Supported by the Program for New Century Excellent Talents in University of Henan Province (2005HANCET-02);the Natural Science Foundation of Henan Province, the Program for Training Young Excellent Cadreman Teachers in University of Henan Province, the Stress Foundation of Henan University(05ZDZR002)
A new organic-inorganic hybrid polyoxometalate based on Dawson-like polyoxotungstate anion [SbW18O60]9, formulated [Co(2,2′-bpy)3]2[Co(2,2′-bpy)2Cl][Co(2,2′-bpy)2]H2[SbW18O60]·4H2O (2,2′-bpy= 2,2′-bipyridine) ha...
Supported by the Natural Science Foundation of L iaoning Province of China(No.2 0 0 32 10 4 )
Organothiophosphoryl polyoxotungstate derivatives α-C_6H_(11)P(S)]_2X^(n+)W_(11)O_(39)^((8-n)-)(X=P, Si, Ge, Ga) were obtained by the reactions of the monovacant α-_2X^(n+)W_(11)O_(39)^((8-n)-)(X=P, Si, Ge, Ga) were...
A new organophosphazene polyoxotungstate, [(N3P3)(SiW11O39H2)3]12-, has been prepared by reaction of hexachlorocyclotriphosphazene with undecatungstosilicate, and characterized by elemental analysis, infrared spectros...