THIOLATE

作品数：44被引量：14H指数：2
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相关期刊：《Aggregate》《Chinese Journal of Chemistry》《Journal of Environmental Sciences》《Science China Chemistry》更多>>
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Single thiolate replacement of metal nanoclusters
《Science China Chemistry》2024年第2期523-528,共6页Ambreen Ambreen Yue Zhou Wanmiao Gu Qing You Liang Fang Guoqing Bian Nan Yan Nan Xia Zhikun Wu 
supported by the National Natural Science Foundation of China (21925303,21829501,21771186,22171268,22171267,21971246);the Anhui Provincial Natural Science Foundation(2108085MB56);the HFIPS Director’s Fund (BJPY2019A02,YZJJ202102,YZJJ202306-TS);the Collaborative Innovation Program of Hefei Science Center,Chinese Academy of Sciences (2020HSC-CIP005,2022HSCCIP018)。
Surface thiolates play important roles in evincing the structures and properties of thiolated metal nanoclusters—one type of recently emerging inorganic-organic hybrids,and thus the thiolate substitution,especially s...
关键词：metal nanoclusters single thiolate replacement thermal expansion STABILITY intercluster interaction 
Temperature-dependent chloride-mediated access to atom-precise silver thiolate nanoclusters被引量：2
《Science China Chemistry》2022年第6期1094-1099,共6页Ling Yang Xin-Yao Wang Xiao-Yan Tang Meng-Yi Wang Chun-Yan Ni Hong Yu Ying-Lin Song Brendan F.Abrahams Jian-Ping Lang 
supported by the National Natural Science Foundation of China (21871196, 21773163, 21531006);the Collaborative Innovation Center of Suzhou Nano Science and Technology;the Priority Academic Program Development of Jiangsu Higher Education Institutions;the Project of Scientific and Technologic Infrastructure of Suzhou (SZS201905)。
By using a unique temperature-dependent,chloride-mediated approach,two atom-precise silver nanoclusters[Cl@Ag_(14)(Tab)_(12)-(C_(5)H_(4)NCl)_(12)](PF_(6))_(13)(Cl@Ag_(14))and[Cl_(3)@Ag_(24)(Tab)_(20)(C_(5)H_(4)NCl)_(1...
关键词：TEMPERATURE-DEPENDENT chloride-mediated core expansion silver thiolate nanocluster transformation 
Solvent-driven reversible transformation between electrically neutral thiolate protected Ag_(25)and Ag_(26)clusters被引量：3
《Science China Chemistry》2021年第6期948-952,共5页Yu-Ling Tan Ling Yang Tian-Chen Yu Hong Yu Xin-Yao Wang Ying-Lin Song Zheng Niu Jian-Ping Lang 
supported by the National Natural Science Foundation of China(21871196,21773163,21531006);the State Key Laboratory of Organometallic Chemistry of Shanghai Institute of Organic Chemistry(KF2021005);Collaborative Innovation Center of Suzhou Nano Science and Technology,the Priority Academic Program Development of Jiangsu Higher Education Institutions;the Project of Scientific and Technologic Infrastructure of Suzhou(SZS201905).
Two atom-precise silver nanoclusters[Ag_(25)Cl_2(Tab)_(14)(Ph COO)_(11)(DMF)_4](PF_6)_(12)(Ag_(25),DMF=N,N-dimethylformamide)and[Ag_(26)Cl_2(Tab)_(14)(Ph COO)_(13)(DMAc)_4](PF_6)_(11)(Ag_(26),DMAc=N,N-dimethylacetamid...
关键词：silver nanocluster electrically neutral thiolate reversible transformation 
Structural Regularities of the Transition Metal Complexes Containing o-Benzenedithiol (H_2bdt)——Synthesis and Structure of Fe_3(bdt)_3(PBu_3~n)_3
《Science China Chemistry》1993年第8期912-919,共8页康北笙 徐勇进 吴达旭 彭金海 洪茂椿 翁林红 陈学太 刘汉钦 
Project supported by the National Natural Science Foundation of China, and the NSF of Academia Sinica and of Fujian Province.
Complex Fe_3(bdt)_3(PBu_3~n)_3 was synthesized in the presence of PBu_3~n and the structural regularities in a series of transition metal complexes containing bdtH_2 ligand were summarized. The title complex crystalli...
关键词：o-benzenedithiol ligand THIOLATE and phosphine-mixed coordinated complex STRUCTURAL regularity trinuclear iron cluster compound. 
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