financially supported by the Zhejiang Provincial Natural Science Foundation,China(No.LY23B040003);the Science Foundation of Zhejiang Sci-Tech University,China(No.22062026-Y)。
Nanographenes(NGs)with twisted backbones are emerging as new candidates for chiroptical materials.In this work,we describe a new strategy for synthesizing a[10]twistacene-embedded NG which exhibits a rare flag-hinge-l...
Fundamental Research Funds for the Central Universities;Natural Science Foundation of Tianjin Municipality,Grant/Award Number:23JCJQJC00110;National Natural Science Foundation of China,Grant/Award Number:52172045;National Key Research and Development Program of China,Grant/Award Numbers:2022YFA1204500,2022YFA1204504。
In recent years,the precisely controlled synthesis of chiral twisted molecular carbons has emerged as a forefront topic in the research of carbon materials.Molecular carbons refer to carbon nanomaterials synthesized w...
fundings by the National Natural Science Foundation of China(22371054,22301045);the Foundation of Basic and Applied Basic Research of Guangdong Province(2020B1515120024,2024A1515012801);Science and Technology Planning Project of Guangdong Province(2021A0505030066,2023A0505050164);Z.X.acknowledges a startup fund from A^(*)STAR(SC25/22-119116).
Organic radicals feature versatile unpaired electrons key for photoelectronic and biomedical applications but remain difficult to access in stable concentrated forms.We disclose easy generation of stable,concentrated ...
Financial support from the Ministry of Education Singapore under the AcRF Tier 1(MOE T1 RG11/21)and AcRF Tier 2(MOE-T2EP10221-0002);The Deutsche Forschungsgemeinschaft via grants(nos.SCHI 619/13 and EB535/1-1);the GRK(Research Training Group)2204“Substitute Materials for Sustainable Energy Technologies”;the LOEWE Program of Excellence of the Federal State of Hesse(LOEWE Focus Group PriOSS“Principles of On-Surface Synthesis”);the National Natural Science Foundation of China(grant nos.21790053,51821002,and 22072103);the National Major State Basic Research Development Program of China(grant nos.2017YFA0205000 and 2017YFA0205002);the Collaborative Innovation Center of Suzhou Nano Science&Technology;the 111 Project are also acknowledged for their financial support.
A highly distorted chiral nanographene structure composed of triple corannulene-fused[5]helicenes is prepared with the help of the Heck reaction and oxidative photocyclization with an overall isolated yield of 28%.The...
the financial support from the National Natural Science Foundation of China(grant nos.21975260 and 22175180);the National Natural Science Foundation of China-National Research Council of Italy(NSFC-CNR)Exchange Program of NSFC(grant no.22011530391);The GIWAXS measurements were performed at SPring-8 with the approval of the Japan Synchrotron Radiation Research Institute(grant nos.2022A1654,2022A1777,and 2022A1822).
Imbalanced charge-carrier extraction remains an issue aggravating interfacial charge accumulation and recombination.More hopping transport channels could accelerate the extraction of charge.Here,we demonstrated an eff...
financially supported by the National Natu-ral Science Foundation of China(Nos.51872234,52222204,and 52002322);the Natural Science Basic Research Plan in Shaanxi(No.2020JQ-154);the Key R&D Program of Shaanxi Province(No.2019ZDLGY04-02);the China Postdoctoral Science Foundation(No.2020M683556).
Both high thermal conductivity(K)and large cross-sectional area are essential for thermal dissipation materials to maximize their heat transfer capability.However,the drastic decrease of K values with the increased th...
supported by the National Natural Science Foundation of China(Nos.21871298,91956118)。
We report the synthesis and characterization of a fan-shaped chiral nanographene 1,which is composed of 6 hexabenzocoronene subunits with 216 conjugated carbon atoms.In the dehydrocyclization reaction,38 C–C bonds ar...
supported by the General Research Fund 14300919 from the Research Grant Council of Hong Kong and a Research Matching Grant from the University Grants Committee(Hong Kong).
Two molecular nanocarbons result from merging a negatively curved nanographene and a carbon nanoring in two constitutional isomers of D2 and C2v symmetry,respectively.They were synthesized by attachment o f C-shaped p...
supported by the National Natural Science Foundation of China(No.61901200);the National Recruitment Program for Young Professionals(No.132310976002);the Yunnan Fundamental Research Projects(Nos.2019FD041,202101AV070008,202101AW070010 and 202101AU070043);the Strategic Priority Research Program of Chinese Academy of Sciences(No.XDB30000000);the Dongguan Innovation Research Team Program。
The magnetism of nanographene is dominated by the structure of its carbon skeleton.However,the magnetism engineering of nanographene is hindered due to finite precursors.Here,we demonstrate an ingenious synthetic stra...
the National Natural Science Foundation of China(Grant Nos.51761135130 and 61888102);the National Key R&D Program of China(Grant Nos.2018YFA0305800 and 2019YFA0308500);DFG EnhanceNano(Grant No.391979941);the Strategic Priority Research Program of Chinese Academy of Sciences(Grant No.XDB30000000);the International Partnership Program of Chinese Academy of Sciences(Grant NO.112111KYSB20160061);the K.C.Wong Education Foundation.Part of the research was performed in the Key Laboratory of Vacuum Physics,Chinese Academy of Sciences.Computational resources were provided by the National Supercomputing Center in Tianjin Municipality,China.
Nanographenes(NGs)can be embedded with predesigned dopants or nonhexagonal rings to tailor the electronic properties and provide ideal platforms to study the unique physical and chemical properties.Here,we report the ...