financially supported by the National Natural Science Foundation of China(Nos.21901020 and 22003076);China Postdoctoral Science Foundation(No.2021M701818);Shandong Provincial Natural Science Foundation(No.ZR2022QE237);the Qingdao Postdoctoral Applied Research Project.H.Liu sincerely acknowledges financial support from the Taishan Scholars Program(No.tsqn202211165)。
High catalytic efficiencies in ring opening polymerization(ROP)of a large ring-sized macrolactone,ω-pentadecalactone(PDL),by using transition metal Fe(II)-based catalysts were achieved for the first time in this stud...
supported by the National Key R&D Program of China(2021YFA1501700);Fundamental Research Funds for the Central Universities(WK9990000142).
The seminal report ofα-diimine palladium and nickel catalysts in 1995 represented a major breakthrough in the preparation of functionalized polyolefin materials.Owing to the high abundance and low cost of nickel,nick...
supported by the National Natural Science Foundation of China(52203016);the USTC Research Funds of the Double First-Class Initiative(YD9990002018);the Overseas Students Innovation and Entrepreneurship Support Program Project of Anhui Province(2021LCX022);the Key R&D Projects in Anhui Province(2022i01020012);the Natural Science Foundation of Hefei(2022039);the Excellent Research and Innovation Team Project of Anhui Province(2022AH010001).
α-Diimide catalysts have attracted widespread attention due to their unique chain walking characteristics.A series ofα-diimide nickel/palladium catalysts with different electronic effects and steric hindrances were ...
This work was financially supported by the Chemistry and Chemical Engineering Guangdong Laboratory(Nos.2111018 and 2132012);Q.M.would like to express gratitude towards the Foreign Youth Talent Program(No.QN2022030008L)for their support.
For practicable elastomeric polyethylene,achieving high catalyst thermal stability and activity,along with precise control of polymer properties such as branching density,molecular weights,and distribution,is crucial ...
The catalysis of olefin polymerization through the chain-walking process is a subject of great interest. In this contribution, the successful synthesis of a Brookhart-type unsymmetrical α-diimine nickel catalyst Ni, ...
This work was supported by the National Natural Science Foundation of China(No.22122110);the Science and Technology Department Program of Jilin Province,China(No.20230101347JC).
Polyolefins are globally important plastics.Molecular weight and molecular weight distribution are two key parameters for determining the properties of polyolefin materials.In this contribution,we develop a strategy f...
supported by National Key R&D Program of China(No.2021YFA1501700);the National Natural Science Foundation of China(Nos.52025031,22001004,22261142664,U19B6001,U1904212).
Heterogenization can improve the thermal tolerance of olefin polymerization catalysts and result in good product morphology con-trol,which are two important parameters for industrial polyethylene production.In this wo...
support from the National Natu-ral Science Foundation of China(Nos.22122110 and 21871250).
Beyond the single ligand electronic and/or steric modifications, external stimuli are a useful tool for modulating catalytic polymerization reactions. Light stands out from external stimuli, but the corresponding phot...
support from the National Natural Science Foundation of China(Nos.21871250 for Z.Jian,22001244 for Y.Zhang);the Jilin Provincial Science and Technology Department Program(No.20200801009GH).
Main observation and conclusion Steric bulk plays a significantly paramount role in late transition metal promoted olefin(co)polymerization in terms of polymer molecular weight and catalyst thermal stability.Numerous ...
Financial support from the National Key Research and Development Program(2016YFB0302403)is gratefully acknowledged.
The structure of polyolefin has an important influence on its performance and application.Ethylene/1-hexene copolymerization is one of the important ways to control the structure of the polyolefin.However,research on ...