supported by the National Basic Research Program of China(Grant Nos.2012CB821500 and 2010CB923303);the National Natural Science Foundation of China(Grant Nos.51133002 and 21074053);the Program for Changjiang Scholars and Innovative Research Team in University,China
Reaction pathways for the formation of thiolate-gold nanoparticles are investigated by density functional theory (DFT) and a new mechanism upon solvent polarity and tetraalkylammonium is obtained. In solvents with h...
supported by the 973 Program (2007CB815301);the National Natural Science Foundation of China (21073192,20733003 and 20871114);the Science Foundation of CAS (KJCX2-YW-H20);Fujian Province (2009HZ0006-1,2006L2005)
A new tri-nuclear mixed metal thiolate complex [Ag(PPh3)2]2[Ni(edtO2)2] 1 has been synthesized and structurally characterized by single-crystal diffraction.The molecule has a crystallographic inversion centre occu...
A di-molybdenum carbonyl compound containing thiolate and dithiocarbamate ligands, [Bu4N][(CO)4Mo(μ-SC6H5)2Mo(C5H10dtc)(CO)2] 1 (CsH10dtc = S2CNC5H10), has been prepared by reaction of [Mo2(SC6H5)2(CO)8...