Α-DIIMINE

作品数:23被引量:49H指数:5
导出分析报告
相关领域:理学更多>>
相关作者:董青松杨晓娟赵艳霞更多>>
相关机构:中国科学院中山大学更多>>
相关期刊:《Chemical Research in Chinese Universities》《中国科学技术大学学报》《Open Journal of Organic Polymer Materials》《Science China Chemistry》更多>>
相关基金:国家自然科学基金更多>>
-

检索结果分析

结果分析中...
条 记 录,以下是1-10
视图:
排序:
Ring Opening Polymerization ofω-Pentadecalactone by Weakly Oxophilic Fe(II)-based Catalytic Systems Bearing Bulkyα-Diimine Ligands
《Chinese Journal of Polymer Science》2025年第4期640-654,共15页Li-Jia Liu Wen-Peng Zhao Li-Shuang Ma Chun-Yu Zhang Feng Wang Xue-Quan Zhang Heng Liu 
financially supported by the National Natural Science Foundation of China(Nos.21901020 and 22003076);China Postdoctoral Science Foundation(No.2021M701818);Shandong Provincial Natural Science Foundation(No.ZR2022QE237);the Qingdao Postdoctoral Applied Research Project.H.Liu sincerely acknowledges financial support from the Taishan Scholars Program(No.tsqn202211165)。
High catalytic efficiencies in ring opening polymerization(ROP)of a large ring-sized macrolactone,ω-pentadecalactone(PDL),by using transition metal Fe(II)-based catalysts were achieved for the first time in this stud...
关键词:ω-Pentadecalactone Ring opening polymerization Polyester Ferrous catalysts 
Remote electron effects and π-π interactions of α-diimine nickel complexes
《中国科学技术大学学报》2024年第9期17-22,68,共7页Yizhan Wang Hailong He Dan Peng 
supported by the National Key R&D Program of China(2021YFA1501700);Fundamental Research Funds for the Central Universities(WK9990000142).
The seminal report ofα-diimine palladium and nickel catalysts in 1995 represented a major breakthrough in the preparation of functionalized polyolefin materials.Owing to the high abundance and low cost of nickel,nick...
关键词:α-diimine nickel catalyst ethylene polymerization π-πinteraction effect electronic effect polar monomer 
Nickel catalysts with asymmetric steric hindrance for ethylene polymerization
《中国科学技术大学学报》2024年第6期48-52,59,I0010,I0011,共8页Wanlu Tian Fuzhou Wang Chen Zou 
supported by the National Natural Science Foundation of China(52203016);the USTC Research Funds of the Double First-Class Initiative(YD9990002018);the Overseas Students Innovation and Entrepreneurship Support Program Project of Anhui Province(2021LCX022);the Key R&D Projects in Anhui Province(2022i01020012);the Natural Science Foundation of Hefei(2022039);the Excellent Research and Innovation Team Project of Anhui Province(2022AH010001).
α-Diimide catalysts have attracted widespread attention due to their unique chain walking characteristics.A series ofα-diimide nickel/palladium catalysts with different electronic effects and steric hindrances were ...
关键词:Α-DIIMINE nickel complex POLYETHYLENE POLYMERIZATION asymmetric steric hindrance 
High-Performanceα-Diimine Nickel Complexes for Facile Access of PE Elastomers with Exceptional Material Properties
《Chinese Journal of Polymer Science》2024年第5期620-635,I0008,共17页Li-Dong Qin Xin-Yu Wang Qaiser Mahmood Zhi-Xin Yu Yi-Zhou Wang Song Zou Tong-Ling Liang Wen-Hua Sun 
This work was financially supported by the Chemistry and Chemical Engineering Guangdong Laboratory(Nos.2111018 and 2132012);Q.M.would like to express gratitude towards the Foreign Youth Talent Program(No.QN2022030008L)for their support.
For practicable elastomeric polyethylene,achieving high catalyst thermal stability and activity,along with precise control of polymer properties such as branching density,molecular weights,and distribution,is crucial ...
关键词:Thermoplastic polyethylene elastomers α-Diimine nickel pre-catalysts Ethylene polymerization Mechanical properties Highly branched polyethylene 
Synthesis of Branched Polyethylene via Bulky α-Diimine Nickel(II)-Catalyzed Ethylene Chain-Walking Polymerization
《Open Journal of Organic Polymer Materials》2024年第1期1-12,共12页Zhengquan Dong Pei Li Guoyong Xu Fuzhou Wang 
The catalysis of olefin polymerization through the chain-walking process is a subject of great interest. In this contribution, the successful synthesis of a Brookhart-type unsymmetrical α-diimine nickel catalyst Ni, ...
关键词:Ethylene Polymerization α-Diimine Ni(II) Complex Chain-Walking Polymerization Branched Polyethylene 
Macrocyclic Binuclearα-Diimine Nickel Catalysts for Ethylene Polymerization被引量:1
《Chemical Research in Chinese Universities》2023年第5期797-802,共6页YANG Jingshuang ZHANG Yuxing JIAN Zhongbao 
This work was supported by the National Natural Science Foundation of China(No.22122110);the Science and Technology Department Program of Jilin Province,China(No.20230101347JC).
Polyolefins are globally important plastics.Molecular weight and molecular weight distribution are two key parameters for determining the properties of polyolefin materials.In this contribution,we develop a strategy f...
关键词:POLYOLEFIN Nickel catalyst Diimine ligand Macrocyclic binuclear strategy Bimodal polyethylene 
Heterogeneousα-Diimine Nickel Catalysts with Improved Catalytic Performance in Ethylene Polymerization被引量:1
《Chinese Journal of Chemistry》2023年第10期1155-1162,共8页Zhanshan Ma Mengli Xu Ningning Zhu Chen Tan Changle Chen 
supported by National Key R&D Program of China(No.2021YFA1501700);the National Natural Science Foundation of China(Nos.52025031,22001004,22261142664,U19B6001,U1904212).
Heterogenization can improve the thermal tolerance of olefin polymerization catalysts and result in good product morphology con-trol,which are two important parameters for industrial polyethylene production.In this wo...
关键词:Ethylene polymerization Mechanical properties NICKEL Supported catalysts Heterogeneous catalysis POLYMERIZATION MORPHOLOGY 
Photoresponsive α-Diimine Nickel Modulated Ethylene (Co)Polymerization被引量:2
《Chinese Journal of Chemistry》2022年第24期2919-2926,共8页Jingshuang Yang Xiaoqiang Hu Zhongbao Jian 
support from the National Natu-ral Science Foundation of China(Nos.22122110 and 21871250).
Beyond the single ligand electronic and/or steric modifications, external stimuli are a useful tool for modulating catalytic polymerization reactions. Light stands out from external stimuli, but the corresponding phot...
关键词:Olefin polymerization PHOTOCHEMISTRY Polyethylene Polar monomer Nickel catalyst 
Horizontally and Vertically Concerted Steric Strategy inα-Diimine Nickel Promoted Ethylene(Co)Polymerization被引量:5
《Chinese Journal of Chemistry》2021年第10期2829-2836,共8页Xiaoqiang Hu Yixin Zhang Baixiang Li Zhongbao Jian 
support from the National Natural Science Foundation of China(Nos.21871250 for Z.Jian,22001244 for Y.Zhang);the Jilin Provincial Science and Technology Department Program(No.20200801009GH).
Main observation and conclusion Steric bulk plays a significantly paramount role in late transition metal promoted olefin(co)polymerization in terms of polymer molecular weight and catalyst thermal stability.Numerous ...
关键词:Olefin polymerization Steric effect Homogeneous catalysis UHMWPE NICKEL 
Study on ethylene/1-hexene copolymerization catalyzed by α-diimine nickel catalysts with different ligands--Dedicated to Professor Xiuwen Han on the occasion of her 80th birthday
《Magnetic Resonance Letters》2021年第2期131-141,共11页Yusheng Xing Haojie Yu Li Wang Nan Wang Lei Zhu Ruixue Liang Md Alim Uddin 
Financial support from the National Key Research and Development Program(2016YFB0302403)is gratefully acknowledged.
The structure of polyolefin has an important influence on its performance and application.Ethylene/1-hexene copolymerization is one of the important ways to control the structure of the polyolefin.However,research on ...
关键词:α-diimine nickel catalysts COPOLYMERIZATION Microstructure EPR spectroscopy 
检索报告 对象比较 聚类工具 使用帮助 返回顶部