ACETONITRILE

作品数：94被引量：64H指数：4
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Molecular simulation study of the microstructures and properties of pyridinium ionic liquid[HPy][BF_(4)]mixed with acetonitrile
《原子与分子物理学报》2025年第4期27-32,共6页XU Jian-Qiang MA Zhao-Peng CHENG Si LIU Zhi-Cong ZHU Guang-Lai 
安徽省自然科学基金(2108085MA21);国家自然科学基金(21173002)。
The microstructures and thermodynamic properties of mixed systems comprising pyridinium ionic liquid[HPy][BF_(4)]and acetonitrile at different mole fractions were studied using molecular dynamics simulation in this wo...
关键词：Pyridinium ionic liquids Thermodynamic properties Molecular dynamics simulation Radial distribution functions 
Ultrathin nickel sulfide nanosheets for sulfur ion electrooxidation assisted acetonitrile electroreduction
《Science China Chemistry》2025年第3期951-960,共10页Xiao-Hui Wang Ze-Nong Zhang Na Li Xuan Ai Xue Xiao Yu Chen Shu-Ni Li 
supported by the National Natural Science Foundation of China (22309108);the Science and Technology Innovation Team of Shaanxi Province (2023-CX-TD-27);the Fundamental Research Funds for the Central Universities (GK202202001);Sanqin Scholars Innovation Teams in Shaanxi Province,China。
Electrochemical reduction of acetonitrile(ACN)to ethylamine(ETA)is a new strategy for producing high-value chemicals.Herein,the ultrathin nickel sulfide nanosheets(Ni_(x)S_(y)NSs)anchored on nickel foam(NF)nanohybrid(...
关键词：ELECTROSYNTHESIS hydrogenation two-dimensional nanomaterials acetonitrile reduction reaction sulfur ion oxidation reaction 
Solubility determination and comparison ofβ-HMX and RDX in two binary mixed solvents(acetonitrile+water,nitric acid+water)
《Chinese Journal of Chemical Engineering》2024年第5期238-249,共12页Yuehua Yao Fan Wang Yinguang Xu Zishuai Xu Lizhen Chen Jianlong Wang 
In order to remove hexahydro-1,3,5-trinitro-1,3,5-triazine(RDX),the main impurity,in process of polymorphic transformation of octrahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine(HMX),the solubility ofβ-HMX and RDX in a...
关键词：SOLUBILITY Octrahydro-1 3 5 7-tetranitro-1 3 5 7-tetrazocine Hexahydro-1 3 5-trinitro-1 3 5-triazine Separation Model Hydrogen bond 
d-d Orbital coupling induced by crystal-phase engineering assists acetonitrile electroreduction to ethylamine
《Journal of Energy Chemistry》2024年第2期216-225,I0006,共11页Honggang Huang Yao Chen Hui Fu Cun Chen Hanjun Li Zhe Zhang Feili Lai Shuxing Bai Nan Zhang Tianxi Liu 
financially supported by the National Natural Science Foundation of China(Grant Nos.52161135302,22105087);the Postdoctoral Research Foundation of China(Grant No.2022M721360);the Natural Science Foundation of Jiangsu Province(Grant No.BK20210446)。
The d-d orbital coupling induced by crystal-phase engineering can effectively adjust the electronic structure of electrocatalysts,thus showing significant catalytic performance,while it has been rarely explored in ele...
关键词：d-d Orbital coupling Crystal-phase engineering Metallic aerogels Acetonitrile electroreduction reaction ETHYLAMINE 
The d-orbital coupling modulation of CuNi alloy for acetonitrile electrochemical reduction and in-situ hydrogenation behavior characterization
《Science China Chemistry》2023年第11期3242-3251,共10页Boling Liu Dong He Zunjian Ke Hongbo Wang Chongyang Tang Qi Zhang Hang Xu Menghua Yang Yafei Yang Qi Liu Xiangheng Xiao 
the National Natural Science Foundation of China (12025503, 12105208);the Fundamental Research Funds for the Central Universities of China (2042022kf1181);China Postdoctoral Science Foundation (2020M682469)。
Electrochemical reduction of acetonitrile to ethylamine with a high selectivity is a novel approach to manufacture valuable primary amines which are important raw material in organic chemical industry. However, the po...
关键词：CuNi alloy acetonitrile reduction reaction d-orbital coupling modulation in-situ spectroscopy analysis acetonitrile adsorption 
Investigation of energy-efficient heat pump assisted heterogeneous azeotropic distillation for separating of acetonitrile/ethyl acetate/n-hexane mixture被引量：1
《Chinese Journal of Chemical Engineering》2023年第3期20-33,共14页Xinhao Li Qing Ye Jinlong Li Lingqiang Yan Xue Jian Licheng Xie Jianyu Zhang 
financial support provided by the National Natural Science Foundation of China (22178030, 21878025, and 22078026)。
The conventional distillation is hard to accomplish the separation of acetonitrile/ethyl acetate/n-hexane mixture. Herein, a heterogeneous azeotropic distillation(HAD) without adding entrainer is proposed to separate ...
关键词：Heterogeneous azeotropic distillation ENERGY-SAVING SA algorithm Heat pump 
High performance Zn-I_(2)battery with acetonitrile electrolyte working at low temperature被引量：2
《Nano Research》2022年第4期3170-3177,共8页Chunlai Song Zongshuai Gong Chong Bai Fengshi Cai Zhihao Yuan Xizheng Liu 
This work was financially supported by the National Key R&D Program of China(No.2017YFA0700104);the Tianjin Natural Science Foundation of China(No.20JCZDJC00280);the National Natural Science Foundation of China(No.U1804255).
Large scale applications of metal-iodine batteries working at sub-zero degree have been challenged by the limited capacity and performance degradation.Herein,we firstly propose a Zn-I_(2)battery working at low tempera...
关键词：Zn-I_(2)battery low temperature acetonitrile electrolyte carbon composite material high performance 
In situ phosphonium-containing Lewis basecatalyzed 1,6-cyanation reaction:a facile way to obtainα-diaryl andα-triaryl acetonitriles
《Organic Chemistry Frontiers》2022年第1期156-162,共7页Jian-Ping Tan Yuan Chen Xiaoyu Ren Yumeng Guo Bing Yi Hongkui Zhang Guowei Gao Tianli Wang 
support was provided by the National Natural Science Foundation of China(21971165,21921002,21772035,22101189);National Key R&D Program of China(2018YFA0903500);National Natural Science Foundation of Hunan(2021JJ40150).
We present a phosphonium-containing catalyst generated in situ from phosphine and tert-butyl acrylate that serves as an unusual Lewis base catalyst.It was applied for the promotion of a remote 1,6-cyanation reaction o...
关键词：catalyst FACILE ACETONITRILE 
Solubility and Thermodynamic Properties of Sulfamethazine-Saccharin Cocrystal in Pure and Binary (Acetonitrile + 2-Propanol) Solvents
《Transactions of Tianjin University》2021年第6期460-472,共13页Hongyuan Wei Ningcan Gao Leping Dang 
supported by the National Natural Science Foundation of China(No.21676196).
In this work,a new crystallization method was used to prepare two polymorphs of sulfamethazine-saccharin(SMT-SAC)cocrystal in bulk.The purity and crystal form of both polymorphs were confirmed by optical microscopy,sc...
关键词：Sulfamethazine-saccharin cocrystal Solid-liquid equilibrium Thermodynamic model Dissolution thermodynamic property 
A long-life and safe lithiated graphite-selenium cell with competitive gravimetric and volumetric energy densities被引量：1
《Journal of Energy Chemistry》2021年第9期556-563,共8页Xiaoqun Qi Qiang Jin Fengyi Yang Ruining Jiang Quan Sun Long Qie Yunhui Huang 
supported by the National Natural Science Foundation of China under Grant No. 51802225;the funding from the State Key Laboratory of Materials Processing and Die & Mould Technology, Huazhong University of Science and Technology (P2020-001)。
Lithium-selenium(Li-Se) battery is a promising system with high theoretical gravimetric and volumetric energy densities, while its long-term cyclability is hard to realize, especially when a practical Se cathode with ...
关键词：Conversion-intercalation Acetonitrile electrolyte Se cathode Lithiated graphite Energy density 
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