OZONOLYSIS

作品数:23被引量:20H指数:3
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相关领域:理学更多>>
相关期刊:《Journal of Zhejiang University-Science B(Biomedicine & Biotechnology)》《Journal of Materials Science and Chemical Engineering》《Chinese Journal of Chemistry》《Science China Chemistry》更多>>
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Effect of industrial alkene ozonolysis on atmospheric H_(2)SO_(4)formation
《Journal of Environmental Sciences》2025年第4期466-476,共11页Xing Wang Xiaowen Shi Youling Jiang Yan Ma Jun Zheng 
supported by the National Natural Science Foundation of China(Nos.41975172,42275116,and 41730106).
This study has employed the master chemical mechanism(MCM)to investigate the influence of the ozone oxidation pathways in the atmospheric formation of H_(2)SO_(4)from shortchain olefins in industrialized areas.In-situ...
关键词:Gaseous sulfuric acid Alkene ozonation reaction MCM model Sensitivity analysis 
Effects of isoprene on the ozonolysis of△^(3)-carene andβ-caryophyllene:Mechanisms of secondary organic aerosol formation and cross-dimerization
《Journal of Environmental Sciences》2025年第4期556-570,共15页Zhaoyan Zhang Yingqi Zhao Ya Zhao Xiangyu Zang Hua Xie Jiayue Yang Weiqing Zhang Guorong Wu Gang Li Xueming Yang Ling Jiang 
supported by the National Natural Science Foundation of China(Nos.92361302,22125303,92061203,and 22288201);the National Key Research and Development Program of China(No.2021YFA1400501);the Innovation Program for Quantum Science and Technology(No.2021ZD0303304);Dalian Institute of Chemical Physics(No.DICP DCLS201702);Chinese Academy of Sciences(No.GJJSTD20220001).
Elucidating the mutual effects between the different volatile organic compounds(VOCs)is crucial for comprehending the formation mechanism of atmospheric secondary organic aerosols(SOA).Here,the mixed VOCs experiments ...
关键词:Secondary organic aerosol △^(3)-Carene andβ-caryophyllene OZONOLYSIS Cross reaction ISOPRENE 
Carbonyl-amine condensation coupled ozonolysis of dipropylamine and styrene:Decay kinetics,reaction mechanism,secondary organic aerosol formation and cytotoxicity
《Journal of Environmental Sciences》2025年第3期444-455,共12页Wanying Li Jiangyao Chen Qinhao Lin Yuemeng Ji Taicheng An 
supported by the National Natural Science Foundation of China(Nos.42177354 and 42020104001);the National Key R&D Program of China(No.2019YFC0214402);the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program(No.2017BT01Z032);Guangdong Basic and Applied Basic Research Foundation(No.2019B151502064).
Oxidation of organic amines(OAs)or aromatic hydrocarbons(AHs)produces carbonyls,which further react with OAs to form carbonyl-amine condensation products,threatening environmental quality and human health.However,ther...
关键词:Organic amines(OAs) Aromatic hydrocarbons(AHs) Coupled ozonolysis Carbonyl-amine condensation Secondary pollution Toxicity assessment 
Ozonolysis of ketoprofen in polluted water:Reaction pathways,kinetics,removal efficiency,and health effects
《Journal of Environmental Sciences》2025年第1期451-461,共11页Qiong Mei Zhaoxu Qiu Jinchan Jiang Mingxue Li Qizhao Wang Maoxia He 
supported by the National Nature Science Foundation of China(Nos.21777087 and 22276109);the Natural Science Basic Research Fund of Shaanxi Province(No.2023-JC-QN-0099);the Fundamental Research Funds for the Central Universities,CHD(No.300102352101);the Innovative Research Team for Science and Technology of Shaanxi Province(No.2022TD-04).
Ketoprofen(KET),as a non-steroidal anti-inflammatory drug frequently detected in aqueous environments,is a threat to human health due to its accumulation and low biodegradability,which requires the transformation and ...
关键词:Ozonolysis Ketoprofen Degradation mechanisms OH radicals Aquatic toxicity Degradation efficiency 
Wintertime ozone surges:The critical role of alkene ozonolysis
《Environmental Science and Ecotechnology》2024年第6期304-313,共10页Jin Yang Yangzong Zeren Hai Guo Yu Wang Xiaopu Lyu Beining Zhou Hong Gao Dawen Yao Zhanxiang Wang Shizhen Zhao Jun Li Gan Zhang 
Research Grants Council(RGC)of the Government of the Hong Kong Special Administrative Region(PolyU 152124/21 E and N_PolyU530/20);research support scheme of Research Institute for Land and Space at The Hong Kong Polytechnic University(1-CD79);Start-up Fund for RAPs under the Strategic Hiring Scheme of the Hong Kong Polytechnic University(1-BD3T).
Ozone(O_(3))pollution is usually linked to warm weather and strong solar radiation,making it uncommon in cold winters.However,an unusual occurrence of four high O_(3)episode days(with maximum hourly concentrations exc...
关键词:Ozone pollution Winter ALKENES Radical chemistry PBM-MCM 
Ozonolysis-oxidation-driven top-down strategy for the target preparation of ultrathin 2D metalorganic framework monolayers
《Industrial Chemistry & Materials》2024年第1期110-117,共8页Baoliu Zhuo Aidong Tan Zhipeng Xiang Jinhua Piao Wenhao Zheng Kai Wan Zhenxing Liang Zhiyong Fu 
The work described in this paper was jointly supported by the National Natural Science Foundation of China(No.U22A20417,21903026,21975081,21975079,22178126,22108085);China Postdoctoral Science Foundation(2022M711196);Science and Technology Program of Guangzhou(2023A04J1357);the SRP Program。
Two-dimensional metal–organic-framework(2D MOF)nanosheets with a modular nature and tunable structures exhibit a bright future for sensors,separation,and catalysis.Developing ultrathin 2D MOF nanosheets with unique p...
关键词:3D pillar-layered MOFs Ultrathin 2D MOF monolayers Top-down strategy Chemical exfoliation Ozonolysis-oxidation 
Atmospheric fate of typical liquid crystal monomers in the tropospheric gas,liquid,and granular phases
《Journal of Environmental Sciences》2024年第2期348-360,共13页Yanru Huo Zexiu An Mingxue Li Jinchan Jiang Yuxin Zhou Ju Xie Jianguo Zhang Maoxia He 
financially supported by the National Natural Science Foundation of China (Nos.22276109,21777087,and 21876099)。
Mineral aerosol particles significantly impact environmental risk prediction of liquid crystal monomers(LCMs).In this work,we investigated the reaction mechanisms and kinetics of three typical LCMs(4-cyano-3,5-difluor...
关键词:Liquid crystal monomers(LCMs) OZONOLYSIS TiO_(2)clusters Adsorption Toxicity assessment 
Vacuum Ultraviolet Free-Electron Laser Photoionization Mass Spectrometry of Alpha-pinene Ozonolysis被引量:1
《Chinese Journal of Chemical Physics》2022年第2期281-288,I0002,共9页Xiangyu Zang Zhaoyan Zhang Chong Wang Tiantong Wang Huijun Zheng Hua Xie Jiayue Yang Dongxu Dai Guorong Wu Weiqing Zhang Gang Li Xueming Yang Ling Jiang 
financially supported by the National Natural Science Foundation of China(No.22125303,No.92061203,and No.21688102);the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB17000000);Dalian Institute of Chemical Physics(DICP DCLS201701);Chinese Academy of Sciences(No.GJJSTD20190002);K.C.Wong Education Foundation(No.GJTD-2018-06)。
α-pinene is the most abundant monoterpene that represents an important family of volatile organic compounds.Molecular identification of key transient compounds during theα-pinene ozonolysis has been proven to be a c...
关键词:Vacuum ultraviolet free-electron laser PHOTOIONIZATION Mass spectrometry Volatile organic compound OZONOLYSIS 
Kinetic and mechanism studies of the ozonolysis of three unsaturated ketones被引量:1
《Journal of Environmental Sciences》2020年第9期23-32,共10页Weiran Li Meifang Chen Yi Chen Shengrui Tong Maofa Ge Yucong Guo Yunhong Zhang 
supported by the National Key Research and Development Program of China(No.2016YFC0202200);the National Natural Science Foundation of China(Nos.41571130022 and 91544227);Beijing Nova Program(No.2018113);the Youth Innovation Promotion Association Chinese Academy of Sciences(CAS)(No.2017042)
Reaction rate constants and products of 1-octen-3-one,3-octen-2-one and 4-hexen-3-one with ozone were studied in a 100-L fluorinated ethylene propylene(FEP) Teflon film bag using absolute rate method at 298 ± 1 K and...
关键词:UNSATURATED OZONE MECHANISM 
Transient species in the ozonolysis of tetramethylethene
《Journal of Environmental Sciences》2020年第9期210-216,共7页Xiaolu Yang Jianguo Deng Dong Li Jianhua Chen Yisheng Xu Kai Zhang Xiaona Shang Qing Cao 
primarily supported by National Key R&D Program of China(No.2019YFC0214200);National Environmental Protection Public Welfare Industry Research Project(No.201509010);National Basic Science Research Program of Chinese Research Academy of Environmental Sciences(No.JY-21277132-201309406);the National Natural Science Foundation of China(No.21277132)
The reaction of alkenes with ozone has great effect on atmospheric oxidation,its transient species can produce OH radicals and contribute to the formation of secondary organic aerosols(SOA).In the present study,the re...
关键词:OZONE TRANSIENT slowly 
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