triclinic P1^(-) space group has been successfully synthesized by a reactive-flux method.Its structural framework is derived from well-known AM^(Ⅲ)M^(Ⅳ)Q_(4...
the financial support by the NSF of China(21701176);the National Postdoctoral Program for Innovative Talents(BX201600163);the China Postdoctoral Science Foundation(2016M600510)
A new quaternary thiophosphate Rb_2FeP_2S_6 was synthesized by the alkali metal halide flux method.The compound crystallizes in the monoclinic space group P2_1/c(No.14) with a = 6.042(3),b = 12.338(6),c = 9.045...