supported by the State Key Project of Fundamental Research for Nanoscience and Nanotechnology (2012CB224802);the National Natural Science Foundation of China (21573119,21221062,21131004,21390393,U1463202 and 21325101);Beijing Municipal Commission of Science and Technology (Z141100003814017)
A novel one-pot approach to synthesize the tiara-like Pd(II) thiolate complex compound, [Pd(SCH_3)_2]_6, was developed. In this strategy, dimethyl sulfoxide(DMSO) was used as a thiolate source instead of methyl mercap...