financially supported by the National Natural Science Foundation of China(61077021,61076016);the Nanjing University of Posts and Telecommunications(NY212076,NY212050)
Two new iridium complexes with C^N=N type ligand (i.e., Ir(BFPPya)3{tris[3,6-bis(4-fluorophenyl)pyridazine]iridium(III)} and Ir(BDFPPya)3{tris[3,6-bis(2,4-di-fluorophenyl)pyridazine]iridium(III)}) attach...
Infrared spectra of mass-selected homoleptic dinuclear palladium carbonyl cluster cations Pd2(CO)n (n=5 8) are measured via infrared photodissociation spectroscopy in the carbonyl stretching frequency region. The ...
Supported by the National Natural Science Foundation of China (Grant Nos. 20873045 and 20973066)
Homoleptic mononuclear and binuclear ruthenium carbonyls Ru(CO)n(n=3―5) and Ru2(CO)n(n=8,9) have been investigated using density functional theory.Sixteen isomers are obtained.For Ru(CO)5,the lowest-energy structure ...
A neutral homoleptic lanthanide amide Yb(NPh 2) 3(THF) 2 was obtained by reaction of anhydrous YbCl 3 with LiNPh 2 in THF. The product was characterized by elemental analysis, infrared spectrum and X-ray crystall...