POLYOXOTUNGSTATE

作品数:27被引量:23H指数:3
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相关领域:理学更多>>
相关作者:李海楼张洁王晓妮赵俊伟陈利娟更多>>
相关机构:中国人民解放军河南大学更多>>
相关期刊:《Journal of Rare Earths》《Science China Chemistry》《Chemical Research in Chinese Universities》《Wuhan University Journal of Natural Sciences》更多>>
相关基金:国家自然科学基金河南省自然科学基金福建省自然科学基金国家重点基础研究发展计划更多>>
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Enhancing adhesive performance of polyvinyl alcohol with sub nanoscale polyoxotungstate clusters under extreme conditions
《Nano Research》2025年第2期432-441,共10页Pengcheng Cui Qiang Yu Jiadong Chen Kun Chen Panchao Yin 
This study was financially supported by the National Natural Science Foundation of China(No.22101086);Guangdong Basic and Applied Basic Research Foundation(Nos.2023A1515140030 and 2024A1515030212).
Innovative advancements in the development of high-performance,eco-friendly adhesives are critical for meeting the demands of diverse applications in various industries.This study reports a significant leap in adhesiv...
关键词:water-based adhesives POLYOXOTUNGSTATES nanocomposites interfacial toughness chaotropic effect 
Synthesis,Cytotoxicity,Apoptosis and Cell Cycle Arrest of a Ruthenium(II)-Substituted Keggin Polyoxotungstate
《Wuhan University Journal of Natural Sciences》2024年第5期461-470,共10页JIA Shifang HAO Xiuli WENYanzhen SHI Shaoqi ZHANG Yan 
Supported by the National Natural Science Foundation of China (21701120);the Science and Technology Innovation Project of Colleges and Universities in Shanxi Province (2020L0334);the Innovation and Entrepreneurship Training Program for College Students in Shanxi Province(20240778)。
The ruthenium multi-substituted polyoxotungstate,K_(7)[Si W_(9)O_(37)Ru_(4)(H_(2)O)_(3)Cl_(3)]·15H_(2)O(S1),was synthesized by a conventional aqueous solution containing the trilacunary Keggin-anionsβ-Na_(9)HSi W_(9...
关键词:ruthenium multi-substituted polyoxometalate CYTOTOXICITY cell apoptosis cell cycle arrest 
Giant Ln_(30)-Cluster-Embedded Polyoxotungstate Nanoclusters with Exceptional Proton-Conducting and Luminescent Properties被引量:2
《CCS Chemistry》2022年第9期2938-2945,共8页Zhong Li Zhi-Hao Lv Hao Yu Yan-Qiong Sun Xin-Xiong Li Shou-Tian Zheng 
support from the NSFs of China(grant nos.21773029,21971039,and 22171045).
Although the synthesis of giant lanthanide(Ln)-containing polyoxotungstates(POTs)has long been actively pursued,it remains challenging to encapsulate high-nuclearity Ln–O clusters in POT shells because of the highly ...
关键词:POLYOXOTUNGSTATE LANTHANIDE highnuclearity proton conductivity luminescence 
A unique organic-inorganic hybrid Fe^(Ⅲ)–Pr^(Ⅲ)-included 2-germano-20-tungstate and its electrochemical biosensing properties
《Chinese Chemical Letters》2022年第5期2630-2634,共5页Xiaoyi Liu Limin Cui Jun Jiang Fan Ji Junwei Zhao 
supported by the National Natural Science Foun-dation of China(Nos.21871077,21671054,21771052,22071042);the Program for Innovation Teams in Science and Technology in Universities of Henan Province(No.20IRTSTHN004).
An organic-inorganic hybrid Fe^(Ⅲ)–Pr^(Ⅲ)-included 2-germano-20-tungstate[Pr(H_(2)O)_(8)]2 H_(2)[Fe_(4)(H_(2)O)_(4)(pca)_(4) Ge_(2)W_(20)O_(72)]•34H_(2)O(Hpca=2-pyridinecarboxylic acid)(1)was hydrothermally prepare...
关键词:POLYOXOMETALATE Germanotungstate Heterometallic polyoxotungstate ELECTROCHEMISTRY BIOSENSING 
A New 1-D Organic-inorganic Hybrid Polyoxotungstate Constructed from Sandwich-type Polyanions and Copper^Ⅱ-organoamine Complexes被引量:4
《Chinese Journal of Structural Chemistry》2017年第5期805-811,共7页李杰 田淑芳 刘云 马鹏涛 
supported by the Foundation of Education Department of Henan Province(15A150037)
A new organic-inorganic hybrid sandwich-type polyoxotungstate [Cu(dien)-(H2O)2]2[{Cu(dien)(H2O)}3{Cu(4.5)W(0.5)(B-α-Sb W9O(33))2}](OH)4·7H2O(1, dien = diethylenetriamine) has been hydrothermally ...
关键词:polyoxometalate  sandwich  copper  magnetic properties 
A New Sandwiched-type Polyoxotungstate Containing {Cd_4} Transition-metal Cluster:Synthesis,Structure and Luminescent Property
《Chinese Journal of Structural Chemistry》2013年第12期1805-1812,共8页FAN Shu-Ge ZHANG Xiao ZHANG Nan-Xi YI Zhi-Hui LIU Lei HUANG Yan-Ping 
Supported by theNNSFC(No.51108122);Open Project of State Key Laboratory of Urban Water Resource and Environment,Harbin Institute of Technology(No.QA201025);Fundamental Research Funds for the Central Universities(No.HIT.NSRIF.2010053);Science and Technology Innovation Talents Special Foundation of Harbin(2010RFQXG035 and 2007RFXXG018)
A new sandwiched polyoxometalate [HK11Cd4Cl2(PW9034)2]·18H2O (1), incor- porating a unique hybrid tetranuclear cadmium cluster (abbreviated to {Cd4}) with two trivacant polyanions [B-α-PW9O34]9-, has been hydr...
关键词:transition metal substituted polyoxometalates tetranuelear cadmium cluster SANDWICH-TYPE 
Synthesis, Crystal Structure and Photocatalytic Properties of a Supramolecular Assembly Based on Keggin Polyoxotungstate
《Chinese Journal of Structural Chemistry》2012年第6期835-842,共8页陈顺玉 陈心琴 林深 
Supported by the Natural Science Foundation of Fujina Province(No.2008I0013);the Foundation of Education Committee of Fujian Provinc(No.JB11002)
A new supramolecular compound (4,4'-bipyH)4[SiW12O40](4,4'-bipy) (4,4'-bipy = 4,4'-bipyridine) was synthesized hydrothermally and characterized by single-crystal X-ray diffraction and IR spectrum. The crysta...
关键词:Keggin-type polyoxotungstate supramolecular architecture HYDROTHERMALSYNTHESIS Rhodamine-B dye photocatalysis degradation 
Mono-lacunary PrIII-Polyoxotungstate: Epoxidation of Alkenes with Unusual Selectivity被引量:1
《Chinese Journal of Structural Chemistry》2011年第8期1183-1188,共6页杨峰 马莉 马致媛 
Supported by the National Natural Science Foundation of China (No. 31060121)
The utilization of polyoxometalates (POMs) or their derivatives as homogeneous or heterogeneous catalysts in alkene epoxidation is a subject of considerable research activity[1]. The limitation to the use of POMs in...
关键词:EPOXIDATION homogeneous catalysis PRASEODYMIUM POLYOXOMETALATES 
A Novel 3D Polyoxotungstate Constructed from Dawson Polyanions and Alkaline Earth Cations被引量:1
《Chinese Journal of Structural Chemistry》2010年第6期940-946,共7页陈丹云 王军生 杨冬 王敬平 牛景杨 
supported by the National Natural Science Foundation of China;the Program for New Century Excellent Talent in Henan University;the Foundation of Education Department of Henan Province;the Natural Science Foundation of Henan Province
A novel 3D polyoxotungstate [Ca(H2O)2][Ca(H2O)3]H2[P2W18O62]·9H2O(1) has been synthesized by the conventional aqueous solution method and characterized by IR spectrum,elemental analyses,single-crystal X-ray dif...
关键词:POLYOXOTUNGSTATE CALCIUM DAWSON alkaline earth 
A New Heteropolyoxotungstate with a Three-dimensional All-inorganic Framework [(C_2H_4N_2)_4(P_4Co_3W_4O_(28)H_6)(H_2C_2O_4)]_n
《Chinese Journal of Structural Chemistry》2010年第6期962-966,共5页孙军 孙宇 陈亚光 孟凡霞 
supported by the Analysis and Testing Foundation of Northeast Normal University
A new heteropolyoxotungstate [(C2H4N2)4(P4Co3W4O28H6)(H2C2O4)]n with a three-dimensional framework was hydrothermally synthesized.The compound crystallizes in a tetragonal system,space group I41/a with a = 17.1...
关键词:hydrothermal synthesis POLYOXOTUNGSTATE three-dimensional framework W-O chains organic ammine 
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