ALKOXIDE

作品数:20被引量:18H指数:2
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相关领域:理学更多>>
相关作者:魏文平黄葆同张丹枫更多>>
相关机构:中国科学院清华大学华东理工大学更多>>
相关期刊:《Journal of Rare Earths》《Journal of Wuhan University of Technology(Materials Science)》《Chinese Physics B》《Chinese Journal of Structural Chemistry》更多>>
相关基金:国家自然科学基金国家重点基础研究发展计划国家科技攻关计划The Royal Society更多>>
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Tuning Magnetic Relaxation in Square-Pyramidal Dysprosium Single-Molecule Magnets Using Apical Alkoxide Ligands被引量:1
《CCS Chemistry》2021年第12期388-398,共11页Zhenhua Zhu Yi-Quan Zhang Xiao-Lei Li Mei Guo Jingjing Lu Shuting Liu Richard A.Layfield Jinkui Tang 
The authors thank the National Natural Science Foundation of China(nos.21525103,21871247,and 21973046);the Key Research Program of Frontier Sciences,CAS(no.ZDBS-LY-SLH023);the ERC(no.CoG 646740);the EPSRC(no.EP/M022064/1)for financial support;J.T.and R.A.L.gratefully acknowledge support from the Royal Society-Newton Advanced Fellowship(no.NA160075).
Eight square-pyramidal dysprosium complexes of the type[Dy(X)(DBP)_(2){TMG(H)}_(2)]were synthesized,where TMG(H)denotes 1,1,3,3-tetramethylguanidine,X denotes an alkoxide ligand or anionic guanidinate in the apical po...
关键词:single-molecule magnets DYSPROSIUM magnetic relaxation energy barrier twocoordination design 
Effect of Synthetic Parameters on Synthesis of Magnesium Aluminum Spinels被引量:1
《Journal of Materials Science and Chemical Engineering》2019年第3期1-15,共15页Jinxia Duan Xiuhui Wang Youfei Zhang Hong Gao Yan Xie Jinlong Yang 
In this work, the magnesium aluminum spinel (MgAl2O4) was prepared by Mg and Al as precursors through a method of sol-gel subsequent with high temperature calcination. The wide range of synthetic conditions, including...
关键词:ALKOXIDE HYDROLYSIS MGAL2O4 SYNTHETIC PARAMETERS 
Effect of Constituent Core-sizes on Microstructure and Dielectric Properties of BaTiO_3@(0.6BaTiO_3-0.4BiAlO_3) Core-Shell Material被引量:1
《Journal of Wuhan University of Technology(Materials Science)》2018年第3期589-597,共9页APPIAH Millicent 郝华 CHEN Wenjin CHEN Cheng YAO Zhonghua CAO Minghe LIU Hanxing 
Funded by NSFC-Guangdong Joint Funds of the Natural Science Foundation of China(No.U1601209);the National Key Basic Research Program of China(973 Program)(No.2015CB654601);National Natural Science Foundation of China(No.51372191)
The fundamental characteristics of varied initial core-sizes of Ba Ti O3(BT) and its influential role on the morphology and dielectric properties of Ba Ti O3@0.6 Ba Ti O3-0.4 Bi Al O3(BT@0.6 BT-0.4 BA) ceramic sam...
关键词:MLCCs core-shell Alkoxide sol-precipitation relaxor grain boundary segregation 
Water-based processed and alkoxide-based processed indium oxide thin-film transistors at different annealing temperatures
《Chinese Physics B》2018年第4期543-550,共8页Xu-Yang Li Zhi-Nong Yu Jin Cheng Yong-Hua Chen Jian-She Xue Jian Guo Wei Xue 
Project supported by the National Natural Science Foundation of China(Grant No.61675024);the National Basic Research Program of China(Grant No.2014CB643600)
In this study,indium oxide(In2O3) thin-film transistors(TFTs) are fabricated by two kinds of low temperature solution-processed technologies(Ta ≤ 300℃),i.e.,water-based(DIW-based) process and alkoxide-based...
关键词:water-based process alkoxide-based process annealing temperature thin-film transistors 
Lanthanocene Diolate Complexes: Synthesis, Structures and Catalytic Property for ε-Caprolactone Polymerization
《Chinese Journal of Chemistry》2015年第5期563-567,共5页Zhanghai Gu Li Li Qianwen Bao Fugen Yuan 
Reaction of LnCl3 first with three equivalent of C5H5Na in THF,then with one equivalent of N-phenyldiethanolamine in THF-DME afforded complexes of{[(C_(5)H_(5))Ln(μ-OCH_(2)CH_(2))_(2)N(C_(6)H_(5))]4(μ_(4)-C_(l))}[Na...
关键词:LANTHANIDE ALKOXIDE catalytic activity CAPROLACTONE 
Synthesis and Crystal Structure of Novel Mixed-metal Alkoxide Clusters of Ytterbium and Sodium: Yb_4O_4(O^iPr)_(16)Na_(12)
《Chinese Journal of Structural Chemistry》2013年第4期571-577,共7页王辉 盛鸿婷 冯燕 史建华 何森 盛含晶 张勇 沈琪 
Supported by the National Natural Science Foundation of China(No.20902001 and 21102001);the Natural Science Foundation of Anhui Province(No.090416220);the 211 Project of Anhui University
The mixed-metal cluster Yb4O4(OiPr)16Na12 has been synthesized and structurally determined by IR, elemental analysis, and single-crystal X-ray diffraction. The crystal belongs to the cubic system, space group P23 wi...
关键词:mixed-metal cluster YTTERBIUM ALKOXIDE crystal structure computational analysis 
Dimethylformamide Dimethyl Acetal (DMFDMA) in Heterocyclic Synthesis: Synthesis of Polysubstituted Pyridines, Pyrimidines, Pyridazine and Their Fused Derivatives被引量:1
《International Journal of Organic Chemistry》2011年第4期207-214,共8页Fathi A. Abu-Shanab Sayed A. S. Mousa E. A. Eshak Ahmed Z. Sayed Ahmed Al-Harrasi 
Reaction of N,N’-dimethylformamide dimethyl acetal (DMFDMA) with malononitrile dimer 8 (1:1) mole afforded 9 while, this reaction when carried out in (2:1) mole to give amidine 11 which can be used for the preparatio...
关键词:DMFDMA MALONONITRILE Dimer Pyridazine-3 5-carbonitrile Pyridine-4-alkoxide 
Acylation of nitriles to β-ketonitriles catalyzed by a heterometallic alkoxide cluster of neodymium and sodium:NdNa_8(O^tBu)_(10)(OH)被引量:1
《Chinese Science Bulletin》2011年第13期1357-1360,共4页LIU HaiDong LI Lan SHENG HongTing ZHU XueHua XU Fan SHEN Qi 
supported by the National Natural Science Foundation of China (20872106 and 20972107)
Catalytic acylation of nitriles with esters in the presence of 10 mol% NdNa8(OtBu)10(OH) is developed.The procedure is suitable for both enolizable and nonenolizable esters and affords β-ketonitriles in moderate to h...
关键词:催化 酰化 集群   结构特征 射线衍射 生产机制 
Ethylene glycol aluminum as a novel catalyst for the synthesis of poly(ethylene terephthalate)被引量:4
《Chinese Chemical Letters》2011年第6期741-744,共4页Bin Xiao 
Ethylene glycol aluminum was prepared efficiently and characterized by FT-IR and NMR.It exhibited higher catalytic activity and had profitable effect than titanium glycolate and ethylene glycol antimony for the synthe...
关键词:Aluminum alkoxide PET POLYCONDENSATION CATALYST Ethylene glycol Terephthalic acid 
Influence of hydrothermal temperature on structure and microstructure of boehmite被引量:3
《Transactions of Nonferrous Metals Society of China》2010年第S1期221-225,共5页付高峰 王晶 徐冰 高宏 徐秀林 成豪 
Project(50974026)supported by the National Natural Science Foundation of China
Boehmites(Al2O3·xH2O)were hydrothermally prepared from aluminum alkoxide.The effect of temperature on preparation was studied in the range of 100-180℃.The XRD analysis shows that with temperature increasing,the tran...
关键词:BOEHMITE hydrothermal synthesis ALKOXIDE MICROSTRUCTURE MORPHOLOGY 
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