POLYOXOMOLYBDATES

作品数：6被引量：1H指数：1
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Photosensitivity in Ce/Sm-decorated Keggin polyoxomolybdates:an interesting photoinduced coloration phenomenon of mixed- metal clusters involving energy transfer from rare-earth fluorescence被引量：1
《Science China Chemistry》2014年第6期918-922,共5页LIU Li LI HongMei DAI JingCao 
supported by the National Natural Science Foundation of China(50971063);the Natural Science Foundation of Fujian Province of China(2003F006,2010J01042);the Scientific Research Foundation for Returned Overseas Chinese Scholars of the State Education Ministry of China
Ce/Sm ions are covalently grafted to a Keggin polyoxomolybdate cluster[PMo12O40]3-to yield interesting fluorescent-photodarkening molecular systems.Their photoresponce processes are observed to be activated via energy...
关键词：lanthanide-decorated polyoxomolybdates photocoloration solar-furnace PHOTOACTIVATION energy transfer 
Hydrothermal syntheses and structural characterizations of three polyoxomolybdates frameworks linked by M(HL)_2 units(M=Co,Ni,Zn;L=3-(2-pyridyl)pyrazole)
《Science China Chemistry》2010年第11期2285-2290,2407-2408,共8页ZHANG XiuTang WU XiaoYuan SUN DaoFeng WEI PeiHai NI ZhongHai DOU JianMin LI DaCheng SHI CongWen HU Bo 
supported by the Chinese Academy of Sciences ("Hundred Talents Program");Ministry of Science and Technology of China (2007CB607606);Shandong Provincial Education Department and Qilu Normal University
Three polyoxomolybdate compounds,namely {[MII(HL)2]2(Mo8O26)}n(M = Co(1),Ni(2),Zn(3))(HL,3-(2-pyridyl)pyrazole),were designed and synthesized under the hydrothermal conditions and characterized by elemental analysis,I...
关键词：POLYOXOMOLYBDATE 3-(2-pyridyl)pyrazole COBALT nickel zinc 
Hydrothermal Syntheses and Structural Characterizations of Two ML-Containing Polyoxomolybdates：[Cu^Ⅱ2（HL）3]2[Mo8O26）]·（H2O）4 and [Ni^Ⅱ（HL）3]2（Mo8O26）·（H2O）3（HL=3-（2-Pyridyl）pyrazole）
《Chinese Journal of Structural Chemistry》2010年第8期1284-1289,共6页李斌 吴小园 刘新征 魏培海 石聪文 胡波 
Supported by the 973 Key Program of the MOST (2006CB932904,2007CB815304);the National Natural Science Foundation of China (20873150,20821061,and 50772113);the Chinese Academy of Sciences (KJCX2-YW-M05);the Chinese Academy of Sciences (''Hundred Talents Program'') ;Ministry of Science and Technology of China (Project of ''973'' plan,No. 2007CB607606),and Shandong Provincial Education Department and Qilu Normal University
Two new polyoxomolybdate compounds,namely CuII2（HL）3]2[Mo8O26]·（H2O）4（1） and [NiII（HL）3]2（Mo8O26）·（H2O）3（2）（HL = 3-（2-pyridyl）pyrazole）,were designed and synthesized under hydrothermal conditions.X...
关键词：POLYOXOMOLYBDATE MOLYBDATE copper nickel X-ray analysis 
Hydrothermal Syntheses and Characterizations of Two One-dimensional Molybdenum 1,4-Butylenediphosphonates
《Chinese Journal of Structural Chemistry》2005年第9期997-1006,共10页张慧双 傅瑞标 张建军 吴新涛 李亚敏 黄细河 
Supported by the State Key Laboratory of Structural Chemistry, the National Science and Technology of China (001CB1089), the Chinese Academy of Sciences (CAS), the National Natural Science Foundation of China (20273073, 20333070 and 90206040), Key Item of Science and Technology of Fujian Province (2004 1+201-2), the Science Foundation of CAS and Fujian Province (2002F014, 2003J042, 2004J041 and Z0513022)
The reaction of Ni（CH3COO）2-4H2O, Na2MoO4·H2O, MoO3, 1,10-phenanthroline and 1,4-butylenediphosphonic acid in distilled water at 180℃ for 72 h produced two new compounds： {[Ni（1,10-phen）3][Ni（1,10-phen）2（Mo6...
关键词：single crystal 1-D polymers hydrothermal 1 4-butylenediphosphonic acid organic-inorganic hybrid material POLYOXOMOLYBDATES 
Synthesis and Structural Characterization of Three New Inorganic “Host-guest”Polyoxomolybdates
《Chinese Journal of Chemistry》2003年第8期1066-1072,共7页杨文斌 卢灿忠 庄鸿辉 
theMajorStateBasicResearchDevelopmentProgramm (No .0 0 1CB10 890 6) ;theNationalNaturalScienceFoun dationofChina (Nos .90 2 0 60 40and 2 0 0 73 0 48) ;theNaturalScienceFoundationofFujianProvince (Nos .2 0 0 0 2F0 15and 2 0 0 2J0 0 6);theState
Since two interesting inorganic “host guest” polyoxomolybdates 1 and 2 have been reported previously, we have now succeeded in selectively isolating three new acetated “host guest” polyoxomolybdates 3—5, which ...
关键词：inorganic “host  guest” polyoxomolybdate SYNTHESIS structural characterization 
ELECTRON PARAMAGNETIC RESONANCE STUDIES OF SINGLE CRYSTAL SODIUM HEXAMOLYBDOCHROMATE (Ⅲ)Cr^(3+)/Na_3(AlMo_6O_(24)H_6)·8H_2O
《Science China Chemistry》1991年第2期129-134,共6页游效曾 陈颉 韩世莹 眭云霞 
An X-band EPR study on a Na_3(CrMo_6O_(24)H_6)·8H_2O single crystal diluted by its isomor-phic compound Na_3(AlMo_6O_(24)H_6)·8H_2O at room temperature is reported. Using the least squares-fitting method to simulate...
关键词：electron PARAMAGNETIC resonance PHOTOREACTION POLYOXOMOLYBDATES zero field SPLITTING 
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