This study was financially supported by the National Natural Science Foundation of China(No.22101086);Guangdong Basic and Applied Basic Research Foundation(Nos.2023A1515140030 and 2024A1515030212).
Innovative advancements in the development of high-performance,eco-friendly adhesives are critical for meeting the demands of diverse applications in various industries.This study reports a significant leap in adhesiv...
supported by the National Natural Science Foundation of China (Grant No. 22001034);the Open Fund of the Jiangxi Province Key Laboratory of Synthetic Chemistry (Grant No. JXSC202008);the Research Found of East China University of Technology (Grant Nos. DHBK2019264, DHBK2019265, DHBK2019267)
In this study,a sandwich-type uranium(Ⅵ)-containing silicotungstate KNa11H2(H2O)30[Na(UO2)(SiW9O34)]2·8H2O(1)with new three-dimensional(3D)structure was synthesized and characterized using single-crystal X-ray diffr...
the financial support from the National Natural Science Foundation of China(NSFC)(nos.21773029,21831001,and 21971039).
This work demonstrates that the introduction of positive lanthanide(Ln)and transition metal(TM)cations into polyoxotungstates(POTs)to stabilize negative oxoboron clusters is a feasible and general synthetic strategy f...
supported by the NNSFC(No.21473030,1371033);Fujian Provincial Natural Science Foundation(2013J01042);the Open Fund of State Key Laboratory of Structural Chemistry(20130015)
A three-dimensional (3D) Keggin-type heteropolytungstate{Zn(phen)3}3[ZnW12O40]·9H2O 1 (phen = 1,10-phenanthroline) has been synthesized through a conventional hydrothermal synthesis and was characterized by X-r...
Supported by the National Natural Science Fund for Distinguished Young Scholars of China (No. 20725101);973 Program (No. 2006CB932904);NNSFC (No. 20821061);NSF of Fujian Province (No. E0510030);the Knowledge Innovation Program of CAS (No. KJCX2.YW.H01)
Two new organic-inorganic hybrid mono-transition-metal-substituted polyoxometalates [Ni(2,2′-bipy)3]3[Ni(H2O)SiW11O39]·11H2O 1 and [Cu(dien)(H2O)][Cu(dien)(H2O)2]2- [CuSiW11O39]·5.5H2O 2 (2,2′-bipy = ...
the National Natural Science Foundation for Distinguished Young Scholars, 973 Program (No. 2006CB932900);NNSFC (No. 20473090);NSF of Fujian Province (No. E0510030);Key Project from CAS (No. KJCX2.YW.H01)
Three new inorganic-organic composite polyoxotungstates [Cu(2,2'-bpy)2]5[α-PW11.5Cu0.5O40]·2H2O 1, [Co(2,2'-bpy)2(N3)2]4H3[α-PW12O40]·3H2O 2 and [Cu(2,2'-bpy)2(4,4'-bpy)]2[α-GeW12O40]-4H2O 3 (2,2'...
Project supported by the Natural Science Foundation of Shaanxi Province (No. 2003B01) and the Education Commission of Shaanxi Province (Nos. 03JK077, 03JS006).
The imidazole covalently coordinated sandwich-type heteropolymngstates Na9[ {Na(H=O2}3{M(C3H4N2)}3( Sb W9O33)2]·xH=O(M=Ni^Ⅱ, Co^Ⅱ, Zn^Ⅱ, Mn^Ⅱ) were obtained by the reaction of Na2WO4·2H2O, SbCl3·6H2O, Ni...
This work was financially supported by the National Natural Science Foundation of China (No.20273070);the National-Key Basic Research and Development Program (No. 2003CB214500);The authors also gratefully acknowledge the Liaoning-Provincial Science and Technology Commission (No. 200310592003);Dalian Municipal Science and Technology Commission for financial support.
The photocatalytic hydrogen evolution and electrochemical behaviors of Kiggen-type XW12O40^n- (X=P, Ge and Si) are investigated. It is found that the two-electron reduced species are active for H^+ reduction and th...
Supported by the Natural Science Foundation of L iaoning Province of China(No.2 0 0 32 10 4 )
Organothiophosphoryl polyoxotungstate derivatives α-C_6H_(11)P(S)]_2X^(n+)W_(11)O_(39)^((8-n)-)(X=P, Si, Ge, Ga) were obtained by the reactions of the monovacant α-_2X^(n+)W_(11)O_(39)^((8-n)-)(X=P, Si, Ge, Ga) were...