Supported by the National Natural Science Foundation of China(No.21101156);the State Key Laboratory of Structural Chemistry(No.20150016);Outstanding youth of colleges and universities of Department of Education,Fujian Province Natural Science Foundation for Youths(No.2016J05109);Fujian Education Department(No.JK2015056)
A new member of mixed-metal Ba2Bi2M-Ⅱ(PO4)4 monophosphate, namely Ba2Bi2Co(PO4)4, was synthesized by solid state method and characterized by X-ray single-crystal diffraction and powder diffraction for the first t...
Supported by the National Natural Science Foundation of China(No.20902001 and 21102001);the Natural Science Foundation of Anhui Province(No.090416220);the 211 Project of Anhui University
The mixed-metal cluster Yb4O4(OiPr)16Na12 has been synthesized and structurally determined by IR, elemental analysis, and single-crystal X-ray diffraction. The crystal belongs to the cubic system, space group P23 wi...
Supported by the National Natural Science Foundation of China (20573114);the MOST (2006DFA43020);Natural Science Foundation of Fujian Province (2006F3133)
Mixed-metal carbonyl clusters of W2Ir2(CO)10(η^5-C5H4Me)2 1 and W2Ir2(μ-L)(CO)8(η^5-C5H4Me)2 (L = dppe 2, dppf 3) have been studied by TDDFT method focusing on their electronic and nonlinear optical pro...
the Innovative Project (No.IP01007), the Introduction of Overseas Elitists Program (No. IB990168) and the Chinese Academy of Sciences
A new compound containing discrete cationic and anionic complexes, [Cu(pyr)3]Hg2I6 (C30H24CuHg2I6N6), where pyr = 2,2-bipyridine, was prepared by the reaction of CuBr with pyr and HgI2 in a mixed solvent of acetone, m...
Two mixed metal complexes [Cr2Fe(μ3-O) (μ-O2CC2H5)6Py3]Cl (A)and [CrFe2 (μ3-O) (μ-O2CC2H5 )6Py3] Cl (B) have been prepared in non-aqueous sol-vents. Crystal (A) is monoclinic, space group C2/c, with a= 13. 782(3),...
Molybdenum-tungsten mixed-metal oxopolymetalate(Et.N)2[Mo4.5W,1.5O19] has been synthesized and characterized by a complete X-ray crystallographic structure determination and a variety of physical measurements.The crys...
The heterotrinuclear cluster compound [MoW_2O_2 (O_2CC_2H_5 )_6-( H_2O)_3] ZnBr4·4H_2O was prepared by the redox reaction of Mo (CO)_6 with Na_2W_O4 in propionic anhydride. The crystal is monoclinic of space group P2...