POLYOXOTUNGSTATES

作品数:16被引量:9H指数:1
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相关领域:理学更多>>
相关作者:崔凤云更多>>
相关机构:北京理工大学更多>>
相关期刊:《Chemical Research in Chinese Universities》《Chinese Journal of Chemistry》《Journal of Rare Earths》《Chinese Journal of Structural Chemistry》更多>>
相关基金:国家自然科学基金中国科学院知识创新工程国家重点基础研究发展计划更多>>
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Enhancing adhesive performance of polyvinyl alcohol with sub nanoscale polyoxotungstate clusters under extreme conditions
《Nano Research》2025年第2期432-441,共10页Pengcheng Cui Qiang Yu Jiadong Chen Kun Chen Panchao Yin 
This study was financially supported by the National Natural Science Foundation of China(No.22101086);Guangdong Basic and Applied Basic Research Foundation(Nos.2023A1515140030 and 2024A1515030212).
Innovative advancements in the development of high-performance,eco-friendly adhesives are critical for meeting the demands of diverse applications in various industries.This study reports a significant leap in adhesiv...
关键词:water-based adhesives POLYOXOTUNGSTATES nanocomposites interfacial toughness chaotropic effect 
Effect of Na(Ⅰ)-H2O clusters on self-assembly of sandwich-type U(Ⅵ)-containing silicotungstates and the efficient catalytic activity for the synthesis of substituted phenylsulfonyl-1H-pyrazoles被引量:1
《Tungsten》2022年第2期149-157,共9页Ke Li Xiao-Ling Lin Kai Zeng Xiao-Fei Gao Wei Cen Yu-Feng Liu Guo-Ping Yang 
supported by the National Natural Science Foundation of China (Grant No. 22001034);the Open Fund of the Jiangxi Province Key Laboratory of Synthetic Chemistry (Grant No. JXSC202008);the Research Found of East China University of Technology (Grant Nos. DHBK2019264, DHBK2019265, DHBK2019267)
In this study,a sandwich-type uranium(Ⅵ)-containing silicotungstate KNa11H2(H2O)30[Na(UO2)(SiW9O34)]2·8H2O(1)with new three-dimensional(3D)structure was synthesized and characterized using single-crystal X-ray diffr...
关键词:Uranium POLYOXOTUNGSTATES Condensation reaction Phenylsulfonyl-1H-pyrazoles 
Multicomponent Cooperative Assembly of Nanoscale Boron-Rich Polyoxotungstates with 22 and 30 Boron Atoms被引量:1
《CCS Chemistry》2022年第4期1305-1314,共10页Yi Chen Zheng-Wei Guo Xin-Xiong Li Shou-Tian Zheng Guo-Yu Yang 
the financial support from the National Natural Science Foundation of China(NSFC)(nos.21773029,21831001,and 21971039).
This work demonstrates that the introduction of positive lanthanide(Ln)and transition metal(TM)cations into polyoxotungstates(POTs)to stabilize negative oxoboron clusters is a feasible and general synthetic strategy f...
关键词:POLYOXOTUNGSTATES MULTICOMPONENT BORON LANTHANIDE transition metal 
Comparing the Structures of Two Allomorphic Polyoxotungstates and the Difference in Weak Interactions by Thermal-dependent 2D-COS IR to Identify
《Chinese Journal of Structural Chemistry》2015年第11期1665-1674,共10页刘婷玉 陈义平 黄晓辉 陈宁 黄梦梦 孙燕琼 
supported by the NNSFC(No.21473030,1371033);Fujian Provincial Natural Science Foundation(2013J01042);the Open Fund of State Key Laboratory of Structural Chemistry(20130015)
A three-dimensional (3D) Keggin-type heteropolytungstate{Zn(phen)3}3[ZnW12O40]·9H2O 1 (phen = 1,10-phenanthroline) has been synthesized through a conventional hydrothermal synthesis and was characterized by X-r...
关键词:Keggin-type polyoxotungstates hydrothermal synthesis thermal-dependent 2D-IR correlation spectroscopy Raman spectra luminescence 
Zero-and One-dimensional Organic-inorganic Hybrid Compounds Based on Monovacant Keggin Polyoxotungstates
《Chinese Journal of Structural Chemistry》2009年第6期655-662,共8页李德娟 郑寿添 杨国昱 
Supported by the National Natural Science Fund for Distinguished Young Scholars of China (No. 20725101);973 Program (No. 2006CB932904);NNSFC (No. 20821061);NSF of Fujian Province (No. E0510030);the Knowledge Innovation Program of CAS (No. KJCX2.YW.H01)
Two new organic-inorganic hybrid mono-transition-metal-substituted polyoxometalates [Ni(2,2′-bipy)3]3[Ni(H2O)SiW11O39]·11H2O 1 and [Cu(dien)(H2O)][Cu(dien)(H2O)2]2- [CuSiW11O39]·5.5H2O 2 (2,2′-bipy = ...
关键词:POLYOXOMETALATE SUBSTITUTED INORGANIC-ORGANIC transition metal 
Three Inorganic-organic Composite Polyoxotungstates:Syntheses,Characterization and Structures of [Cu(2,2ˊ-bpy)_2]_5[α-PW_(11.5)Cu_(0.5)O_(40)]·2H_2O,[Co(2,2ˊ-bpy)_2(N_3)_2]_4H_3[α-PW_(12)O_(40)]·3H_2O and [Cu(2,2ˊ-bpy)_2(4,4ˊ-bpy)]_2[α-GeW_(12)O_被引量:1
《Chinese Journal of Structural Chemistry》2008年第8期933-942,共10页赵俊伟 张杰 郑寿添 杨国昱 
the National Natural Science Foundation for Distinguished Young Scholars, 973 Program (No. 2006CB932900);NNSFC (No. 20473090);NSF of Fujian Province (No. E0510030);Key Project from CAS (No. KJCX2.YW.H01)
Three new inorganic-organic composite polyoxotungstates [Cu(2,2'-bpy)2]5[α-PW11.5Cu0.5O40]·2H2O 1, [Co(2,2'-bpy)2(N3)2]4H3[α-PW12O40]·3H2O 2 and [Cu(2,2'-bpy)2(4,4'-bpy)]2[α-GeW12O40]-4H2O 3 (2,2'...
关键词:polyoxometalate copper cobalt tungsten Keggin structure 
Imidazole Coordinated Sandwich-type Antimony Polyoxotungstates Na9[ {Na(H=O2}3{M(C3H4N2)}3( Sb W9O33)2]·xH=O(M=Ni^Ⅱ, Co^Ⅱ, Zn^Ⅱ, Mn^Ⅱ)被引量:1
《Chinese Journal of Chemistry》2007年第2期176-181,共6页崔蕊蕊 王虎林 杨欣雨 任淑华 胡怀明 付峰 王继武 薛岗林 
Project supported by the Natural Science Foundation of Shaanxi Province (No. 2003B01) and the Education Commission of Shaanxi Province (Nos. 03JK077, 03JS006).
The imidazole covalently coordinated sandwich-type heteropolymngstates Na9[ {Na(H=O2}3{M(C3H4N2)}3( Sb W9O33)2]·xH=O(M=Ni^Ⅱ, Co^Ⅱ, Zn^Ⅱ, Mn^Ⅱ) were obtained by the reaction of Na2WO4·2H2O, SbCl3·6H2O, Ni...
关键词:POLYOXOMETALATE crystal structure IMIDAZOLE transition metal 
Photocatalytic Hydrogen Evolution of Keggin-type Polyoxo-tungstates and their Electrochemical Behaviors被引量:1
《Chinese Chemical Letters》2006年第7期973-976,共4页Li Qin DANG Wan Sheng YOU Xin ZHANG Cui Ying HUANG Zhi Bin LEI Zhen Gang SUN Can LI 
This work was financially supported by the National Natural Science Foundation of China (No.20273070);the National-Key Basic Research and Development Program (No. 2003CB214500);The authors also gratefully acknowledge the Liaoning-Provincial Science and Technology Commission (No. 200310592003);Dalian Municipal Science and Technology Commission for financial support.
The photocatalytic hydrogen evolution and electrochemical behaviors of Kiggen-type XW12O40^n- (X=P, Ge and Si) are investigated. It is found that the two-electron reduced species are active for H^+ reduction and th...
关键词:POLYOXOTUNGSTATES PHOTOCATALYSIS hydrogen evolution electrochemistry. 
Synthesis and Spectroscopic Characterization of Organothiophosphoryl Polyoxotungstates α-[RP(S)]2PW9O34^5- (R=C6H5, C6H11)
《Chinese Journal of Chemistry》2005年第5期530-532,共3页孙振刚 朱再明 由万胜 郑学仿 谷源鹏 
Synthesis and Spectroscopic Characterization of Organothiophosphoryl Polyoxotungstates α-[C_6H_(11)P(S)]_2X^(n+)W_(11)O_(39)^((8-n)-)(X^(n+)P^(5+), Si^(4+), Ge^(4+), Ga^(3+)被引量:1
《Chemical Research in Chinese Universities》2004年第5期517-520,共4页SUNZhen-gang YOUWan-sheng ZHUZai-ming GUYuan-peng LIUJing-fu 
Supported by the Natural Science Foundation of L iaoning Province of China(No.2 0 0 32 10 4 )
Organothiophosphoryl polyoxotungstate derivatives α-C_6H_(11)P(S)]_2X^(n+)W_(11)O_(39)^((8-n)-)(X=P, Si, Ge, Ga) were obtained by the reactions of the monovacant α-_2X^(n+)W_(11)O_(39)^((8-n)-)(X=P, Si, Ge, Ga) were...
关键词:POLYOXOTUNGSTATE Organophosphorus SYNTHESIS ()^(31)P NMR ()^(183)W NMR 
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