MIXED-METAL

作品数:20被引量:19H指数:3
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相关领域:理学更多>>
相关作者:李群祥黄静李淑娟类淑来更多>>
相关机构:中国科学技术大学安徽建筑工业学院更多>>
相关期刊:《Chinese Journal of Structural Chemistry》《Journal of Environmental Sciences》《Science China(Technological Sciences)》《Science China Materials》更多>>
相关基金:国家自然科学基金天津市自然科学基金福建省自然科学基金中国科学院知识创新工程更多>>
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A New Mixed-metal Monophosphate:Ba2Bi2Co(PO4)4
《Chinese Journal of Structural Chemistry》2017年第6期1027-1033,共7页张炜龙 郭振刚 陈达贵 程文旦 
Supported by the National Natural Science Foundation of China(No.21101156);the State Key Laboratory of Structural Chemistry(No.20150016);Outstanding youth of colleges and universities of Department of Education,Fujian Province Natural Science Foundation for Youths(No.2016J05109);Fujian Education Department(No.JK2015056)
A new member of mixed-metal Ba2Bi2M-Ⅱ(PO4)4 monophosphate, namely Ba2Bi2Co(PO4)4, was synthesized by solid state method and characterized by X-ray single-crystal diffraction and powder diffraction for the first t...
关键词:mixed-metal monophosphate solid-state synthesis crystal structure stereoactivity magnetic property 
Synthesis and Crystal Structure of Novel Mixed-metal Alkoxide Clusters of Ytterbium and Sodium: Yb_4O_4(O^iPr)_(16)Na_(12)
《Chinese Journal of Structural Chemistry》2013年第4期571-577,共7页王辉 盛鸿婷 冯燕 史建华 何森 盛含晶 张勇 沈琪 
Supported by the National Natural Science Foundation of China(No.20902001 and 21102001);the Natural Science Foundation of Anhui Province(No.090416220);the 211 Project of Anhui University
The mixed-metal cluster Yb4O4(OiPr)16Na12 has been synthesized and structurally determined by IR, elemental analysis, and single-crystal X-ray diffraction. The crystal belongs to the cubic system, space group P23 wi...
关键词:mixed-metal cluster YTTERBIUM ALKOXIDE crystal structure computational analysis 
TDDFT Study on the Electronic Excitations and First Hyperpolarizabilities of Mixed-metal Carbonyl Clusters W_2Ir_2(μ-L)(CO)_8(η~5-C_5H_4Me)_2(L=dppe/dppf)
《Chinese Journal of Structural Chemistry》2009年第1期99-105,共7页李福君 洒荣建 吴克琛 
Supported by the National Natural Science Foundation of China (20573114);the MOST (2006DFA43020);Natural Science Foundation of Fujian Province (2006F3133)
Mixed-metal carbonyl clusters of W2Ir2(CO)10(η^5-C5H4Me)2 1 and W2Ir2(μ-L)(CO)8(η^5-C5H4Me)2 (L = dppe 2, dppf 3) have been studied by TDDFT method focusing on their electronic and nonlinear optical pro...
关键词:TDDFT UV-vis spectrum transition metal nonlinear optical 
Syntheses and Crystal Structure of [Cu(pyr)_3]·Hg_2I_6
《Chinese Journal of Structural Chemistry》2003年第1期29-32,共4页宋俊玲 曾卉一 杨冰苹 董振超 郭国聪 黄锦顺 
the Innovative Project (No.IP01007), the Introduction of Overseas Elitists Program (No. IB990168) and the Chinese Academy of Sciences
A new compound containing discrete cationic and anionic complexes, [Cu(pyr)3]Hg2I6 (C30H24CuHg2I6N6), where pyr = 2,2-bipyridine, was prepared by the reaction of CuBr with pyr and HgI2 in a mixed solvent of acetone, m...
关键词:copper complex mercury halide mixed-metal compound single-crystal structure X-ray diffraction 
Synthesis, Structure and IR Spectrum of Octanuclear Mixed-metal Cluster Compound Na_2[CrW_3O_4(O_2CCH_3)_8]_2· H_2O
《Chinese Journal of Structural Chemistry》1998年第4期284-288,共5页YAN Duan-Chao HUANG Jin-Shun  XU Li ZHANG Qian-Er(State Key Laboratory of Structural Chemistry, Fujian Institute of Research on theStructure of Matter, the Chinese Academy of Sciences, Fuzhou, Fujian 350002, China) 
The complex Na2 [CrW3O4(O2CCH3)8]2·H2O (Mr = 2343. 80) crystallizes in monoclinic, space group P21/n with a=11. 206 (4 ), b=18. 016 (9), c=14. 465 (5) A, β=98. 00(3)°, V=2891. 9 A, Z=2, Dc=2. 69 g/cm3, F(000) =2168...
关键词:CHROMIUM TUNGSTEN CLUSTER struoture IR 
Synthesis, Structure and IR Spectrum of Octanuclear Mixed-metal Cluster Compound Na<sub>2</sub>[CrW<sub>3</sub>O<sub>4</sub>(O<sub>2</sub>CCH<sub>3</sub>)<sub>8</sub>]<sub>2</sub>· H<sub>2</sub>O
《Chinese Journal of Structural Chemistry》1998年第4期284-288,共页
The complex Na2 [CrW3O4(O2CCH3)8]2·H2O (Mr = 2343. 80) crystallizes in monoclinic, space group P21/n with a=11. 206 (4 ), b=18. 016 (9), c=14. 465 (5) A, β=98. 00(3)°, V=2891. 9 A, Z=2, Dc=2. 69 g/cm3, F(000) =2168...
关键词:CHROMIUM TUNGSTEN cluster struoture IR 
Syntheses, Crystal Structures and IR Spectra of Two Mixed Metal Complexes:〔Cr_nFe_(3-n)(μ_3-O)-(μ-O_2CC_2H_5)_6 Py_3〕Cl(n=1,2)
《Chinese Journal of Structural Chemistry》1997年第3期247-252,共6页CUI Yong ZHANG Lin-Na  HUANG Xiao-Ying HE Ling-Jie WANG Yan-Min CAI Su-Hua  CHEN Bo(Fujian Institute of Research on the Structure of Matter, State Key Laboratory ofStructural Chemistry, the Chinese Academy of Sciences, Fuzhou, Fujian 350002, China) 
Two mixed metal complexes [Cr2Fe(μ3-O) (μ-O2CC2H5)6Py3]Cl (A)and [CrFe2 (μ3-O) (μ-O2CC2H5 )6Py3] Cl (B) have been prepared in non-aqueous sol-vents. Crystal (A) is monoclinic, space group C2/c, with a= 13. 782(3),...
关键词:crystal structure MIXED-METAL complex IR 
Synthesis and Characterization of the Molybdenum-Tungsten Mixed-metal Oxopolymetalate(Et<sub>4</sub>N)<sub>2</sub>[Mo<sub>4.5</sub>W<sub>1.5</sub>O<sub>19</sub>]
《Chinese Journal of Structural Chemistry》1995年第6期78-82,共5页
Molybdenum-tungsten mixed-metal oxopolymetalate(Et.N)2[Mo4.5W,1.5O19] has been synthesized and characterized by a complete X-ray crystallographic structure determination and a variety of physical measurements.The crys...
关键词:SYNTHESIS CHARACTERIZATION Mo-W MIXED-METAL oxopolymetalate 
Synthesis and Structure of Propionate-bridged Mixed-metal Cluster Compound: MoW_2O_2 (O_2CC_2H_5)_6 (H_2O)_3 ZnBr_4·4H_2O被引量:3
《Chinese Journal of Structural Chemistry》1994年第1期52-55,共4页刘晃 徐立  
The heterotrinuclear cluster compound [MoW_2O_2 (O_2CC_2H_5 )_6-( H_2O)_3] ZnBr4·4H_2O was prepared by the redox reaction of Mo (CO)_6 with Na_2W_O4 in propionic anhydride. The crystal is monoclinic of space group P2...
关键词:SYNTHESIS crystal structure mixed-metal cluster Mo-W propionate compound 
Synthesis and Structure of Propionate-bridged Mixed-metal Cluster Compound:〔MoW<sub>2</sub>O<sub>2</sub>(O<sub>2</sub>CC<sub>2</sub>H<sub>5</sub>)<sub>6</sub>(H<sub>2</sub>O)<sub>3</sub>〕ZnBr<sub>4</sub>·4H<sub>2</sub>O
《Chinese Journal of Structural Chemistry》1994年第1期52-55,共页
The heterotrinuclear cluster compound [MoW2O2 (O2CC2H56-( H2O)3] ZnBr4·4H2O was prepared by the redox reaction ...
关键词:SYNTHESIS crystal structure mixed-metal cluster Mo-W propionate compound 
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