financially supported by the National Natural Science Foundation of China (Nos. 51973037 and 52173056);PetroChina Company Limited,China。
The melt memory effect is a widely observed phenomenon in semi-crystalline polymers. In practical applications, various additives are usually introduced into polymers, which may affect their melt memory behavior. In t...
financially supported by the Natural Science Foundation of Hebei Province(No.B2015202049);the National Natural Science Foundation of China(Nos.21004017 and 50573018)
Tandem catalytic systems, consisting of ethylene bis(indenyl) zirconium dichloride with two different cocatalysts, alkylaluminum(diethylaluminium chloride or trialkylaluminum) and methylaluminoxane, were employed ...
supported by the National Natural Science Foundation of China (Nos. 20734002, 51103163,51003106 and 51003105);Chinese Academy of Sciences (Directional key project on high performance polypropylene alloy resin development)
In this paper, we review our recent progress in the synthesis and application of styryl-capped polypropylene (PP-t- St), an excellent reactive polyolefin that is both convenient and efficient in synthesis and facile...
the Korea Ministry of Commerce,Industry,and Energy(Grant RTI04-01-04,Regional Technology Innovation Program).
Polymerization of isobutyl vinyl ether(IBVE)has been studied with mononuclear half-titanocene,CpTiCl_3[1]and dinuclear half-titanocenes,[(C_5H_4)_2(CH_2)_n][(TiCl_3)_2][2(n=3),3(n=6)],and[(C_5H_4)_2(CH_2)_n[(TiCl_2OR_...
National Basic Research Program of China(No.2005CB623804);the National Natural Science Foundation of China(No.20476090).
i-PP/m-EPR reactor alloy were prepared through ethylene/propylene slurry copolymerization catalyzed by metallocene(rac-Et(Ind)_2ZrCl_2)supported on porous iPP particles.Polar monomer(dihydromyrcene alcohol)treated wit...
the National Natural Science Foundation of China(No.50573018)
Three ansa-metallocenes(Me_2C)(Me_2Si)Cp_2TiCl_2(1),[(CH_2)_5C](Me_2Si)Cp_2TiCl_2 (2)and (Me_2C)(Me_2Si)Cp_2ZrCl_2 (3)with larger dihedral angles and longer distance from metal to the center of Cp planes were synthesi...
This work was financially supported by the National Natural Science Foundation of China(Nos.20374043,20074028)China Petroleum & Chemical Corporation(No.X503027).
By treating disodium(thiophenedimethylene)dicyclopentadienide C4H2S(CH2C5H4Na)2 with two equivalent of CpTiCl3 or CpZrC13 DME at 0℃ in THF, two new thiophenedimethylene bridged binuclear metallocenes [Cl2MC5H5][C...
This work was supported by the China National Distinguished Young Investigator Fund (No. 29925413) and the NationalNatural Science Foundation of China (No.20274028).
Metallocene-catalyzed short chain branched polyethylene (SCBPE) was blended with LDPE, HDPE, PS, EPDM and iPP in the weight proportions of 80 and 20. The crystallization and mechanical properties of these blends were ...
This work was supported by the National Natural Science Foundation of China (Grant No. 29734144 and 59703002) andby the Special Funds for Major State Basic Research Projects (Grant No. G1999064803).
The fractions of one metallocene-based (mPE) and one conventional (znPE) ethylene-butene copolymer eluted at from temperature rising elution fractionation were selected for DSC and time-resolved small angle X-ray scat...
This work was supported by National Natural Science Foundation of China (No. 59703002).
The impact properties of two selected metallocene-catalyzed ethylene-butene copolymers and one conventionalcopolymer were evaluated using Izod impact test. It is found that the metallocene-catalyzed copolymer shows su...