supported by the National Natural Science Foundation of China(Nos.22171002 and 21603001);the Wanjiang Scholar Program,and the Natural Science Foundation of Anhui Province(No.2108085MB54).
1.Introduction Metal ions have played a vital role in various living systems and in-dustrial applications for a long time[1].Among them,Fe3+is a basic component of hemoglobin,and undertakes the responsibility of biolo...
supported by the High-level Teachers in Beijing Municipal Universities in the Period of 13th Five-year Plan (CIT&TCD201904044);URT program of Beijing Institute of Petrochemical Technology (2021J00003)
By using solvothermal method,a one-dimensional chain compound[KEu_(2)(FDCA)_(3)(H_(2)O)_(9)·0.5(FDCA)](1)was synthesized.Single-crystal X-ray diffraction data reveal that 1 crystallizes in monoclinic system,space gro...
supported by the NSF of China(21827813,21921001,22075283);Scientific Research Fund of Natural Science Foundation of Fujian Province(2020J01115);the Youth Innovation Promotion Association of CAS(No.20200303)。
A new quaternary metal thiophosphate,Cs_(2)Ga_(3)PS_(8),in triclinic P1^(-) space group has been successfully synthesized by a reactive-flux method.Its structural framework is derived from well-known AM^(Ⅲ)M^(Ⅳ)Q_(4...
the NSF of China(21703247);the Science Foundation of Fujian Province(2018J05029,2019J05156,2019H0053)。
A new rare earth organic complex with a double interleaved structure,namely[Sm(BDC)1.5(DMF)(H2O)]n(H2BDC=1,4-benzenedicarboxylic acid,DMF=N,N΄-dimethyl formamide)was synthesized.The crystal structure is of triclinic,s...
supported by the Natural Science Foundation of Hunan Province(2020JJ6041);the Foundation of Key Laboratory of Functional Organometallic Compounds of Hunan Province(MO20K04);the Center for Functionalization of Metal-Organic Frameworks Materials Studies(KYJG1082)。
Two new bearing Bi(Ⅲ) supramolecular compounds [Bi(pydcH)_(3)(Bi(pydcH)(pydcH_(2))(pydc)(Bi(pydcH)(pydcH_(2))(pydc)](1) and {[Bi(pydcH)_(3)]·(H_(2)O)_(5)(Dmap)}_(2)(2) have been successfully synthesized via hydrothe...
supported by the Foundation of Key Laboratory of Functional Metal-organic Compounds of Hunan Province(MO20K05);the Foundation of Key Laboratory of Functional Organometallic Materials;University of Hunan Province。
A new europium(Ⅲ)complex Eu(C_(20)H_(14)O_(3)N)_(3)(2,2'-bipy)(H2O)·H2O has been synthesized with2-diphenylanine carbonyl benzoic acid and 2,2'-bipyridine as ligands.Crystal data for the complex are as follows:tricl...
Supported by the the Science and Technology Research Project of Hubei Provincial Department of Education(No.Q20194301);the Cultivating Scientific Research Project of Jingchu University of Technology(No.PY201901);the Third Batch of Hubei Provincial Youth Talent Development Plan Project(QNYC201901)。
In this work,a cis-dicyanoiron(Ⅱ)building block,cis-FeⅡ(bpy)2(CN)2(1,bpy=2,2?-bipyridine),has been prepared and fully characterized by IR,electronic absorption spectra,elemental analysis,cyclic voltammetry and singl...
supported by the Foundation of Key Laboratory of Functional Metal-organic Compounds of Hunan Province(MO20K05);Hunan Provincial Natural Science Foundation of China(2019JJ60021,2019JJ50013);the Scientific Research Found of Hunan Provincial Education Department of China(17A049);Industry and Research Key Project of Hengyang City(2019jhzx1093,2018KJ016,2017KJ155,2017KJ193)。
A new terbium(Ⅲ)complex Tb2(C15H11O3)6(2,2?-bipy)2 has been synthesized with 2-(4-methylbenzoyl)benzoic acid and 2,2?-bipy ligands.Crystal data for the complex:monoclinic,space group P21/n,a=14.9738(5),b=13.5469(4),c...
Supported by the Science and Technology Research Project of Hubei Provincial Department of Education(No.Q20194301);the Cultivating Scientific Research Project of Jingchu University of Technology(No.PY201901)。
In this work,a terpyridine ligand L,(4΄-phenyl-2,2΄:6΄,2΄΄-terpyridine),was synthesized and fully characterized.Interactions of the ligand with selected metal ions like Cu(Ⅱ),Fe(Ⅲ),Pb(Ⅱ),Fe(Ⅱ),Cr(Ⅲ),Cd(Ⅱ),Co(Ⅱ)...
supported by the cooperative project of Hengyang Normal University with Hengyang Yile New Materials Co.,Ltd.(HXKJ201905);the Natural Science Foundation of Hunan Province(2019JJ60021,2019JJ50013);the Scientific Research Found of Hunan Provincial Education Department of China(17A049);the Industry and Research Key Project of Hengyang City(2018k KJ016,2017KJ155,2017KJ193)
A new terbium(Ⅲ complex Tb(C20H14O3N)3(C12H8N2)(H2O)·H2O has been synthesized with 2-diphenylanine carbonyl benzoic acid and 1,10-phenanthroline as ligands. Crystal data for the complex are as follows: triclinic, ...