REACTIVITIES

作品数:34被引量:26H指数:3
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相关领域:理学更多>>
相关作者:解春松钟素红龚学庆卢冠忠更多>>
相关机构:杭州师范大学南开大学大连民族学院光电子技术研究所华东理工大学更多>>
相关期刊:《Chinese Journal of Structural Chemistry》《Science Bulletin》《Chinese Journal of Catalysis》《中国科学:化学》更多>>
相关基金:国家自然科学基金The Royal Society中国博士后科学基金更多>>
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Unorthodox chemistry for an unorthodox challenge:Exploration of new chemical reactivities for a sustainable future被引量:1
《Science China Chemistry》2011年第12期1815-1830,共16页LI Chao-Jun 
the Canada Research Chair (Tier I) foundation;the E. B. Eddy Endowment Fund;the CFI, NSERC, FQRNT;the NSF and the NSF-EPA Joint Program for a Sustainable Environment for partial support of our research over the years
The sustainable development of our future represents an unorthodox challenge in sciences and technologies.The exploration of unconventional chemical reactivities that could potentially result in more sustainable chemi...
关键词:green chemistry organometallic reactions in water aldehyde-alkyne-amine coupling cross-dehydrogenative-coupling 
Reactivities of d^0 transition metal complexes toward oxygen:Synthetic and mechanistic studies被引量:2
《Science China Chemistry》2009年第11期1723-1733,共11页CHEN ShuJian ZHANG XinHao LIN ZhenYang WU YunDong XUE ZiLing 
Supported by the U.S. National Science Foundation (CHE-051692), Research Grants Council of Hong Kong and the British Royal Society Kan Tong Po Visiting Professorship Program
Transition metals such as Fe in porphyrin complexes are known to bind or react with O2,and such reactions are critical to many biological functions and catalytic oxidation using O2.The transition metals in these react...
关键词:OXYGEN AMIDE metal oxide GATE INSULATOR THEORETICAL study 
Synthesis and characterization of poly(pyrazolyl)borate tantalum amide complexes and their reactivities toward oxygen被引量:2
《Science China Chemistry》2009年第10期1583-1589,共7页CHEN ShuJian Glenn P.A.YAP XUE ZiLing 
Supported by the US National Science Foundation (CHE-051692)
Reaction of TaCl(NMe2)4 (1) with KTp* [Tp* = tris(3,5-dimethylpyrazolyl)borohydride] yields two products: Tp*Ta(NMe2)4 (2), in which one N atom of the Tp* ligand binds to Ta, and [Tp*Ta(NMe2)4]· 2KTp* (3) where three...
关键词:polypyrazolyborate TANTALUM AMIDE OXYGEN 
Relative reactivities of halogen-substituted substrates (R-Br,R-C1) toward the halophilic attack by a carbanion
《Science China Chemistry》2001年第4期337-343,共7页傅伟敏 张晓军 蒋锡夔 
Relative reactivities of bromine-substituted substrates (R-Br) or chlorine-substituted substrates (R-CI) toward bromophilic or chlorophilic attack by a carbanion have been evaluated by the intermolecular competition k...
关键词:relative reactivities halogen-substituted substrates relative rates of halophilic attacks intermolecular competition kinetics 
Syntheses, characterization and catalytic reactivities of heteropolyanion-pillared clay of anions of Zn-Al type被引量:1
《Science China Chemistry》1996年第1期86-94,共9页刘彦勇 胡长文 王作屏 张继余 王恩波 
Project supported by the National Natural Science Foundation of China
Mono-substituted Keggin ions PW11O39Cr(H2O)4 , PW11TiO403 and PW11VO404 were intercalated between the layers of the clay of anions of Zn-Al type using the ion exchange method to obtain a new type of pillared layered m...
关键词:beteropolyanions PILLARED layered clay synthesis ESTERIFICATION activity. 
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