supported by the National Natural Science Foundation of China (Nos. 20471026 and 20771054);the Henan Tackle Key Problem of Science and Technology (No. 0524220001)
A new dinuclear copper(Ⅱ) complex with imino nitroxide radicals [Cu2(NO3)2(IM- 1 ′-MeBzIm)2(dca)2] (IM-1 ′-MeBzIm = 2-{2′-[(1′-methyl)benzimidazolyl]}-4,4,5,5-tetramethylimidazoline-1-oxyl, dca = dicya...
The work was supported by the Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces (No. 0506) and the University of Malaya (F0712/2005c)
The title compound, [Cu2(CH3COO)4(C8H10N2)]n·nCH3CN 1 (C8H10N2, 4,4'-bipy = 4,4'-bipyridine), has been solvothermally synthesized in CH3CN and characterized by X-ray diffraction. The crystal is of monoclinic,...
The reaction between [Cu2(m-dppm)2(MeCN)4](ClO4)2(dppm = bis(diphenylphos- phino)methane) and [Zn(PhS)2(bpy)] (bpy = 2,2-bipyridine, PhS = benzenethiolate) gave the complex [Cu2(m-dppm)2(m-PhS)(MeCN)]ClO40.5(Et2O)(C58...
This work was supported by the National Natural Science Foundation of China (No. 20271029)
A new dicopper(II) compound with oxalate and reduced imino nitroxide radicals [Cu2(m-C2O4)(Him2-py)2(H2O)2](NO3)2 (Him2-py=1-hydroxy-2-(2-pyridyl)-4,4,5,5-tetramethyli- midazoline) has been synthesized and its crystal...
The title complex [Cu2(-dppm)2(-Et2dtc)](ClO4)EtOH0.25H2O (dppm = bis- (diphenylphosphino)methane, Et2dtc = diethyldithiocarbamate) has been synthesized and characterized by single-crystal X-ray diffraction analysis. ...
This work was supported by NNSFC(No.20171044and2023074); the project for "Hundred Talents" from the Chinese Academy of Sciences
Self-organization of copper (I) ion with bridging ligand bis(diphenylphosphino)-acetylene resulted in the isolation of a dinuclear copper ( I ) complex [Cu2(μ-Ph2PC≡ CPPh2)3(MeCN)2](ClO4)2·Et2O. Structural analysis...
Reaction of Cu with dibenzovi peroxide, 2-aminothiazol gave a binuclear complex [Cu_2 (C_6H_5COO)_4(C_3H_4N_2S)_2]. Crystal of the title compound is monoclinic system space group P2_1/n , M_r = 807. 84 with cell param...