ALLYLIC

作品数：51被引量：38H指数：4
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相关领域：理学更多>>
相关作者：王刚伟张万斌杨尚东徐永强涂永强更多>>
相关机构：兰州大学上海交通大学华南理工大学更多>>
相关期刊：《有机化学》《Science Bulletin》《Green Synthesis and Catalysis》《Science China Chemistry》更多>>
相关基金：国家自然科学基金国家重点基础研究发展计划Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry更多>>
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Palladium-catalyzed asymmetric allylic C–H alkylation of 1,4-dienes and glycine Schiff bases被引量：1
《Science China Chemistry》2020年第4期454-459,共6页Tian-Ci Wang Pu-Sheng Wang Liu-Zhu Gong 
Ministry of Science and Technology of China(2015CB856600);the National Natural Science Foundation of China(21672197,21602214);the Chinese Academy of Sciences(XDB20020000).
A highly regio-and enantioselective allylic C–H alkylation of 1,4-dienes with glycine Schiff bases has been established by chiral palladium-phosphoramidite catalysis. This reaction can proceed under mild conditions a...
关键词：ASYMMETRIC catalysis palladium ALLYLIC C–H ALKYLATION 1 4-diene GLYCINE Schiff base 
CuCl-Catalyzed Aerobic Oxidation of Allylic and Propargylic Alcohols to Aldehydes or Ketones with 1 ： 1 Combination of Phenanthroline and Bipyridine as the Ligandst被引量：4
《Chinese Journal of Chemistry》2012年第1期29-34,共6页刘宇 麻生明 
We developed a modified protocol for the oxidation of 2,3-allenyl alcohols using CuCI with l ： 1 combination of phenanthroline and bipyridine as the catalyst. To further investigate the applicability of this system, ...
关键词：Cu（I） catalyst allylic alcohol propargylic alcohol ALDEHYDE ketone 
An unexpected palladium migration from vinylic sp^2 carbon to allylic sp^3 carbon
《Chinese Science Bulletin》2010年第25期2807-2810,共4页LI BiJie SHI ZhangJie 
supported by Peking University,the National Natural Science Foundation of China (20542001 and 20521202);the National Basic Research Program of China (2009CB825300)
A unique transformation to realize the allylic amination from vinylic bromides was described and an unexpected C-Pd migration was observed from sp2 carbon to adjacent allylic sp3 carbon initiated from vinyl bromide. V...
关键词：SP3 SP2 碳烯 迁移 钯 烯丙基 溴乙烯 乙烯基 
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