This study was financially supported by the National Natural Science Foundation of China(No.22101086);Guangdong Basic and Applied Basic Research Foundation(Nos.2023A1515140030 and 2024A1515030212).
Innovative advancements in the development of high-performance,eco-friendly adhesives are critical for meeting the demands of diverse applications in various industries.This study reports a significant leap in adhesiv...
Supported by the National Natural Science Foundation of China (21701120);the Science and Technology Innovation Project of Colleges and Universities in Shanxi Province (2020L0334);the Innovation and Entrepreneurship Training Program for College Students in Shanxi Province(20240778)。
The ruthenium multi-substituted polyoxotungstate,K_(7)[Si W_(9)O_(37)Ru_(4)(H_(2)O)_(3)Cl_(3)]·15H_(2)O(S1),was synthesized by a conventional aqueous solution containing the trilacunary Keggin-anionsβ-Na_(9)HSi W_(9...
support from the NSFs of China(grant nos.21773029,21971039,and 22171045).
Although the synthesis of giant lanthanide(Ln)-containing polyoxotungstates(POTs)has long been actively pursued,it remains challenging to encapsulate high-nuclearity Ln–O clusters in POT shells because of the highly ...
supported by the National Natural Science Foun-dation of China(Nos.21871077,21671054,21771052,22071042);the Program for Innovation Teams in Science and Technology in Universities of Henan Province(No.20IRTSTHN004).
An organic-inorganic hybrid Fe^(Ⅲ)–Pr^(Ⅲ)-included 2-germano-20-tungstate[Pr(H_(2)O)_(8)]2 H_(2)[Fe_(4)(H_(2)O)_(4)(pca)_(4) Ge_(2)W_(20)O_(72)]•34H_(2)O(Hpca=2-pyridinecarboxylic acid)(1)was hydrothermally prepare...
supported by the Foundation of Education Department of Henan Province(15A150037)
A new organic-inorganic hybrid sandwich-type polyoxotungstate [Cu(dien)-(H2O)2]2[{Cu(dien)(H2O)}3{Cu(4.5)W(0.5)(B-α-Sb W9O(33))2}](OH)4·7H2O(1, dien = diethylenetriamine) has been hydrothermally ...
Supported by theNNSFC(No.51108122);Open Project of State Key Laboratory of Urban Water Resource and Environment,Harbin Institute of Technology(No.QA201025);Fundamental Research Funds for the Central Universities(No.HIT.NSRIF.2010053);Science and Technology Innovation Talents Special Foundation of Harbin(2010RFQXG035 and 2007RFXXG018)
A new sandwiched polyoxometalate [HK11Cd4Cl2(PW9034)2]·18H2O (1), incor- porating a unique hybrid tetranuclear cadmium cluster (abbreviated to {Cd4}) with two trivacant polyanions [B-α-PW9O34]9-, has been hydr...
Supported by the Natural Science Foundation of Fujina Province(No.2008I0013);the Foundation of Education Committee of Fujian Provinc(No.JB11002)
A new supramolecular compound (4,4'-bipyH)4[SiW12O40](4,4'-bipy) (4,4'-bipy = 4,4'-bipyridine) was synthesized hydrothermally and characterized by single-crystal X-ray diffraction and IR spectrum. The crysta...
Supported by the National Natural Science Foundation of China (No. 31060121)
The utilization of polyoxometalates (POMs) or their derivatives as homogeneous or heterogeneous catalysts in alkene epoxidation is a subject of considerable research activity[1]. The limitation to the use of POMs in...
supported by the National Natural Science Foundation of China;the Program for New Century Excellent Talent in Henan University;the Foundation of Education Department of Henan Province;the Natural Science Foundation of Henan Province
A novel 3D polyoxotungstate [Ca(H2O)2][Ca(H2O)3]H2[P2W18O62]·9H2O(1) has been synthesized by the conventional aqueous solution method and characterized by IR spectrum,elemental analyses,single-crystal X-ray dif...
supported by the Analysis and Testing Foundation of Northeast Normal University
A new heteropolyoxotungstate [(C2H4N2)4(P4Co3W4O28H6)(H2C2O4)]n with a three-dimensional framework was hydrothermally synthesized.The compound crystallizes in a tetragonal system,space group I41/a with a = 17.1...