financial support provided by the National Natural Science Foundation of China(No.22061032);Natural Science Foundation of Inner Mongolia(Nos.2020MS02022,and 2022QN02005);Science and Technology Program of Inner Mongolia(No.2020GG0134);Opening-fund from State Key Laboratory of Bio-organic and Natural Products Chemistry of SIOC(No.21300-5206002);“JUN-MA”Highlevel Talents Program of Inner Mongolia University(No.21300-5185121);“Grassland Talents”Program of Inner Mongolia(No.12000-12102414);High-level Recruit Program of Inner Mongolia(No.12000-13000603);Key Project at Central Government Level:the ability establishment of sustainable use for valuable Chinese medicine resources(No.2060302)is sincerely acknowledged。
The construction of chiral quaternary carbon stereocenters is a significant challenge in asymmetric synthesis.Catalytic synthesis of these structures with trisubstituted allylic alcohols is highly important. However, ...
We gratefully acknowledge the National Natural Science Foundation of China(Nos.21801040,22008028,22102022);the Natural Science Foundation of Jiangxi Province(Nos.20192BAB213006,20181BBH80007);the Opening Project of Jiangxi Province Key Laboratory of Polymer Micro/Nano Manufacturing and Devices(Nos.PMND202001,PMND202003);East China University of Technology Research Foundation for Advanced Talents(No.DHBK2017168)provides financial support.
An efficient palladium-catalyzed sulfonylative coupling for the synthesis of benzyl(allyl)sulfones from sulfonyl hydrazides and carbonates was developed.The novel methodology employs easily accessible chemical feedsto...