This work was supported by the National Key R&D Program of China[2022YFE0110400];the National Natural Science Foundation of China[52122207,52173245,U20A20337,52130206,and 52221006];the Fundamental Research Funds for the Central Universities[CLYY2022].
Developing highly stable and efficient catalysts for oxygen evolution reaction(OER)is extremely important to sustainable energy conversion and storage,but improved efficiency is largely hindered by sluggish reaction k...
supported by the National Natural Science Foundation of China(Grant Nos.12275009,12192280,and 11935004);the National Magnetic Confinement Fusion Energy Research Project(No.2021YFE031100).
The properties of high entropy pyrochlore have been studied extensively,but there is no consistent conclusion on its radiation tolerance.Besides,the mechanism of the high entropy effect on the radiation tolerance of p...
Project supported by the National Natural Science Foundation of China(51621091,51321061,51021002);the National Science and Technology Major Project(2017-Ⅵ-0020-0093)。
A density functional theory(DFT)study was employed to investigate the mechanical property,thermal conductivity,Debye temperature,electronic structure and defect chemistry of(Gd_(1-x)Sm_(x))_(2)Zr_(2)O_(7).All the(Gd_(...
Mesoporous structured metal oxides exhibit many active applications.However,the synthesis of crystalline metal oxides with a ternary composition while maintaining satisfactory pore features is challeng-ing.Typically,h...
The authors are grateful to L.A.Shilkina for X-ray phase analysis of the BZN samples.The reported study was funded by Russian Science Foundation(RSF)-research projects no.20-72-00086(BZN ceramics preparation,dielectric mea-surements);At RTU MIREA,the work was supported by the Ministry of Science and Higher Education of Russia(project FSFZ 0706-2020-2022,Bi2Ti2O7 single crystal growth),the equipment of the Center for Collective Use of RTU MIREA was used.
The comparative analysis of the dielectric properties of bismuth-containing pyrochlores with different manifestation of atomic order/disorder was carried out.We examined the dielectric properties(including behavior in...
High entropy pyrochlores(HEP)are potential candidates as dispersoids in the oxide dispersed strengthened steels or alloys,which can be used in nuclear reactors and supercritical boilers.For the first time,HEP oxides Y...
supported by the National Natural Science Foundation of China(No.51602188);the Program for Professor of Special Appointment(Eastern Scholar)by Shanghai Municipal Education Commission(No.TP2015040)。
Various excellent properties of rare earth zirconate and stannate pyrochlores are close related with their native point defects.First-principles calculations are performed to systematically investigate the point defec...
Financial support from the National Natural Science Foundation of China (Nos. 51532009, 51602324, and 51872405) are gratefully acknowledged.
High-entropy pyrochlore-type structures based on rare-earth zirconates are successfully produced by conventional solid-state reaction method. Six rare-earth oxides(La2O3, Nd2O3, Sm2O3, Eu2O3, Gd2O3, and Y2O3) and ZrO2...
The work was performed at the Los Alamos National Laboratory(LANL),an affirmative action equal opportunity employer,operated by Los Alamos National Security,LLC,for the National Nuclear Security Administration of the U.S.DOE under contract DE-AC52-06NA25396;Computational support for this work was provided by LANL’s high performance computing clusters.
Pyrochlore oxides(A2B2O7)are interesting for a number of technological applications,including radiation damage tolerance and as ionic conductors.Mixed pyrochlores—containing two A and/or two B site cations—provide e...
supported by the Seventh Framework Programme(Grant no.310750 THEBARCODE);Federal Agency of Scientific Institutions(Project 0303-2016-0013);Russian Ministry of High Education and Science
LnZrOx(Ln: La, Sm) mixed oxides of Ln: Zr = 1 were prepared by different methods(complex polymerized method, sorption of cations on starch from aqueous salt solution and conventional co-precipitation with additional r...