The work described in this paper was supported by grants from the Research Grants Council of the Hong Kong Special Administration Region(Nos.404610 and CUHK7/CRF/12G).
The reasons for facile double desilylation of 13-vertex carborane 1,2-Me_(2)Si(CH_(2))_(2)-1,2-C_(2)B_(11)H_(11)(2)are discussed in this article.New 13-and 14-vertex ruthenacarboranes bearing the same-CH_(2)SiMe_(2)CH...
supported by National Natural Science Foundation of China (Nos. 20872035, 21076078), and Specialized Research Fund for the Doctoral Program of Higher Education (No. 20070251018).
Three routes were designed to synthesize a n-conjugated aryleneethynylenesiloles dendron. With the desilylation of the disilole mono(silylethynyl) derivative in the presence of potassium carbonate (K2CO3), the sil...
the National Natural Science Foundation of China (Grant No. 29972018) for financial support.
A photochemical desilylation reaction with nearly quantilative yield and excellent selectivity between silyl alkyl ether and silyl enol ether is reported.