supported by the National Key Research and Development Program of China(Grant Nos.2023YFD1501400 and 2023YFD1500802);the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDA28020302);the National Natural Science Foundation of China(Grant Nos.42177214 and 41701309);the Shandong Provincial Natural Science Foundation(Grant No.ZR2023YQ030);the Liaoning Vitalization Talents Program(Grant Nos.XLYC2203058 and XLYC1902016);Shenyang Science and Technology Talent Program(Grant No.RC230102),and the Taishan Scholars(Grant No.202211306);We also acknowledge support from the K.C.Wong Education Foundation(Y.F.);the Youth Innovation Promotion Association CAS(Z.Q).
The application of nitrification inhibitors(NIs)and crop straw with nitrogen(N)fertilizers is a common practice aimed at enhancing soil N conservation and improving crop N use.However,their effects on gaseous N emissi...
supported by the National Natural Science Foundation of China(21988101 for Z.-J.S.,22201044 for D.-D.Z.,22071029 for F.L.);Fundamental Research Funds for the Central Universities(20720220010).
The reaction between tripodal trisamidophosphine ligand H_(3)PN_(3)^(Ar)and V(Mes)_(3)(THF)(Mes=mesityl)yields the vanadium(Ⅲ)complex(PN_(3)^(Ar))V(1)with an open site in the axial position,which could coordinate wit...
financially supported by CAS Project for Young Scientists in Basic Research (No.YSBR-050);the National Natural Science Foundation of China (Nos.92261113 and 222721809);Beijing Natural Science Foundation (No.2232035)。
Catalytic reduction of dinitrogen to ammonia under mild conditions remains an attractive topic for the purpose of lowering energy consumption.Three-atom metal clusters have been proved an ideal model to explore highly...
supported by the National Natural Science Foundation of China(Nos.21988101 and 22201013);Beijing Natural Science Foundation(No.2222008);supported by the High-performance Computing Platform of Peking University。
A nonsymmetrical PNN pincer ligand[6-(^(t)Bu_(2)PNH)C_(5)H_(4)N-2-(3-Mes)C_(3)H_(2)N_(2)]and its corresponding cobalt-N_(2)complex were synthesized and characterized.By the stoichiometric reaction of the PNN ligand li...
supported by the King Abdullah University of Science and Technology;supported by Agency for Science,Technology,and Research(SC22/23-82301U,SC22/23-82801U)。
Nitrogen fixation is a complex process involving the transfer of six electrons and protons.Diverging from the conventional Haber-Bosch process,which relies on hydrogen(H_(2))to provide both electrons and protons to re...
This work was supported by the National Natural Science Foundation of China(no.21972010);National Key Research and Development Program of China(No.2022YFC2105900);Beijing Natural Science Foundation(no.2192039).
The Haber–Bosch process is the dominant approach for NH3 production today,but the process has to be maintained at energy-intensive high temperatures and pressures.Li-mediated electrocatalytic dinitrogen reduction rea...
The authors regret that the incorrect permissions were provided in the figure captions of Fig.1–15 in the original article.The correct versions of the figures,including the updated permissions,are shown below.
supported by the Strategic Priority Research Program of Chinese Academy of Sciences(XDB36030300);the National Natural Science Foundation of China(21890750,U2032212);the Youth Innovation Promotion Association CAS(202092);and the Fundamental Research Funds for the Central Universities(WK2340000094).
Air has the advantage of abundance and easy availability,so it is suitable to be used as a synthetic raw material and energy source.However,the triggering of inert small molecules in the air,like O_(2),N2,and CO_(2),i...
This work was supported financially by the National Key R&D Program of China(Grant Nos.2018YFA0305900 and 2018YFA0703404);the National Natural Science Foundation of China under Grant Nos.21905159,11634004,51320105007,11604116,and 51602124,the Program for Changjiang Scholars and Innovative Research Team in the University of the Ministry of Education of China under Grant No.IRT1132;the Higher Educational Youth Innovation Science and Technology Program Shandong Province(Grant No.2022KJ183);GHfund B(Grant No.202202026143).
Synthesis pressure and structural stability are two crucial factors for highly energetic materials,and recent investigations have indicated that cerium is an efficient catalyst for N2 reduction reactions.Here,we syste...
supported by the Basic Science Center of Transformation Chemistry of Key Components of Air, the National Natural Science Foundation of China (21988101);supported by the High-performance Computing Platform of Peking University
The synthesis,characterization,and theoretical studies of titanium-μ-N_(2) complexes with di-anionic guanidinate ligands were reported as the first example of its kind.Thus,with(Me_(3)Si)_(2)N-guanidinate ligands,the...