NITROALKANE

作品数:5被引量:3H指数:1
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相关领域:理学更多>>
相关期刊:《Chinese Journal of Structural Chemistry》《Chinese Journal of Chemistry》《Chinese Chemical Letters》更多>>
相关基金:国家自然科学基金更多>>
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Understanding the Initial Decomposition Pathways of the n-Alkane/Nitroalkane Binary Mixture
《Chinese Journal of Chemistry》2013年第8期1087-1094,共8页Yulei Guan Ying Zhang Chunhai Yi Bolun Yang 
Addition of nitroalkanes into n-alkanes can lower the activation barriers of free-radical production and acceler- ate the decomposition of n-alkanes at relatively low temperatures. Four initial decomposition mechanism...
关键词:free radical initial decomposition mechanism computational chemistry hydrogen-abstraction bimol-ecular 
Density Functional Calculations of C–NO_2 Bond Dissociation Energies for Nitroalkanes Molecules被引量:1
《Chinese Journal of Structural Chemistry》2007年第12期1481-1485,共5页李小红 张瑞州 张现周 杨向东 程新路 
The project was supported by the National Natural Science Foundation of China (No. 10574096 and 10676025)
Bond dissociation energies for the removal of nitrogen dioxide group in some nitroalkane energetic materials have been calculated by using the three hybrid density functional theory (DFT) methods B3LYP, B3PW91 and B...
关键词:bond dissociation energy density functional calculation nitroalkane energetic compound 
A Facile and Efficient Synthesis of Substituted Pyrroles by Three Component Coupling Reaction of Amines, Aldehydes and Nitroalkanes
《Chinese Chemical Letters》2003年第9期893-896,共4页Yi Song XIAO, Yan Guang WANG Department of Chemistry, Zhejiang University, Hangzhou 310027 
This work is financially supported by the National Natural Science Foundation of China(No.29972037).
A facile and efficient synthesis of highly substituted pyrroles has been achieved by a one-pot three-component coupling reaction of aldehyde, amine and nitroalkane by triethyl orthoformate.
关键词:PYRROLE NITROALKANE aldehyde. 
Synthesis of Substituted Pyrroles via Ultrasound Assisted Three-component Coupling Reaction of Amines, α,β-Unsaturated Aldehydes and Nitroalkanes
《Chinese Journal of Chemistry》2003年第5期562-565,共4页肖贻崧 王彦广 
ProjectsupportedbytheNationalNaturalScienceFoundationofChina (No .2 9972 0 3 7)
An efficient synthesis of substituted pyrroles via ultrasound assisted three component coupling reaction of amines with α,β unsaturated aldehydes and nitroalkanes is reported.
关键词:amine  pyrrole  ultrasound    α β unsaturated aldehyde  nitroalkane  one  pot synthesis 
MICHAEL ADDITION OF NITROALKANE TO α,β-UNSATURATED CARBONYL COMPOUNDS ON KF / Al_2O_3/ PEG4000被引量:2
《Chinese Chemical Letters》1992年第3期159-160,共2页Lian An L1AO’ Qi Zhen GUO Bang Ji LI Xiao Yia WU Dept. of Chem., Xiamen Univ, Fujian 361005 
Michael addition of nitroalkanes to α,β-unsaturated carbonyl compounds occurs in the presence of KF/AI_2O_3/PEG4000 without solvent.Yields are fair to good and work-ups are easy.
关键词:UNSATURATED CARBONYL COMPOUNDS ON KF MICHAEL ADDITION OF NITROALKANE TO AL2O3 PEG4000 
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