MIXED-VALENT

作品数：7被引量：2H指数：1
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A mixed-valent high spin(μ-hydroxo)dicobalt(Ⅱ/Ⅲ) complex and its end-on type dioxygen adduct: synthesis, geometric and electronic structure studies
《Science China Chemistry》2021年第10期1693-1697,共5页Ceng-Ceng Du Si-Jun Xie Dan-Dan Zhai Zhang-Jie Shi Huayi Fang 
the National Natural Science Foundation of China(21988101,21801044,22071122,U19B6002);Shanghai Sailing Program(18YF1401800)。
A mixed-valent high spin (μ-hydroxo)dicobalt(Ⅱ/Ⅲ) complex bearing N,N′-bis(5-tertbutylsalicylidene)-1,2-diaminobenzene(Salophen^(tBu)) ligand was synthesized by reacting (Salophen^(tBu))Co(Ⅱ)(Py) with O_(2) at lo...
关键词：dicobalt complex MIXED-VALENT electronic structure dioxygen adduct 
Structural limiting factors of mixed-valent tin oxides in photoelectrochemical application:A comparative exploration
《Journal of Energy Chemistry》2021年第5期504-511,共8页Yalong Zou Deyu Liu Xiangrui Meng Qitao Liu Yang Zhou Jianming Li Zhiying Zhao Ding Chen Yongbo Kuang 
support by the National Natural Science Foundation of China(NSFC,Grant Nos.21805298,21905288,51904288);K.C.Wong Education Foundation(GJTD-2019-13);Ningbo major special projects of the Plan"Science and Technology Innovation 2025"(No.2018B10056,No.2019B10046);Ningbo 3315 Program。
Photoelectrocatalytic(PEC)materials for harvesting solar energy can be discovered from existing photocatalytic semiconductors.Nonetheless,mixed valence tin oxides,a group of widely reported visible light active photoc...
关键词：Mixed-valence tin oxide Photoelectrochemical water splitting NANOSTRUCTURE 
A new mixed-valent iron arsenate black crystal被引量：1
《Transactions of Nonferrous Metals Society of China》2018年第5期1036-1044,共9页Jin-qin YANG Qing-zhu LI Li-yuan CHAI Qing-wei WANG Hui LIU Xiao-bo MIN Rui-yang XIAO 
Project(51634010)supported by the Key Project of National Natural Science Foundation of China;Project(51304251)supported by the National Natural Science Foundation of China;Project(201509050)supported by Special Program on Environmental Protection for Public Welfare of China
Scorodite（FeAsO4·2H2O）is the most popular phase for arsenic（As）immobilization while the reductive dissolution of Fe（Ⅲ）to Fe（Ⅱ）will promote As release.In the present study,an equilibrium between Fe（Ⅲ）and...
关键词：ARSENIC IRON CRYSTAL arsenic immobilization hazardous wastes 
Pressure-Induced Charge-Order Melting and Reentrant Charge Carrier Localization in the Mixed-Valent Pb3Rh7O15被引量：1
《Chinese Physics Letters》2017年第8期117-120,共4页李妍 孙朝 蔡嘉伟 孙建平 王铂森 赵志颖 Y.Uwatoko 闫加强 程金光 
Supported by the"Shi-Pei Ji Hua",the National Science Foundation of China under Grant Nos 51402019 and 11574377;the Beijing Natural Science Foundation under Grant No 2152011;the National Basic Research Program of China under Grants No2014CB921500;the Strategic Priority Research Program;Key Research Program of Frontier Sciences of the Chinese Academy of Sciences under Grant Nos XDB07020100 and QYZDB-SSW-SLH013;the U.S.Department of Energy,Office of Science,Basic Energy Sciences,Materials Sciences and Engineering Division;the CEM;NSF MRSEC under Grant No DMR-1420451
The mixed-valent Pb3Rh7O15 undergoes a Verwey-type transition at Tv≈180K, below which the development of Rh3＋3＋/Rh4＋4＋ charge order induces an abrupt conductor-to-insulator transition in resistivity. Here we inve...
关键词：Rh Pressure-Induced Charge-Order Melting and Reentrant Charge Carrier Localization in the Mixed-Valent Pb3Rh7O Pb 
Highly efficient electrochemically driven water oxidation by graphenesupported mixed-valent Mn_(16)-containing polyoxometalate
《Green Energy & Environment》2016年第2期138-143,共6页Xiaolin Xing Meng Wang Rongji Liu Shuangshuang Zhang Ke Zhang Bin Li Guangjin Zhang 
supported by the National Natural Science Foundation of China(No.21371173,51402298,91545125);the China Postdoctoral Foundation(No.2014M550846)
A highly efficient catalyst of graphene-supported mixed-valent Mn_(16)-containing polyoxometalate is reported here by electrochemical strategy. The modified electrode with the catalyst exhibits an excellent electrocat...
关键词：Water oxidation POLYOXOMETALATES GRAPHENE ELECTROCATALYSIS 
A Mixed-valent Hexanuclear Cu~Ⅱ-Cu~ⅠComplex with Unusual Tridentate pbi Ligand (pbi = 2-(2-Pyridyl)-benzimidazole)
《Chinese Journal of Structural Chemistry》2006年第12期1507-1511,共5页刘九辉 吴小园 张全争 何翔 卢灿忠 
This work was supported by the 973 Program of the MOST (001CB108906), the NNSFC (90206040, 20425313, 20521101, 20333070, and 20303021), the NSF of Fujian Province (2005HZ01-1) and the Chinese Academy of Sciences
A mixed-valent hexanuclear complex [Cu^ⅡCu^Ⅰ2（pbi）2Br2]2 （pbi = （2-（2-pyridyl）-benzimidazole） exhibiting a dimeric unit bridged by two Br atoms was synthesized by hydrothermal reaction Interestingly, there ex...
关键词：mixed-valence π-π staeking interaction metal-aromatic ring interaction 
Synthesis and characterization of a new Mo-Fe-S cluster compound containing MoO_3S_3 unit and mixed-valent Mo atoms [Et_4N]_2[Mo_2Fe(CO)_4(S,O-C_6H_4-1,2)_3Cl_2]
《Chinese Journal of Chemistry》1994年第6期495-502,共8页ZHUANG, Bo-Tao LAN, An-Jian HE, Ling-Jie HUANG, Liang-RenFujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, State Key Laboratory of Structural Chemistry, Fuzhou, Fujian 350002, China 
Project supported by the National Natural Science Foundation of China.
Reaction of [Mo3(CO)7(S,O-C6H4-1,2)3]2- with FeCl2 in MeCN at 60℃ affords a new Mo-Fe-S cluster complex containing MoO3S3 unit and mixed-valeut Mo atoms, [Et4N]2[Mo2Fe-(CO)4(O,S-C6H4-1,2)aCl2] (1). 1 is characterize...
关键词：Synthesis characterization Mo-Fe-S cluster MoO3S3 unit mixed-valence. 
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